In situ atomic-scale imaging of the metal/oxide interfacial transformation
Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu 2 O/Cu interfaces via the oxidation of Cu, and subsequently probe the...
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| Published in | Nature communications Vol. 8; no. 1; pp. 307 - 8 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
21.08.2017
Nature Publishing Group Nature Portfolio |
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| Abstract | Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu
2
O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H
2
gas environment. The Cu
2
O→Cu transformation is observed to occur initially along the Cu
2
O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu
2
O/Cu interface drives the collapse of the Cu
2
O lattice near the interface region, which results in a tilted Cu
2
O/Cu interface with concomitant Cu
2
O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase.
Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu
2
O/Cu interfaces as they undergo redox reactions. |
|---|---|
| AbstractList | Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu
2
O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H
2
gas environment. The Cu
2
O→Cu transformation is observed to occur initially along the Cu
2
O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu
2
O/Cu interface drives the collapse of the Cu
2
O lattice near the interface region, which results in a tilted Cu
2
O/Cu interface with concomitant Cu
2
O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase.
Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu
2
O/Cu interfaces as they undergo redox reactions. Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature.Using environmental transmission electron microscopy,here we report observations of the in-place formation of Cu2O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H2 gas environment. The Cu2O→Cu transformation is observed to occur initially along the Cu2O/Cu interface in a layer-by-layer manner.The accumulation of oxygen vacancies at the Cu2O/Cu interface drives the collapse of the Cu2O lattice near the interface region, which results in a tilted Cu2O/Cu interface with concomitant Cu2O island rotation. Lastly, these results provide unprecedented microscopic detail regarding the redox reactions of supported oxides,which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase. Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu2O/Cu interfaces as they undergo redox reactions. Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu2O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H2 gas environment. The Cu2O→Cu transformation is observed to occur initially along the Cu2O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu2O/Cu interface drives the collapse of the Cu2O lattice near the interface region, which results in a tilted Cu2O/Cu interface with concomitant Cu2O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase. Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu 2 O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H 2 gas environment. The Cu 2 O→Cu transformation is observed to occur initially along the Cu 2 O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu 2 O/Cu interface drives the collapse of the Cu 2 O lattice near the interface region, which results in a tilted Cu 2 O/Cu interface with concomitant Cu 2 O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase. Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu2O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H2 gas environment. The Cu2O→Cu transformation is observed to occur initially along the Cu2O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu2O/Cu interface drives the collapse of the Cu2O lattice near the interface region, which results in a tilted Cu2O/Cu interface with concomitant Cu2O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase.Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu2O/Cu interfaces as they undergo redox reactions.Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu2O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H2 gas environment. The Cu2O→Cu transformation is observed to occur initially along the Cu2O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu2O/Cu interface drives the collapse of the Cu2O lattice near the interface region, which results in a tilted Cu2O/Cu interface with concomitant Cu2O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase.Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu2O/Cu interfaces as they undergo redox reactions. Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron microscopy, here we report observations of the in-place formation of Cu O/Cu interfaces via the oxidation of Cu, and subsequently probe the atomic mechanisms by which interfacial transformation and grain rotation occur at the interfaces during reduction in an H gas environment. The Cu O→Cu transformation is observed to occur initially along the Cu O/Cu interface in a layer-by-layer manner. The accumulation of oxygen vacancies at the Cu O/Cu interface drives the collapse of the Cu O lattice near the interface region, which results in a tilted Cu O/Cu interface with concomitant Cu O island rotation. These results provide unprecedented microscopic detail regarding the redox reactions of supported oxides, which differs fundamentally from the reduction of bulk or isolated oxides that requires the formation of new interfaces between the parent oxide and the reduced phase.Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the authors use environmental transmission electron microscopy to probe the atomic-level transformations at Cu O/Cu interfaces as they undergo redox reactions. |
| ArticleNumber | 307 |
| Author | Zakharov, Dmitri Zhou, Guangwen Zou, Lianfeng Li, Jonathan Stach, Eric A. |
| Author_xml | – sequence: 1 givenname: Lianfeng surname: Zou fullname: Zou, Lianfeng organization: Department of Mechanical Engineering & Materials Science and Engineering Program, State University of New York at Binghamton – sequence: 2 givenname: Jonathan surname: Li fullname: Li, Jonathan organization: Department of Physics, Applied Physics and Astronomy & Materials Science and Engineering Program, State University of New York – sequence: 3 givenname: Dmitri surname: Zakharov fullname: Zakharov, Dmitri organization: Center for Functional Nanomaterials, Brookhaven National Laboratory – sequence: 4 givenname: Eric A. orcidid: 0000-0002-3366-2153 surname: Stach fullname: Stach, Eric A. organization: Center for Functional Nanomaterials, Brookhaven National Laboratory – sequence: 5 givenname: Guangwen surname: Zhou fullname: Zhou, Guangwen email: gzhou@binghamton.edu organization: Department of Mechanical Engineering & Materials Science and Engineering Program, State University of New York at Binghamton |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28824169$$D View this record in MEDLINE/PubMed https://www.osti.gov/servlets/purl/1438307$$D View this record in Osti.gov |
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| Snippet | Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature. Using environmental transmission electron... Directly probing structure dynamics at metal/oxide interfaces has been a major challenge due to their buried nature.Using environmental transmission electron... Metal/oxide interfaces play an important role in heterogeneous catalysis and redox reactions, but their buried nature makes them difficult to study. Here, the... |
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| SubjectTerms | 639/301/119/544 639/301/357/537 639/301/357/551 639/301/930/328/2082 Catalysis Copper Copper oxides Cu oxidation Cu reduction DFT calculations Electron microscopy environmental transmission electron microscopy Evolution Humanities and Social Sciences Interfaces MATERIALS SCIENCE metal oxide interfaces Metal oxides Morphology multidisciplinary Redox reactions Scale (corrosion) Science Science (multidisciplinary) Thin films Transmission electron microscopy |
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| Title | In situ atomic-scale imaging of the metal/oxide interfacial transformation |
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