Electrocatalytic Hydrogen Generation by Ni-PN 3 P Pincer Complexes: Role of Phosphorus Substituents in Tuning the Reactivity

• Published in: Chemistry, an Asian journal Vol. 19; no. 23; p. e202400690
• Main Authors: Chatterjee, Sudipta, Dutta, Indranil, Dereli, Busra, Chakraborty, Priyanka, Peramaiah, Karthik, Gupta, Neha, Cavallo, Luigi, Huang, Kuo-Wei
• Format: Journal Article
• Language: English
• Published: Germany 02.12.2024
• Subjects: Cyclic voltammetry; Electrocatalysis; DFT; Pincer; Hydrogen evolution

Electrocatalytic hydrogen evolution reaction (eHER) is crucial in addressing the growing global energy demand. Although nickel-pincer-based molecular complexes, varying in donor atoms, were studied previously for eHER, the impact of variations in the substituents attached to the donor atoms was not...