Solid-State NMR and DFT Studies on the Formation of Well-Defined Silica-Supported Tantallaaziridines: From Synthesis to Catalytic Application

Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica‐supported tetrakis(dimethylamido)tantalum [≡Si‐O‐Ta(NMe2)4] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and 1H,13C HETCOR and...

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Published inChemistry : a European journal Vol. 22; no. 9; pp. 3000 - 3008
Main Authors Hamzaoui, Bilel, Pelletier, Jérémie D. A., Abou-Hamad, Edy, Chen, Yin, El Eter, Mohamed, Chermak, Edrisse, Cavallo, Luigi, Basset, Jean-Marie
Format Journal Article
LanguageEnglish
Published WEINHEIM Blackwell Publishing Ltd 24.02.2016
Wiley
Wiley Subscription Services, Inc
Subjects
Activation
Alkenes
Amines
Aromatic compounds
Catalysis
Catalysts
Chemical synthesis
Chemistry
Chemistry, Multidisciplinary
Formations
Fourier transforms
hydroamination
Infrared spectroscopy
Intermediates
Magnetic resonance spectroscopy
Mathematical analysis
metallacycles
NMR
NMR spectroscopy
Nuclear magnetic resonance
Physical Sciences
Science & Technology
Silica
Silicon dioxide
solid-state NMR spectroscopy
Spectroscopic analysis
Spectroscopy
Spectrum analysis
Substrates
supported catalysts
Tantalum
ZIRCONOCENE ETA-2-IMINE COMPLEXES
solid-state NMR spectroscopy
TANTALUM COMPLEXES
UNACTIVATED OLEFINS
supported catalysts
INTERMOLECULAR HYDROAMINOALKYLATION
DYNAMIC KINETIC RESOLUTION
hydroamination
ORDER REGULAR APPROXIMATION
CYCLIC CARBONATE
tantalum
DENSITY-FUNCTIONAL THEORY
GAUSSIAN-BASIS SETS
metallacycles
AMINO-ACID ESTERS
Online AccessGet full text

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Abstract Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica‐supported tetrakis(dimethylamido)tantalum [≡Si‐O‐Ta(NMe2)4] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and 1H,13C HETCOR and DQ TQ solid‐state (SS) NMR spectroscopy. The formation mechanism, by β‐H ion, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C−H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N‐alkyl aryl amine substrates being more efficient than N‐dialkyl amines. Single‐site well‐defined silica‐supported tantallaaziridines [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] (R=Me, Ph) were isolated and fully characterized. The formation mechanism by β‐H ion was investigated by solid‐state NMR spectroscopy and supported by DFT calculations. Catalytic testing for the hydroaminoalkylations of alkenes were consistent with the N‐alkyl‐arylamine substrates being more efficient than N‐dialkylamines (see scheme).
AbstractList Single-site, well-defined, silica-supported tantallaaziridine intermediates [≡Si-O-Ta(η(2) -NRCH2 )(NMe2 )2 ] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [≡Si-O-Ta(NMe2 )4 ] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and (1) H,(13) C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by β-H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines.
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta(η2-NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [Si-O-Ta(NMe2)4] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and 1H,13C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by [beta]-H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines.
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta((2)-NRCH2)(NMe2)(2)] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [Si-O-Ta(NMe2)(4)] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and H-1,C-13 HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by -H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines.
Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η 2 ‐NRCH 2 )(NMe 2 ) 2 ] [R=Me ( 2 ), Ph ( 3 )] were prepared from silica‐supported tetrakis(dimethylamido)tantalum [≡Si‐O‐Ta(NMe 2 ) 4 ] ( 1 ) and fully characterized by FTIR spectroscopy, elemental analysis, and 1 H, 13 C HETCOR and DQ TQ solid‐state (SS) NMR spectroscopy. The formation mechanism, by β‐H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C−H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N ‐alkyl aryl amine substrates being more efficient than N ‐dialkyl amines.
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta( eta super(2)-NRCH sub(2))(NMe sub(2)) sub(2)] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [Si-O-Ta(NMe sub(2)) sub(4)] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and super(1)H, super(13)C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by beta -H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines. Single-site well-defined silica-supported tantallaaziridines [Si-O-Ta( eta super(2)-NRCH sub(2))(NMe sub(2)) sub(2)] (R=Me, Ph) were isolated and fully characterized. The formation mechanism by beta -H abstraction was investigated by solid-state NMR spectroscopy and supported by DFT calculations. Catalytic testing for the hydroaminoalkylations of alkenes were consistent with the N-alkyl-arylamine substrates being more efficient than N-dialkylamines (see scheme).
Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica‐supported tetrakis(dimethylamido)tantalum [≡Si‐O‐Ta(NMe2)4] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and 1H,13C HETCOR and DQ TQ solid‐state (SS) NMR spectroscopy. The formation mechanism, by β‐H ion, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C−H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N‐alkyl aryl amine substrates being more efficient than N‐dialkyl amines. Single‐site well‐defined silica‐supported tantallaaziridines [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] (R=Me, Ph) were isolated and fully characterized. The formation mechanism by β‐H ion was investigated by solid‐state NMR spectroscopy and supported by DFT calculations. Catalytic testing for the hydroaminoalkylations of alkenes were consistent with the N‐alkyl‐arylamine substrates being more efficient than N‐dialkylamines (see scheme).
Single-site, well-defined, silica-supported tantallaaziridine intermediates [≡Si-O-Ta(η(2) -NRCH2 )(NMe2 )2 ] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [≡Si-O-Ta(NMe2 )4 ] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and (1) H,(13) C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by β-H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines.Single-site, well-defined, silica-supported tantallaaziridine intermediates [≡Si-O-Ta(η(2) -NRCH2 )(NMe2 )2 ] [R=Me (2), Ph (3)] were prepared from silica-supported tetrakis(dimethylamido)tantalum [≡Si-O-Ta(NMe2 )4 ] (1) and fully characterized by FTIR spectroscopy, elemental analysis, and (1) H,(13) C HETCOR and DQ TQ solid-state (SS) NMR spectroscopy. The formation mechanism, by β-H abstraction, was investigated by SS NMR spectroscopy and supported by DFT calculations. The C-H activation of the dimethylamide ligand is favored for R=Ph. The results from catalytic testing in the hydroaminoalkylation of alkenes were consistent with the N-alkyl aryl amine substrates being more efficient than N-dialkyl amines.
Author El Eter, Mohamed
Cavallo, Luigi
Hamzaoui, Bilel
Chen, Yin
Abou-Hamad, Edy
Basset, Jean-Marie
Chermak, Edrisse
Pelletier, Jérémie D. A.
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Cites_doi 10.1021/ja806367e
10.1063/1.467146
10.1002/ange.201206027
10.1063/1.478813
10.1039/c2dt30781b
10.1021/ja0718366
10.1002/(SICI)1097-461X(1997)61:6<899::AID-QUA3>3.0.CO;2-R
10.1021/ja211945m
10.1021/ja00194a052
10.1021/cs400349p
10.1063/1.467943
10.1021/ja506187m
10.1021/jo010940h
10.1103/PhysRevLett.77.3865
10.1002/ange.200900735
10.1016/S0040-4039(00)61172-3
10.1063/1.466059
10.1016/0040-4039(95)00741-T
10.1039/C5SC02276B
10.1039/c0cc01265c
10.1021/om9606496
10.1055/s-1980-29002
10.1063/1.463096
10.1055/s-1990-21061
10.1039/dt9730000381
10.1021/ja00347a023
10.1002/jcc.1056
10.1055/s-1992-21993
10.1039/c3cc43463j
10.1021/ct200143w
10.1002/anie.201304153
10.1021/om00013a031
10.1021/om1011006
10.1063/1.478522
10.1002/chem.201405788
10.1002/anie.200900735
10.1021/ja00218a027
10.1021/ol402890m
10.1016/S0040-4039(00)76242-3
10.1021/ja5113468
10.1002/(SICI)1097-461X(1996)60:3<753::AID-QUA4>3.0.CO;2-W
10.1002/ange.201101239
10.1002/adsc.201500484
10.1021/om000915m
10.1021/om00101a012
10.1021/om500684e
10.1007/978-94-011-1693-0_3
10.1002/ejoc.201400082
10.1021/ja00108a015
10.1039/c3cc40385h
10.1002/anie.201403203
10.1002/ange.200903656
10.1002/ange.201304153
10.1021/ja984061x
10.1021/cs5001703
10.1016/0022-328X(86)80154-1
10.1002/jcc.21759
10.1002/anie.201206027
10.1021/cs5020749
10.1021/j100002a024
10.1002/anie.201101239
10.1021/om000768s
10.1021/ja5130258
10.1021/jp0346559
10.1021/ja00006a071
10.1021/jacs.5b02872
10.1002/anie.200903656
10.1002/ange.201403203
10.1016/S0022-328X(00)81160-2
10.1021/om00073a031
10.1021/om00037a027
10.1039/c5sc02276b
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Issue 9
Keywords ZIRCONOCENE ETA-2-IMINE COMPLEXES
solid-state NMR spectroscopy
TANTALUM COMPLEXES
UNACTIVATED OLEFINS
supported catalysts
INTERMOLECULAR HYDROAMINOALKYLATION
DYNAMIC KINETIC RESOLUTION
hydroamination
ORDER REGULAR APPROXIMATION
CYCLIC CARBONATE
tantalum
DENSITY-FUNCTIONAL THEORY
GAUSSIAN-BASIS SETS
metallacycles
AMINO-ACID ESTERS
Language English
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2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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PublicationDate February 24, 2016
PublicationDateYYYYMMDD 2016-02-24
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  year: 2016
  text: February 24, 2016
  day: 24
PublicationDecade 2010
PublicationPlace WEINHEIM
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PublicationSubtitle A European Journal
PublicationTitle Chemistry : a European journal
PublicationTitleAbbrev CHEM-EUR J
PublicationTitleAlternate Chem. Eur. J
PublicationYear 2016
Publisher Blackwell Publishing Ltd
Wiley
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References L. W. Francisco, P. S. White, J. L. Templeton, Organometallics 1996, 15, 5127-5136
I. Prochnow, P. Zark, T. Muller, S. Doye, Angew. Chem. Int. Ed. 2011, 50, 6401-6405
S. B. Herzon, J. F. Hartwig, J Am Chem. Soc 2007, 129, 6690
J. M. Basset, S. L. Scott, L. Choplin, A. Leconte, M. Quignard, F. Santini, C. Theolier in Organometallic Chemistry as a Basis for Understanding Heterogeneous Catalysis, Vol. 39: Elementary Reaction Steps in Heterogeneous Catalysis (Eds.: R. W. Joyner and R. A. van Santen), Springer Science+Business Media, Dordrecht, 1993, pp. 39-49.
J. M. Davis, R. J. Whitby, A. Jaxachamiec, Tetrahedron Lett. 1994, 35, 1445-1448
B. Hamzaoui, J. D. A. Pelletier, M. El Eter, Y. Chen, E. Abou-Hamad, J.-M. Basset, Adv. Synth. Catal. 2015, 357, 3148-3154.
D. A. Gately, J. R. Norton, P. A. Goodson, J. Am. Chem. Soc. 1995, 117, 986-996
J. A. Tunge, C. J. Czerwinski, D. A. Gately, J. R. Norton, Organometallics 2001, 20, 254-260
J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865-3868.
E. van Lenthe, E.-J. Baerends, J. G. Snijders, J. chem. phys. 1994, 101, 9783-9792
F. A. Pasha, L. Cavallo, J. M. Basset, ACS Catal. 2014, 4, 1868-1874.
J. Autschbach, E. Zurek, J. Phys. Chem. A 2003, 107, 4967-4972.
J. X. Chen, J. A. Tunge, J. R. Norton, J. Org. Chem. 2002, 67, 4366-4369
G. Schreckenbach, T. Ziegler, J. Phys. Chem. 1995, 99, 606-611
J. Autschbach, S. Patchkovskii, B. Pritchard, J. Chem. Theory Comput. 2011, 7, 2175-2188
J. Browning, H. D. Empsall, M. Green, F. G. A. Stone, J. Chem. Soc. Dalton Trans. 1973, 381-387.
S. Grimme, S. Ehrlich, L. Goerigk, J. Comput. Chem. 2011, 32, 1456-1465.
E. Chong, J. W. Brandt, L. L. Schafer, J Am Chem. Soc 2014, 136, 10898-10901
J. M. Mayer, C. J. Curtis, J. E. Bercaw, J Am Chem. Soc 1983, 105, 2651-2660.
M. C. J. Harris, R. J. Whitby, J. Blagg, Tetrahedron Lett. 1995, 36, 4287-4290.
T. V. Lubben, K. Plossl, J. R. Norton, M. M. Miller, O. P. Anderson, Organometallics 1992, 11, 122-127
Angew. Chem. 2011, 123, 6525-6529
E. van Lenthe, A. Ehlers, E.-J. Baerends, J. chem. phys. 1999, 110, 8943-8953
L. H. Polm, G. Vankoten, C. J. Elsevier, K. Vrieze, B. F. K. Vansanten, C. H. Stam, J. Organomet. Chem. 1986, 304, 353-370
P. W. Roesky, Angew. Chem. Int. Ed. 2009, 48, 4892-4894
S. L. Buchwald, R. B. Nielsen, J. C. Dewan, Organometallics 1988, 7, 2324-2328.
T. Y. Chen, R. Tsutsumi, T. P. Montgomery, I. Volchkov, M. J. Krische, J. Am. Chem. Soc. 2015, 137, 1798-1801.
A. L. Reznichenko, K. C. Hultzsch, J. Am. Chem. Soc. 2012, 134, 3300-3311.
G. F. Zi, F. R. Zhang, H. B. Song, Chem. Commun. 2010, 46, 6296-6298
Angew. Chem. 2009, 121, 4988-4991
N. Coles, M. C. J. Harris, R. J. Whitby, J. Blagg, Organometallics 1994, 13, 190-199
W. A. Nugent, D. W. Ovenall, S. J. Holmes, Organometallics 1983, 2, 161-162
J. Dörfler, S. Doye, Angew. Chem. Int. Ed. 2013, 52, 1806-1809
E. van Lenthe, E.-J. Baerends, J. G. Snijders, J. chem. phys. 1993, 99, 4597-4610.
S. L. Buchwald, R. B. Nielsen, J. Am. Chem. Soc. 1988, 110, 3171-3175
J. M. P. Lauzon, L. L. Schafer, Dalton Trans. 2012, 41, 11539-11550.
P. Eisenberger, R. O. Ayinla, J. M. P. Lauzon, L. L. Schafer, Angew. Chem. Int. Ed. 2009, 48, 8361-8365
D. C. Schmitt, J. Lee, A. M. R. Dechert-Schmitt, E. Yamaguchi, M. J. Krische, Chem. Commun. 2013, 49, 6096-6098
A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571-2577.
M. Beaudoin, S. L. Scott, Organometallics 2001, 20, 237-239.
B. Werghi, A. Bendjeriou-Sedjerari, J. Sofack-Kreutzer, A. Jedidi, E. Abou-Hamad, L. Cavallo, J.-M. Basset, Chem. Sci. 2015, 6, 5456-5465
E. Chong, L. L. Schafer, Org Lett. 2013, 15, 6002-6005
V. D′Elia, H. Dong, A. J. Rossini, C. M. Widdifield, S. V. C. Vummaleti, Y. Minenkov, A. Poater, E. Abou-Hamad, J. D. A. Pelletier, L. Cavallo, L. Emsley, J.-M. Basset, J. Am. Chem. Soc. 2015, 137, 7728-7739
A. Hamieh, Y. Chen, S. Abdel-Azeim, E. Abou-hamad, S. Goh, M. Samantaray, R. Dey, L. Cavallo, J. M. Basset, ACS Catal. 2015, 5, 2164-2171
R. B. Grossman, W. M. Davis, S. L. Buchwald, J. Am. Chem. Soc. 1991, 113, 2321-2322
Y. Chen, R. Credendino, E. Callens, M. Atiqullah, M. A. Al-Harthi, L. Cavallo, J.-M. Basset, ACS Catal. 2013, 3, 1360-1364
N. Coles, R. J. Whitby, J. Blagg, Synlett 1992, 143-145.
H. Hoberg, V. Gotz, C. Kruger, Y. H. Tsay, J. Organomet. Chem. 1979, 169, 209-217
G. Te Velde, F. M. Bickelhaupt, E. J. Baerends, C. Fonseca Guerra, S. J. van Gisbergen, J. G. Snijders, T. Ziegler, J. Comput. Chem. 2001, 22, 931-967
N. Riache, A. Dery, E. Callens, A. Poater, M. Samantaray, R. Dey, J. Hong, K. Li, L. Cavallo, J.-M. Basset, Organometallics 2015, 34, 690-695.
S. B. Herzon, J. F. Hartwig, J. Am. Chem. Soc. 2008, 130, 14940.
Angew. Chem. 2013, 125, 1851-1854.
A. Schäfer, C. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 100, 5829-5835.
G. Schreckenbach, T. Ziegler, Int. J. Quantum Chem. 1997, 61, 899-918
B. Hamzaoui, M. El Eter, E. Abou-Hamad, Y. Chen, J. D. A. Pelletier, J. M. Basset, Chem. Eur. J. 2015, 21, 4294-4299
Angew. Chem. 2013, 125, 9314-9318
J. A. Tunge, D. A. Gately, J. R. Norton, J. Am. Chem. Soc. 1999, 121, 4520-4521.
Angew. Chem. 2014, 126, 8052-8056
J. Dörfler, T. Preuss, A. Schischko, M. Schmidtmann, S. Doye, Angew. Chem. Int. Ed. 2014, 53, 7918-7922
P. Garcia, Y. Y. Lau, M. R. Perry, L. L. Schafer, Angew. Chem. Int. Ed. 2013, 52, 9144-9148
N. Coles, R. J. Whitby, J. Blagg, Synlett 1990, 271-272
M. El Eter, B. Hamzaoui, E. Abou-Hamad, J. D. A. Pelletier, J. M. Basset, Chem. Commun. 2013, 49, 4616-4618.
M. G. Clerici, F. Maspero, Synthesis 1980, 305-306
J. M. Davis, R. J. Whitby, A. Jaxachamiec, Tetrahedron Lett. 1992, 33, 5655-5658
J. Dörfler, S. Doye, Eur J Org Chem. 2014, 2014, 2790-2797
Y. Chen, E. Abou-hamad, A. Hamieh, B. Hamzaoui, L. Emsley, J. M. Basset, J. Am. Chem. Soc. 2015, 137, 588-591.
G. Schreckenbach, T. Ziegler, Int. J. Quantum Chem. 1996, 60, 753-766
C. Adamo, V. Barone, J. Chem. Phys. 1999, 110, 6158-6170.
A. L. Reznichenko, T. J. Emge, S. Audorsch, E. G. Klauber, K. C. Hultzsch, B. Schmidt, Organometallics 2011, 30, 921-924.
Angew. Chem. 2009, 121, 8511-8515
S. L. Buchwald, B. T. Watson, M. W. Wannamaker, J. C. Dewan, J Am Chem. Soc 1989, 111, 4486-4494.
2014 2014; 53 126
2015; 34
2013; 3
1991; 113
1983; 2
2009 2009; 48 121
1995; 36
1989; 111
1999; 121
1973
1992; 97
1992; 11
2014; 136
2013 2013; 52 125
1996; 77
1994; 101
1986; 304
1983; 105
1994; 100
2013; 15
2014; 4
2012; 134
2015; 137
1990
1996; 60
1994; 35
1980
1979; 169
2007; 129
2015; 6
2015; 5
1997; 61
2013; 49
1995; 99
1995; 117
2011; 30
2011; 32
2014; 2014
1993
1992
2001; 22
1992; 33
1996; 15
2011; 7
2001; 20
2003; 107
2010; 46
2015; 357
2002; 67
1993; 99
1988; 7
2015; 21
1999; 110
1994; 13
1988; 110
2011 2011; 50 123
2008; 130
2012; 41
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Eisenberger, P. (000370452300021.29) 2009; 121
CLERICI, MG (WOS:A1980JQ10300013) 1980
Tunge, JA (WOS:000080550100028) 1999; 121
NUGENT, WA (WOS:A1983PZ13200031) 1983; 2
Reznichenko, AL (WOS:000301161500072) 2012; 134
Autschbach, J (WOS:000292617900018) 2011; 7
Werghi, B (WOS:000361212000013) 2015; 6
Francisco, LW (WOS:A1996VV37400010) 1996; 15
van Lenthe, E (WOS:000080073200011) 1999; 110
Zi, GF (WOS:000281007400021) 2010; 46
Pasha, FA (WOS:000337074700027) 2014; 4
SCHRECKENBACH, G (WOS:A1995QB56800024) 1995; 99
Reznichenko, AL (WOS:000287955800001) 2011; 30
Dorfler, J (WOS:000339562400043) 2014; 53
Garcia, P (WOS:000323393100018) 2013; 52
COLES, N (WOS:A1994MR76800031) 1994; 13
Eisenberger, P (WOS:000271302900038) 2009; 48
LUBBEN, TV (WOS:A1992GZ04000027) 1992; 11
GROSSMAN, RB (WOS:A1991FB94000071) 1991; 113
Tunge, JA (WOS:000166493900005) 2001; 20
BROWNING, J (WOS:A1973P453800007) 1973
Chong, E (WOS:000328231500025) 2013; 15
VANLENTHE, E (WOS:A1994PV95600066) 1994; 101
Hamzaoui, B (WOS:000363507400020) 2015; 357
Dorfler, J (WOS:000334783300019) 2014; 2014
BUCHWALD, SL (WOS:A1988N407100027) 1988; 110
VANLENTHE, E (WOS:A1993LX14300035) 1993; 99
SCHAFER, A (WOS:A1992JJ41100041) 1992; 97
Herzon, SB (WOS:000260682300019) 2008; 130
Schmitt, DC (WOS:000320199000029) 2013; 49
BUCHWALD, SL (WOS:A1988Q914800012) 1988; 7
Schreckenbach, G (WOS:A1997WG25000003) 1997; 61
Schreckenbach, G (WOS:A1996VJ82600004) 1996; 60
Chong, E (WOS:000340079800020) 2014; 136
MAYER, JM (WOS:A1983QN29200023) 1983; 105
Garcia, P. (000370452300021.32) 2013; 125
Lauzon, JMP (WOS:000308655800001) 2012; 41
Basset, J. M. (000370452300021.4) 1993; 39
Herzon, SB (WOS:000246686700014) 2007; 129
COLES, N (WOS:A1990DN41400013) 1990
SCHAFER, A (WOS:A1994NF08100043) 1994; 100
Adamo, C (WOS:000079419000010) 1999; 110
Chen, TY (WOS:000349575800020) 2015; 137
Dorfler, J (WOS:000314650600038) 2013; 52
Chen, Y (WOS:000320298800032) 2013; 3
COLES, N (WOS:A1992HE28000017) 1992
te Velde, G (WOS:000168441600004) 2001; 22
HARRIS, MCJ (WOS:A1995RC87400037) 1995; 36
Chen, JX (WOS:000176173700048) 2002; 67
Perdew, JP (WOS:A1996VP22500044) 1996; 77
Dorfler, J. (000370452300021.27) 2014; 126
Grimme, S (WOS:000288871100026) 2011; 32
BUCHWALD, SL (WOS:A1989AB03100052) 1989; 111
Roesky, P. W. (000370452300021.56) 2009; 121
Dorfler, J. (000370452300021.24) 2013; 125
D'Elia, V (WOS:000357062000039) 2015; 137
Hamzaoui, B (WOS:000350763600019) 2015; 21
GATELY, DA (WOS:A1995QD40600015) 1995; 117
Riache, N (WOS:000349943200004) 2015; 34
Roesky, PW (WOS:000267713800005) 2009; 48
Hamieh, A (WOS:000352464400017) 2015; 5
El Eter, M (WOS:000318028500008) 2013; 49
Prochnow, I. (000370452300021.52) 2011; 123
Beaudoin, M (WOS:000166493900003) 2001; 20
POLM, LH (WOS:A1986C159800008) 1986; 304
DAVIS, JM (WOS:A1994MY72600038) 1994; 35
Chen, Y (WOS:000348483400010) 2015; 137
DAVIS, JM (WOS:A1992JN76700053) 1992; 33
Prochnow, I (WOS:000292642600038) 2011; 50
Autschbach, J (WOS:000183592100028) 2003; 107
HOBERG, H (WOS:A1979GR50100010) 1979; 169
References_xml – reference: A. L. Reznichenko, K. C. Hultzsch, J. Am. Chem. Soc. 2012, 134, 3300-3311.
– reference: B. Hamzaoui, M. El Eter, E. Abou-Hamad, Y. Chen, J. D. A. Pelletier, J. M. Basset, Chem. Eur. J. 2015, 21, 4294-4299;
– reference: S. L. Buchwald, B. T. Watson, M. W. Wannamaker, J. C. Dewan, J Am Chem. Soc 1989, 111, 4486-4494.
– reference: L. W. Francisco, P. S. White, J. L. Templeton, Organometallics 1996, 15, 5127-5136;
– reference: M. Beaudoin, S. L. Scott, Organometallics 2001, 20, 237-239.
– reference: S. Grimme, S. Ehrlich, L. Goerigk, J. Comput. Chem. 2011, 32, 1456-1465.
– reference: G. Schreckenbach, T. Ziegler, J. Phys. Chem. 1995, 99, 606-611;
– reference: N. Coles, R. J. Whitby, J. Blagg, Synlett 1990, 271-272;
– reference: Angew. Chem. 2009, 121, 4988-4991;
– reference: J. M. Basset, S. L. Scott, L. Choplin, A. Leconte, M. Quignard, F. Santini, C. Theolier in Organometallic Chemistry as a Basis for Understanding Heterogeneous Catalysis, Vol. 39: Elementary Reaction Steps in Heterogeneous Catalysis (Eds.: R. W. Joyner and R. A. van Santen), Springer Science+Business Media, Dordrecht, 1993, pp. 39-49.
– reference: Angew. Chem. 2011, 123, 6525-6529;
– reference: Y. Chen, R. Credendino, E. Callens, M. Atiqullah, M. A. Al-Harthi, L. Cavallo, J.-M. Basset, ACS Catal. 2013, 3, 1360-1364;
– reference: V. D′Elia, H. Dong, A. J. Rossini, C. M. Widdifield, S. V. C. Vummaleti, Y. Minenkov, A. Poater, E. Abou-Hamad, J. D. A. Pelletier, L. Cavallo, L. Emsley, J.-M. Basset, J. Am. Chem. Soc. 2015, 137, 7728-7739;
– reference: J. A. Tunge, D. A. Gately, J. R. Norton, J. Am. Chem. Soc. 1999, 121, 4520-4521.
– reference: H. Hoberg, V. Gotz, C. Kruger, Y. H. Tsay, J. Organomet. Chem. 1979, 169, 209-217;
– reference: B. Werghi, A. Bendjeriou-Sedjerari, J. Sofack-Kreutzer, A. Jedidi, E. Abou-Hamad, L. Cavallo, J.-M. Basset, Chem. Sci. 2015, 6, 5456-5465;
– reference: E. Chong, J. W. Brandt, L. L. Schafer, J Am Chem. Soc 2014, 136, 10898-10901;
– reference: J. X. Chen, J. A. Tunge, J. R. Norton, J. Org. Chem. 2002, 67, 4366-4369;
– reference: G. F. Zi, F. R. Zhang, H. B. Song, Chem. Commun. 2010, 46, 6296-6298;
– reference: Y. Chen, E. Abou-hamad, A. Hamieh, B. Hamzaoui, L. Emsley, J. M. Basset, J. Am. Chem. Soc. 2015, 137, 588-591.
– reference: J. M. Davis, R. J. Whitby, A. Jaxachamiec, Tetrahedron Lett. 1994, 35, 1445-1448;
– reference: J. Dörfler, S. Doye, Eur J Org Chem. 2014, 2014, 2790-2797;
– reference: Angew. Chem. 2014, 126, 8052-8056;
– reference: J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865-3868.
– reference: E. Chong, L. L. Schafer, Org Lett. 2013, 15, 6002-6005;
– reference: P. Eisenberger, R. O. Ayinla, J. M. P. Lauzon, L. L. Schafer, Angew. Chem. Int. Ed. 2009, 48, 8361-8365;
– reference: P. W. Roesky, Angew. Chem. Int. Ed. 2009, 48, 4892-4894;
– reference: G. Schreckenbach, T. Ziegler, Int. J. Quantum Chem. 1997, 61, 899-918;
– reference: F. A. Pasha, L. Cavallo, J. M. Basset, ACS Catal. 2014, 4, 1868-1874.
– reference: W. A. Nugent, D. W. Ovenall, S. J. Holmes, Organometallics 1983, 2, 161-162;
– reference: Angew. Chem. 2013, 125, 9314-9318;
– reference: J. M. Mayer, C. J. Curtis, J. E. Bercaw, J Am Chem. Soc 1983, 105, 2651-2660.
– reference: J. A. Tunge, C. J. Czerwinski, D. A. Gately, J. R. Norton, Organometallics 2001, 20, 254-260;
– reference: L. H. Polm, G. Vankoten, C. J. Elsevier, K. Vrieze, B. F. K. Vansanten, C. H. Stam, J. Organomet. Chem. 1986, 304, 353-370;
– reference: J. M. Davis, R. J. Whitby, A. Jaxachamiec, Tetrahedron Lett. 1992, 33, 5655-5658;
– reference: E. van Lenthe, A. Ehlers, E.-J. Baerends, J. chem. phys. 1999, 110, 8943-8953;
– reference: S. L. Buchwald, R. B. Nielsen, J. Am. Chem. Soc. 1988, 110, 3171-3175;
– reference: J. Autschbach, S. Patchkovskii, B. Pritchard, J. Chem. Theory Comput. 2011, 7, 2175-2188;
– reference: E. van Lenthe, E.-J. Baerends, J. G. Snijders, J. chem. phys. 1993, 99, 4597-4610.
– reference: M. G. Clerici, F. Maspero, Synthesis 1980, 305-306;
– reference: N. Coles, M. C. J. Harris, R. J. Whitby, J. Blagg, Organometallics 1994, 13, 190-199;
– reference: N. Riache, A. Dery, E. Callens, A. Poater, M. Samantaray, R. Dey, J. Hong, K. Li, L. Cavallo, J.-M. Basset, Organometallics 2015, 34, 690-695.
– reference: N. Coles, R. J. Whitby, J. Blagg, Synlett 1992, 143-145.
– reference: A. L. Reznichenko, T. J. Emge, S. Audorsch, E. G. Klauber, K. C. Hultzsch, B. Schmidt, Organometallics 2011, 30, 921-924.
– reference: J. Browning, H. D. Empsall, M. Green, F. G. A. Stone, J. Chem. Soc. Dalton Trans. 1973, 381-387.
– reference: S. B. Herzon, J. F. Hartwig, J. Am. Chem. Soc. 2008, 130, 14940.
– reference: A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571-2577.
– reference: E. van Lenthe, E.-J. Baerends, J. G. Snijders, J. chem. phys. 1994, 101, 9783-9792;
– reference: R. B. Grossman, W. M. Davis, S. L. Buchwald, J. Am. Chem. Soc. 1991, 113, 2321-2322;
– reference: M. C. J. Harris, R. J. Whitby, J. Blagg, Tetrahedron Lett. 1995, 36, 4287-4290.
– reference: I. Prochnow, P. Zark, T. Muller, S. Doye, Angew. Chem. Int. Ed. 2011, 50, 6401-6405;
– reference: J. M. P. Lauzon, L. L. Schafer, Dalton Trans. 2012, 41, 11539-11550.
– reference: Angew. Chem. 2013, 125, 1851-1854.
– reference: C. Adamo, V. Barone, J. Chem. Phys. 1999, 110, 6158-6170.
– reference: A. Hamieh, Y. Chen, S. Abdel-Azeim, E. Abou-hamad, S. Goh, M. Samantaray, R. Dey, L. Cavallo, J. M. Basset, ACS Catal. 2015, 5, 2164-2171;
– reference: G. Te Velde, F. M. Bickelhaupt, E. J. Baerends, C. Fonseca Guerra, S. J. van Gisbergen, J. G. Snijders, T. Ziegler, J. Comput. Chem. 2001, 22, 931-967;
– reference: A. Schäfer, C. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 100, 5829-5835.
– reference: J. Dörfler, S. Doye, Angew. Chem. Int. Ed. 2013, 52, 1806-1809;
– reference: Angew. Chem. 2009, 121, 8511-8515;
– reference: T. Y. Chen, R. Tsutsumi, T. P. Montgomery, I. Volchkov, M. J. Krische, J. Am. Chem. Soc. 2015, 137, 1798-1801.
– reference: S. L. Buchwald, R. B. Nielsen, J. C. Dewan, Organometallics 1988, 7, 2324-2328.
– reference: P. Garcia, Y. Y. Lau, M. R. Perry, L. L. Schafer, Angew. Chem. Int. Ed. 2013, 52, 9144-9148;
– reference: M. El Eter, B. Hamzaoui, E. Abou-Hamad, J. D. A. Pelletier, J. M. Basset, Chem. Commun. 2013, 49, 4616-4618.
– reference: D. C. Schmitt, J. Lee, A. M. R. Dechert-Schmitt, E. Yamaguchi, M. J. Krische, Chem. Commun. 2013, 49, 6096-6098;
– reference: J. Autschbach, E. Zurek, J. Phys. Chem. A 2003, 107, 4967-4972.
– reference: D. A. Gately, J. R. Norton, P. A. Goodson, J. Am. Chem. Soc. 1995, 117, 986-996;
– reference: J. Dörfler, T. Preuss, A. Schischko, M. Schmidtmann, S. Doye, Angew. Chem. Int. Ed. 2014, 53, 7918-7922;
– reference: T. V. Lubben, K. Plossl, J. R. Norton, M. M. Miller, O. P. Anderson, Organometallics 1992, 11, 122-127;
– reference: B. Hamzaoui, J. D. A. Pelletier, M. El Eter, Y. Chen, E. Abou-Hamad, J.-M. Basset, Adv. Synth. Catal. 2015, 357, 3148-3154.
– reference: G. Schreckenbach, T. Ziegler, Int. J. Quantum Chem. 1996, 60, 753-766;
– reference: S. B. Herzon, J. F. Hartwig, J Am Chem. Soc 2007, 129, 6690;
– volume: 136
  start-page: 10898
  year: 2014
  end-page: 10901
  publication-title: J Am Chem. Soc
– volume: 110
  start-page: 6158
  year: 1999
  end-page: 6170
  publication-title: J. Chem. Phys.
– volume: 53 126
  start-page: 7918 8052
  year: 2014 2014
  end-page: 7922 8056
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 15
  start-page: 6002
  year: 2013
  end-page: 6005
  publication-title: Org Lett.
– volume: 48 121
  start-page: 8361 8511
  year: 2009 2009
  end-page: 8365 8515
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 99
  start-page: 606
  year: 1995
  end-page: 611
  publication-title: J. Phys. Chem.
– volume: 52 125
  start-page: 1806 1851
  year: 2013 2013
  end-page: 1809 1854
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 32
  start-page: 1456
  year: 2011
  end-page: 1465
  publication-title: J. Comput. Chem.
– volume: 49
  start-page: 6096
  year: 2013
  end-page: 6098
  publication-title: Chem. Commun.
– volume: 97
  start-page: 2571
  year: 1992
  end-page: 2577
  publication-title: J. Chem. Phys.
– volume: 33
  start-page: 5655
  year: 1992
  end-page: 5658
  publication-title: Tetrahedron Lett.
– volume: 52 125
  start-page: 9144 9314
  year: 2013 2013
  end-page: 9148 9318
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– start-page: 143
  year: 1992
  end-page: 145
  publication-title: Synlett
– volume: 99
  start-page: 4597
  year: 1993
  end-page: 4610
  publication-title: J. chem. phys.
– volume: 113
  start-page: 2321
  year: 1991
  end-page: 2322
  publication-title: J. Am. Chem. Soc.
– start-page: 305
  year: 1980
  end-page: 306
  publication-title: Synthesis
– volume: 101
  start-page: 9783
  year: 1994
  end-page: 9792
  publication-title: J. chem. phys.
– start-page: 381
  year: 1973
  end-page: 387
  publication-title: J. Chem. Soc. Dalton Trans.
– volume: 137
  start-page: 1798
  year: 2015
  end-page: 1801
  publication-title: J. Am. Chem. Soc.
– volume: 21
  start-page: 4294
  year: 2015
  end-page: 4299
  publication-title: Chem. Eur. J.
– volume: 50 123
  start-page: 6401 6525
  year: 2011 2011
  end-page: 6405 6529
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 61
  start-page: 899
  year: 1997
  end-page: 918
  publication-title: Int. J. Quantum Chem.
– volume: 111
  start-page: 4486
  year: 1989
  end-page: 4494
  publication-title: J Am Chem. Soc
– volume: 49
  start-page: 4616
  year: 2013
  end-page: 4618
  publication-title: Chem. Commun.
– volume: 6
  start-page: 5456
  year: 2015
  end-page: 5465
  publication-title: Chem. Sci.
– volume: 36
  start-page: 4287
  year: 1995
  end-page: 4290
  publication-title: Tetrahedron Lett.
– start-page: 39
  year: 1993
  end-page: 49
– volume: 41
  start-page: 11539
  year: 2012
  end-page: 11550
  publication-title: Dalton Trans.
– volume: 105
  start-page: 2651
  year: 1983
  end-page: 2660
  publication-title: J Am Chem. Soc
– volume: 22
  start-page: 931
  year: 2001
  end-page: 967
  publication-title: J. Comput. Chem.
– volume: 169
  start-page: 209
  year: 1979
  end-page: 217
  publication-title: J. Organomet. Chem.
– volume: 15
  start-page: 5127
  year: 1996
  end-page: 5136
  publication-title: Organometallics
– volume: 46
  start-page: 6296
  year: 2010
  end-page: 6298
  publication-title: Chem. Commun.
– volume: 34
  start-page: 690
  year: 2015
  end-page: 695
  publication-title: Organometallics
– volume: 137
  start-page: 588
  year: 2015
  end-page: 591
  publication-title: J. Am. Chem. Soc.
– volume: 2014
  start-page: 2790
  year: 2014
  end-page: 2797
  publication-title: Eur J Org Chem.
– volume: 117
  start-page: 986
  year: 1995
  end-page: 996
  publication-title: J. Am. Chem. Soc.
– volume: 77
  start-page: 3865
  year: 1996
  end-page: 3868
  publication-title: Phys. Rev. Lett.
– start-page: 271
  year: 1990
  end-page: 272
  publication-title: Synlett
– volume: 60
  start-page: 753
  year: 1996
  end-page: 766
  publication-title: Int. J. Quantum Chem.
– volume: 4
  start-page: 1868
  year: 2014
  end-page: 1874
  publication-title: ACS Catal.
– volume: 304
  start-page: 353
  year: 1986
  end-page: 370
  publication-title: J. Organomet. Chem.
– volume: 100
  start-page: 5829
  year: 1994
  end-page: 5835
  publication-title: J. Chem. Phys.
– volume: 7
  start-page: 2324
  year: 1988
  end-page: 2328
  publication-title: Organometallics
– volume: 121
  start-page: 4520
  year: 1999
  end-page: 4521
  publication-title: J. Am. Chem. Soc.
– volume: 20
  start-page: 237
  year: 2001
  end-page: 239
  publication-title: Organometallics
– volume: 13
  start-page: 190
  year: 1994
  end-page: 199
  publication-title: Organometallics
– volume: 20
  start-page: 254
  year: 2001
  end-page: 260
  publication-title: Organometallics
– volume: 129
  start-page: 6690
  year: 2007
  publication-title: J Am Chem. Soc
– volume: 134
  start-page: 3300
  year: 2012
  end-page: 3311
  publication-title: J. Am. Chem. Soc.
– volume: 5
  start-page: 2164
  year: 2015
  end-page: 2171
  publication-title: ACS Catal.
– volume: 30
  start-page: 921
  year: 2011
  end-page: 924
  publication-title: Organometallics
– volume: 3
  start-page: 1360
  year: 2013
  end-page: 1364
  publication-title: ACS Catal.
– volume: 357
  start-page: 3148
  year: 2015
  end-page: 3154
  publication-title: Adv. Synth. Catal.
– volume: 137
  start-page: 7728
  year: 2015
  end-page: 7739
  publication-title: J. Am. Chem. Soc.
– volume: 67
  start-page: 4366
  year: 2002
  end-page: 4369
  publication-title: J. Org. Chem.
– volume: 110
  start-page: 3171
  year: 1988
  end-page: 3175
  publication-title: J. Am. Chem. Soc.
– volume: 2
  start-page: 161
  year: 1983
  end-page: 162
  publication-title: Organometallics
– volume: 48 121
  start-page: 4892 4988
  year: 2009 2009
  end-page: 4894 4991
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 7
  start-page: 2175
  year: 2011
  end-page: 2188
  publication-title: J. Chem. Theory Comput.
– volume: 35
  start-page: 1445
  year: 1994
  end-page: 1448
  publication-title: Tetrahedron Lett.
– volume: 11
  start-page: 122
  year: 1992
  end-page: 127
  publication-title: Organometallics
– volume: 130
  start-page: 14940
  year: 2008
  publication-title: J. Am. Chem. Soc.
– volume: 110
  start-page: 8943
  year: 1999
  end-page: 8953
  publication-title: J. chem. phys.
– volume: 107
  start-page: 4967
  year: 2003
  end-page: 4972
  publication-title: J. Phys. Chem. A
– ident: e_1_2_6_47_1
  doi: 10.1021/ja806367e
– ident: e_1_2_6_68_1
  doi: 10.1063/1.467146
– ident: e_1_2_6_7_3
  doi: 10.1002/ange.201206027
– ident: e_1_2_6_76_1
– ident: e_1_2_6_77_2
  doi: 10.1063/1.478813
– ident: e_1_2_6_1_1
  doi: 10.1039/c2dt30781b
– ident: e_1_2_6_9_2
  doi: 10.1021/ja0718366
– ident: e_1_2_6_71_2
  doi: 10.1002/(SICI)1097-461X(1997)61:6<899::AID-QUA3>3.0.CO;2-R
– ident: e_1_2_6_40_2
  doi: 10.1021/ja211945m
– ident: e_1_2_6_63_1
– ident: e_1_2_6_55_1
  doi: 10.1021/ja00194a052
– ident: e_1_2_6_58_2
  doi: 10.1021/cs400349p
– ident: e_1_2_6_78_2
  doi: 10.1063/1.467943
– ident: e_1_2_6_11_2
  doi: 10.1021/ja506187m
– ident: e_1_2_6_25_2
  doi: 10.1021/jo010940h
– ident: e_1_2_6_64_1
  doi: 10.1103/PhysRevLett.77.3865
– ident: e_1_2_6_10_3
  doi: 10.1002/ange.200900735
– ident: e_1_2_6_32_2
  doi: 10.1016/S0040-4039(00)61172-3
– ident: e_1_2_6_79_2
  doi: 10.1063/1.466059
– ident: e_1_2_6_69_1
– ident: e_1_2_6_34_2
  doi: 10.1016/0040-4039(95)00741-T
– ident: e_1_2_6_59_2
  doi: 10.1039/C5SC02276B
– ident: e_1_2_6_15_2
  doi: 10.1039/c0cc01265c
– ident: e_1_2_6_42_2
  doi: 10.1021/om9606496
– ident: e_1_2_6_3_2
  doi: 10.1055/s-1980-29002
– ident: e_1_2_6_65_1
  doi: 10.1063/1.463096
– ident: e_1_2_6_36_2
  doi: 10.1055/s-1990-21061
– ident: e_1_2_6_45_2
  doi: 10.1039/dt9730000381
– ident: e_1_2_6_46_1
  doi: 10.1021/ja00347a023
– ident: e_1_2_6_70_2
  doi: 10.1002/jcc.1056
– ident: e_1_2_6_50_1
– ident: e_1_2_6_37_2
  doi: 10.1055/s-1992-21993
– ident: e_1_2_6_18_2
  doi: 10.1039/c3cc43463j
– ident: e_1_2_6_74_2
  doi: 10.1021/ct200143w
– ident: e_1_2_6_13_2
  doi: 10.1002/anie.201304153
– ident: e_1_2_6_31_2
  doi: 10.1021/om00013a031
– ident: e_1_2_6_16_2
  doi: 10.1021/om1011006
– ident: e_1_2_6_66_1
  doi: 10.1063/1.478522
– ident: e_1_2_6_51_2
  doi: 10.1002/chem.201405788
– ident: e_1_2_6_10_2
  doi: 10.1002/anie.200900735
– ident: e_1_2_6_20_1
– ident: e_1_2_6_22_2
  doi: 10.1021/ja00218a027
– ident: e_1_2_6_6_2
  doi: 10.1021/ol402890m
– ident: e_1_2_6_33_2
  doi: 10.1016/S0040-4039(00)76242-3
– ident: e_1_2_6_49_1
  doi: 10.1021/ja5113468
– ident: e_1_2_6_72_2
  doi: 10.1002/(SICI)1097-461X(1996)60:3<753::AID-QUA4>3.0.CO;2-W
– ident: e_1_2_6_39_3
  doi: 10.1002/ange.201101239
– ident: e_1_2_6_53_1
  doi: 10.1002/adsc.201500484
– ident: e_1_2_6_54_1
  doi: 10.1021/om000915m
– ident: e_1_2_6_23_2
  doi: 10.1021/om00101a012
– ident: e_1_2_6_62_2
  doi: 10.1021/om500684e
– ident: e_1_2_6_48_1
  doi: 10.1007/978-94-011-1693-0_3
– ident: e_1_2_6_14_2
  doi: 10.1002/ejoc.201400082
– ident: e_1_2_6_26_2
  doi: 10.1021/ja00108a015
– ident: e_1_2_6_52_2
  doi: 10.1039/c3cc40385h
– ident: e_1_2_6_5_2
  doi: 10.1002/anie.201403203
– ident: e_1_2_6_12_3
  doi: 10.1002/ange.200903656
– ident: e_1_2_6_13_3
  doi: 10.1002/ange.201304153
– ident: e_1_2_6_17_1
– ident: e_1_2_6_29_2
  doi: 10.1021/ja984061x
– ident: e_1_2_6_56_1
  doi: 10.1021/cs5001703
– ident: e_1_2_6_41_1
– ident: e_1_2_6_43_2
  doi: 10.1016/0022-328X(86)80154-1
– ident: e_1_2_6_67_1
  doi: 10.1002/jcc.21759
– ident: e_1_2_6_2_1
– ident: e_1_2_6_30_1
– ident: e_1_2_6_7_2
  doi: 10.1002/anie.201206027
– ident: e_1_2_6_24_1
– ident: e_1_2_6_61_2
  doi: 10.1021/cs5020749
– ident: e_1_2_6_73_2
  doi: 10.1021/j100002a024
– ident: e_1_2_6_39_2
  doi: 10.1002/anie.201101239
– ident: e_1_2_6_8_1
– ident: e_1_2_6_28_2
  doi: 10.1021/om000768s
– ident: e_1_2_6_19_2
  doi: 10.1021/ja5130258
– ident: e_1_2_6_38_1
– ident: e_1_2_6_35_1
– ident: e_1_2_6_57_1
– ident: e_1_2_6_75_2
  doi: 10.1021/jp0346559
– ident: e_1_2_6_21_2
  doi: 10.1021/ja00006a071
– ident: e_1_2_6_60_2
  doi: 10.1021/jacs.5b02872
– ident: e_1_2_6_12_2
  doi: 10.1002/anie.200903656
– ident: e_1_2_6_5_3
  doi: 10.1002/ange.201403203
– ident: e_1_2_6_44_2
  doi: 10.1016/S0022-328X(00)81160-2
– ident: e_1_2_6_4_2
  doi: 10.1021/om00073a031
– ident: e_1_2_6_27_2
  doi: 10.1021/om00037a027
– volume: 121
  start-page: 8511
  year: 2009
  ident: 000370452300021.29
  publication-title: Angew. Chem.
– volume: 61
  start-page: 899
  year: 1997
  ident: WOS:A1997WG25000003
  article-title: Calculation of NMR shielding tensors based on density functional theory and a scalar relativistic Pauli-type Hamiltonian. The application to transition metal complexes
  publication-title: INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
– start-page: 271
  year: 1990
  ident: WOS:A1990DN41400013
  article-title: ELABORATION OF 1,2,3,4-TETRAHYDROQUINOLINE VIA ETA-2-IMINE COMPLEXES OF ZIRCONOCENE
  publication-title: SYNLETT
– volume: 33
  start-page: 5655
  year: 1992
  ident: WOS:A1992JN76700053
  article-title: FORMATION OF ZIRCONOCENE ETA-2-IMINE COMPLEXES BY REARRANGEMENT OF CYCLIC IMINOACYL COMPLEXES
  publication-title: TETRAHEDRON LETTERS
– volume: 50
  start-page: 6401
  year: 2011
  ident: WOS:000292642600038
  article-title: The Mechanism of the Titanium-Catalyzed Hydroaminoalkylation of Alkenes
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201101239
– volume: 15
  start-page: 6002
  year: 2013
  ident: WOS:000328231500025
  article-title: 2-Pyridonate Titanium Complexes for Chemoselectivity. Accessing Intramolecular Hydroaminoalkylation over Hydroamination
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol402890m
– volume: 111
  start-page: 4486
  year: 1989
  ident: WOS:A1989AB03100052
  article-title: ZIRCONOCENE COMPLEXES OF IMINES - GENERAL-SYNTHESIS, STRUCTURE, REACTIVITY, AND INSITU GENERATION TO PREPARE GEOMETRICALLY PURE ALLYLIC AMINES
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 137
  start-page: 1798
  year: 2015
  ident: WOS:000349575800020
  article-title: Ruthenium-Catalyzed C-C Coupling of Amino Alcohols with Dienes via Transfer Hydrogenation: Redox-Triggered Imine Addition and Related Hydroaminoalkylations
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja5130258
– volume: 99
  start-page: 4597
  year: 1993
  ident: WOS:A1993LX14300035
  article-title: RELATIVISTIC REGULAR 2-COMPONENT HAMILTONIANS
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 20
  start-page: 254
  year: 2001
  ident: WOS:000166493900005
  article-title: Mechanism of insertion of carbodiimides into the Zr-C bonds of zirconaaziridines. Formation of alpha-amino amidines
  publication-title: ORGANOMETALLICS
– volume: 137
  start-page: 588
  year: 2015
  ident: WOS:000348483400010
  article-title: Alkane Metathesis with the Tantalum Methylidene [( SiO)Ta(=CH2)Me-2]/[( SiO)(2)Ta(=CH2)Me] Generated from Well-Defined Surface Organometallic Complex [( SiO)(TaMe4)-Me-V]
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja5113468
– volume: 126
  start-page: 8052
  year: 2014
  ident: 000370452300021.27
  publication-title: Angew. Chem.
– volume: 11
  start-page: 122
  year: 1992
  ident: WOS:A1992GZ04000027
  article-title: SYNTHESIS AND STRUCTURE OF 2 ORGANOZIRCONOCENES WITH ALPHA NITROGEN SUBSTITUENTS
  publication-title: ORGANOMETALLICS
– volume: 304
  start-page: 353
  year: 1986
  ident: WOS:A1986C159800008
  article-title: IRON AND RUTHENIUM COMPLEXES [M2(CO)6(PYRIDINE-2-CARBALDEHYDE-IMINE)] HAVING A SIGMA-N,MU-2-N',ETA-2-C=N'BONDED 6-R-1-PY-2-C(R-2)=NR LIGAND - X-RAY STRUCTURE OF [RU-2(CO)5(1,2-BIS(MU-ISOPROPYLAMIDO)-1,2-BIS(2-PYRIDYL)ETHANE)] CONTAINING 2 C-C LINKED PYRIDINE-2-CARBALDEHYDE-IMINE LIGANDS
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 6
  start-page: 5456
  year: 2015
  ident: WOS:000361212000013
  article-title: Well-defined silica supported aluminum hydride: another step towards the utopian single site dream?
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c5sc02276b
– volume: 53
  start-page: 7918
  year: 2014
  ident: WOS:000339562400043
  article-title: A 2,6-Bis(phenylamino)pyridinato Titanium Catalyst for the Highly Regioselective Hydroaminoalkylation of Styrenes and 1,3-Butadienes
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201403203
– volume: 121
  start-page: 4988
  year: 2009
  ident: 000370452300021.56
  publication-title: Angew. Chem.
– volume: 7
  start-page: 2175
  year: 2011
  ident: WOS:000292617900018
  article-title: Calculation of Hyperfine Tensors and Paramagnetic NMR Shifts Using the Relativistic Zeroth-Order Regular Approximation and Density Functional Theory
  publication-title: JOURNAL OF CHEMICAL THEORY AND COMPUTATION
  doi: 10.1021/ct200143w
– volume: 169
  start-page: 209
  year: 1979
  ident: WOS:A1979GR50100010
  article-title: PREPARATION, PROPERTIES AND BOND RATIOS OF BENZOPHENON IMINO-NICKEL(0) COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– start-page: 381
  year: 1973
  ident: WOS:A1973P453800007
  article-title: REACTIONS OF LOW-VALENT METAL-COMPLEXES WITH FLUOROCARBONS .25. PHOSPHINE, PHOSPHITE AND CYCLO-OCTA-1,5-DIENE PLATINUM COMPLEXES
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
– volume: 130
  start-page: 14940
  year: 2008
  ident: WOS:000260682300019
  article-title: Hydroaminoalkylation of Unactivated Olefins with Dialkylamines
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja806367e
– volume: 5
  start-page: 2164
  year: 2015
  ident: WOS:000352464400017
  article-title: Well-Defined Surface Species [( Si-O)W(=O)Me-3) Prepared by Direct Methylation of [( Si-O-)W(=O)Cl-3), a Catalyst for Cycloalkane Metathesis and Transformation of Ethylene to Propylene
  publication-title: ACS CATALYSIS
  doi: 10.1021/cs5020749
– volume: 129
  start-page: 6690
  year: 2007
  ident: WOS:000246686700014
  article-title: Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja0718366
– volume: 4
  start-page: 1868
  year: 2014
  ident: WOS:000337074700027
  article-title: Mechanism of n-Butane Hydrogenolysis Promoted by Ta-Hydrides Supported on Silica
  publication-title: ACS CATALYSIS
  doi: 10.1021/cs5001703
– volume: 110
  start-page: 6158
  year: 1999
  ident: WOS:000079419000010
  article-title: Toward reliable density functional methods without adjustable parameters: The PBE0 model
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 100
  start-page: 5829
  year: 1994
  ident: WOS:A1994NF08100043
  article-title: FULLY OPTIMIZED CONTRACTED GAUSSIAN-BASIS SETS OF TRIPLE ZETA VALENCE QUALITY FOR ATOMS LI TO KR
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 36
  start-page: 4287
  year: 1995
  ident: WOS:A1995RC87400037
  article-title: CONVERGENT SYNTHESIS OF PYRROLIDINES, PIPERIDINES, PERHYDROAZEPINES AND TETRAHYDROISOQUINOLINES VIA ZIRCONOCENE ETA(2)-IMINE COMPLEXES
  publication-title: TETRAHEDRON LETTERS
– volume: 48
  start-page: 4892
  year: 2009
  ident: WOS:000267713800005
  article-title: Catalytic Hydroaminoalkylation
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200900735
– start-page: 305
  year: 1980
  ident: WOS:A1980JQ10300013
  article-title: CATALYTIC C-ALKYLATION OF SECONDARY-AMINES WITH ALKENES
  publication-title: SYNTHESIS-STUTTGART
– volume: 123
  start-page: 6525
  year: 2011
  ident: 000370452300021.52
  publication-title: Angew. Chem.
– volume: 52
  start-page: 1806
  year: 2013
  ident: WOS:000314650600038
  article-title: Aminopyridinato Titanium Catalysts for the Hydroaminoalkylation of Alkenes and Styrenes
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201206027
– volume: 2014
  start-page: 2790
  year: 2014
  ident: WOS:000334783300019
  article-title: A Commercially Available Tantalum Catalyst for the Highly Regioselective Intermolecular Hydroaminoalkylation of Styrenes
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1002/ejoc.201400082
– volume: 60
  start-page: 753
  year: 1996
  ident: WOS:A1996VJ82600004
  article-title: The calculation of NMR shielding tensors based on density functional theory and the frozen-core approximation
  publication-title: INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
– volume: 137
  start-page: 7728
  year: 2015
  ident: WOS:000357062000039
  article-title: Cooperative Effect of Monopodal Silica-Supported Niobium Complex Pairs Enhancing Catalytic Cyclic Carbonate Production
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/jacs.5b02872
– volume: 49
  start-page: 4616
  year: 2013
  ident: WOS:000318028500008
  article-title: Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c3cc40385h
– volume: 20
  start-page: 237
  year: 2001
  ident: WOS:000166493900003
  article-title: Spontaneous evolution of silica-supported Ti amide fragments to imine and imido complexes
  publication-title: ORGANOMETALLICS
– volume: 136
  start-page: 10898
  year: 2014
  ident: WOS:000340079800020
  article-title: 2-Pyridonate Tantalum Complexes for the Intermolecular Hydroaminoalkylation of Sterically Demanding Alkenes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja506187m
– volume: 21
  start-page: 4294
  year: 2015
  ident: WOS:000350763600019
  article-title: Well-Defined Single-Site Monohydride Silica-Supported Zirconium from Azazirconacyclopropane
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201405788
– volume: 117
  start-page: 986
  year: 1995
  ident: WOS:A1995QD40600015
  article-title: INSERTION OF ISOCYANATES, CO2, AND ETHYLENE CARBONATE INTO THE ZR-C AND ZR-N BONDS OF IMINE COMPLEXES - CONSTRUCTION OF CHIRAL CENTERS LIKE THOSE IN ALPHA-AMINO-ACIDS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 7
  start-page: 2324
  year: 1988
  ident: WOS:A1988Q914800012
  article-title: SYNTHESIS, STRUCTURE, AND REACTIONS OF (1-ETHOXYETHYL)ZIRCONOCENE CHLORIDE, A STABLE ACYCLIC SECONDARY ZIRCONOCENE ALKYL
  publication-title: ORGANOMETALLICS
– volume: 110
  start-page: 3171
  year: 1988
  ident: WOS:A1988N407100027
  article-title: KINETICS AND SUBSTITUENT EFFECTS IN THE FORMATION OF ZIRCONOCENE THIOALDEHYDE COMPLEXES - BETA-HYDRIDE ELIMINATION VERSUS CYCLOMETALATION
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 52
  start-page: 9144
  year: 2013
  ident: WOS:000323393100018
  article-title: Phosphoramidate Tantalum Complexes for Room-Temperature CH Functionalization: Hydroaminoalkylation Catalysis
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201304153
– volume: 110
  start-page: 8943
  year: 1999
  ident: WOS:000080073200011
  article-title: Geometry optimizations in the zero order regular approximation for relativistic effects
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 134
  start-page: 3300
  year: 2012
  ident: WOS:000301161500072
  article-title: The Mechanism of Hydroaminoalkylation Catalyzed by Group 5 Metal Binaphtholate Complexes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja211945m
– volume: 34
  start-page: 690
  year: 2015
  ident: WOS:000349943200004
  article-title: Silica-Supported Tungsten Carbynes ( SiO)(x)W( CH)(Me)(y) (x=1, y=2; x=2, y=1): New Efficient Catalysts for Alkyne Cyclotrimerization
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om500684e
– volume: 48
  start-page: 8361
  year: 2009
  ident: WOS:000271302900038
  article-title: Tantalum-Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200903656
– volume: 105
  start-page: 2651
  year: 1983
  ident: WOS:A1983QN29200023
  article-title: HYDROGEN-TRANSFER REACTIONS WHICH GENERATE NEW IMINE, IMIDO, AND TRIMETHYLENEMETHANE COMPLEXES OF TANTALUM
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– start-page: 143
  year: 1992
  ident: WOS:A1992HE28000017
  article-title: ALPHA-ALKYLATION OF ALPHA,ALPHA-DISUBSTITUTED AMINES VIA ETA-2-KETIMINE COMPLEXES OF ZIRCONOCENE
  publication-title: SYNLETT
– volume: 3
  start-page: 1360
  year: 2013
  ident: WOS:000320298800032
  article-title: Understanding Tantalum-Catalyzed Ethylene Trimerization: When Things Go Wrong
  publication-title: ACS CATALYSIS
  doi: 10.1021/cs400349p
– volume: 39
  start-page: 39
  year: 1993
  ident: 000370452300021.4
  publication-title: Organometallic Chemistry as a Basis for Understanding Heterogeneous Catalysis, Vol. 39: Elementary Reaction Steps in Heterogeneous Catalysis
– volume: 32
  start-page: 1456
  year: 2011
  ident: WOS:000288871100026
  article-title: Effect of the Damping Function in Dispersion Corrected Density Functional Theory
  publication-title: JOURNAL OF COMPUTATIONAL CHEMISTRY
  doi: 10.1002/jcc.21759
– volume: 35
  start-page: 1445
  year: 1994
  ident: WOS:A1994MY72600038
  article-title: SYNTHESIS OF CYCLOPENTYLAMINES USING ZIRCONIUM CHEMISTRY
  publication-title: TETRAHEDRON LETTERS
– volume: 41
  start-page: 11539
  year: 2012
  ident: WOS:000308655800001
  article-title: Tantallaaziridines: from synthesis to catalytic applications
  publication-title: DALTON TRANSACTIONS
  doi: 10.1039/c2dt30781b
– volume: 99
  start-page: 606
  year: 1995
  ident: WOS:A1995QB56800024
  article-title: CALCULATION OF NMR SHIELDING TENSORS USING GAUGE-INCLUDING ATOMIC ORBITALS AND MODERN DENSITY-FUNCTIONAL THEORY
  publication-title: JOURNAL OF PHYSICAL CHEMISTRY
– volume: 67
  start-page: 4366
  year: 2002
  ident: WOS:000176173700048
  article-title: Asymmetric synthesis of silylated alpha-amino acid esters through dynamic kinetic resolution
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo010940h
– volume: 113
  start-page: 2321
  year: 1991
  ident: WOS:A1991FB94000071
  article-title: ENANTIOSELECTIVE, ZIRCONIUM-MEDIATED SYNTHESIS OF ALLYLIC AMINES
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 49
  start-page: 6096
  year: 2013
  ident: WOS:000320199000029
  article-title: Ruthenium catalyzed hydroaminoalkylation of isoprene via transfer hydrogenation: byproduct-free prenylation of hydantoins
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c3cc43463j
– volume: 46
  start-page: 6296
  year: 2010
  ident: WOS:000281007400021
  article-title: Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c0cc01265c
– volume: 97
  start-page: 2571
  year: 1992
  ident: WOS:A1992JJ41100041
  article-title: FULLY OPTIMIZED CONTRACTED GAUSSIAN-BASIS SETS FOR ATOMS LI TO KR
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 125
  start-page: 9314
  year: 2013
  ident: 000370452300021.32
  publication-title: Angew. Chem.
– volume: 107
  start-page: 4967
  year: 2003
  ident: WOS:000183592100028
  article-title: Relativistic density-functional computations of the chemical shift of Xe-129 in Xe@C-60
  publication-title: JOURNAL OF PHYSICAL CHEMISTRY A
  doi: 10.1021/jp0346559
– volume: 22
  start-page: 931
  year: 2001
  ident: WOS:000168441600004
  article-title: Chemistry with ADF
  publication-title: JOURNAL OF COMPUTATIONAL CHEMISTRY
– volume: 30
  start-page: 921
  year: 2011
  ident: WOS:000287955800001
  article-title: Group 5 Metal Binaphtholate Complexes for Catalytic Asymmetric Hydroaminoalkylation and Hydroamination/Cyclization
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om1011006
– volume: 15
  start-page: 5127
  year: 1996
  ident: WOS:A1996VV37400010
  article-title: Chemistry surrounding chiral tungsten(II) eta(1)-imine complexes
  publication-title: ORGANOMETALLICS
– volume: 125
  start-page: 1851
  year: 2013
  ident: 000370452300021.24
  publication-title: Angew. Chem.
– volume: 77
  start-page: 3865
  year: 1996
  ident: WOS:A1996VP22500044
  article-title: Generalized gradient approximation made simple
  publication-title: PHYSICAL REVIEW LETTERS
– volume: 2
  start-page: 161
  year: 1983
  ident: WOS:A1983PZ13200031
  article-title: CATALYTIC C-H ACTIVATION IN EARLY TRANSITION-METAL DIALKYLAMIDES AND ALKOXIDES
  publication-title: ORGANOMETALLICS
– volume: 101
  start-page: 9783
  year: 1994
  ident: WOS:A1994PV95600066
  article-title: RELATIVISTIC TOTAL-ENERGY USING REGULAR APPROXIMATIONS
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 13
  start-page: 190
  year: 1994
  ident: WOS:A1994MR76800031
  article-title: STRUCTURE-REACTIVITY CORRELATIONS FOR THE FORMATION OF ZIRCONOCENE ETA-2-IMINE COMPLEXES FROM AMINES
  publication-title: ORGANOMETALLICS
– volume: 357
  start-page: 3148
  year: 2015
  ident: WOS:000363507400020
  article-title: Isolation and Characterization of Well-Defined Silica-Supported Azametallacyclopentane: A Key Intermediate in Catalytic Hydroaminoalkylation Reactions
  publication-title: ADVANCED SYNTHESIS & CATALYSIS
  doi: 10.1002/adsc.201500484
– volume: 121
  start-page: 4520
  year: 1999
  ident: WOS:000080550100028
  article-title: Asymmetric formation of alpha-amino acid esters through dynamic kinetic resolution: A cyclic carbonate as an optically active CO2 synthon
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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Snippet Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η2‐NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica‐supported...
Single‐site, well‐defined, silica‐supported tantallaaziridine intermediates [≡Si‐O‐Ta(η 2 ‐NRCH 2 )(NMe 2 ) 2 ] [R=Me ( 2 ), Ph ( 3 )] were prepared from...
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta((2)-NRCH2)(NMe2)(2)] [R=Me (2), Ph (3)] were prepared from...
Single-site, well-defined, silica-supported tantallaaziridine intermediates [≡Si-O-Ta(η(2) -NRCH2 )(NMe2 )2 ] [R=Me (2), Ph (3)] were prepared from...
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta(η2-NRCH2)(NMe2)2] [R=Me (2), Ph (3)] were prepared from silica-supported...
Single-site, well-defined, silica-supported tantallaaziridine intermediates [Si-O-Ta( eta super(2)-NRCH sub(2))(NMe sub(2)) sub(2)] [R=Me (2), Ph (3)] were...
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SubjectTerms Activation
Alkenes
Amines
Aromatic compounds
Catalysis
Catalysts
Chemical synthesis
Chemistry
Chemistry, Multidisciplinary
Formations
Fourier transforms
hydroamination
Infrared spectroscopy
Intermediates
Magnetic resonance spectroscopy
Mathematical analysis
metallacycles
NMR
NMR spectroscopy
Nuclear magnetic resonance
Physical Sciences
Science & Technology
Silica
Silicon dioxide
solid-state NMR spectroscopy
Spectroscopic analysis
Spectroscopy
Spectrum analysis
Substrates
supported catalysts
Tantalum
Title Solid-State NMR and DFT Studies on the Formation of Well-Defined Silica-Supported Tantallaaziridines: From Synthesis to Catalytic Application
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