Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide

• Published in: Nature communications Vol. 8; no. 1; pp. 566 - 9
• Main Authors: Shadike, Zulipiya, Zhou, Yong-Ning, Chen, Lan-Li, Wu, Qu, Yue, Ji-Li, Zhang, Nian, Yang, Xiao-Qing, Gu, Lin, Liu, Xiao-Song, Shi, Si-Qi, Fu, Zheng-Wen
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 18.09.2017; Nature Publishing Group; Nature Portfolio
• Subjects: 639/4077/909; 639/638/161/891; Aquatic plants; Cations; Chromium; Chromium compounds; Design optimization; Electrochemistry; Electrodes; ENERGY STORAGE; Heavy metals; Humanities and Social Sciences; Intercalation; Intercalation compounds; Lattice vacancies; multidisciplinary; National Synchrotron Light Source; Oxidation; Redox reactions; Science; Science (multidisciplinary); Sodium; Stabilization; Sulfides; Sulfur; Transition metals

The intercalation compounds with various electrochemically active or inactive elements in the layered structure have been the subject of increasing interest due to their high capacities, good reversibility, simple structures, and ease of synthesis. However, their reversible intercalation/deintercala...