Highly Effective Non-Noble MnO 2 Catalysts for 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid

Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal-based catalysts. The catalytic activity of six MnO crystal str...

Full description

Saved in:
Bibliographic Details
Published inChemSusChem Vol. 17; no. 14; p. e202400115
Main Authors Álvarez-Hernández, Débora, Megías-Sayago, Cristina, Penkova, Anna, Centeno, Miguel Ángel, Ivanova, Svetlana
Format Journal Article
LanguageEnglish
Published Germany 22.07.2024
Subjects
MnO2
crystal structure
2,5-furandicarboxylic acid
5-hydroxymethylfurfural oxidation
Online AccessGet full text

Cover

Abstract Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal-based catalysts. The catalytic activity of six MnO crystal structures is studied as alternative. The obtained results showed a strong connection between catalytic activity the type of MnO structure organization and redox behavior. Among all tested catalysts, ϵ-MnO showed the best performance with an excellent yield of 74 % of 2,5-furandicarboxylic acid at full -hydroxymethylfurfural conversion.
AbstractList Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal-based catalysts. The catalytic activity of six MnO crystal structures is studied as alternative. The obtained results showed a strong connection between catalytic activity the type of MnO structure organization and redox behavior. Among all tested catalysts, ϵ-MnO showed the best performance with an excellent yield of 74 % of 2,5-furandicarboxylic acid at full -hydroxymethylfurfural conversion.
Abstract Noble metal‐free catalyst or catalytic oxidation of 5‐hydroxymethylfurfural into 2,5‐furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal‐based catalysts. The catalytic activity of six MnO 2 crystal structures is studied as alternative. The obtained results showed a strong connection between catalytic activity the type of MnO 2 structure organization and redox behavior. Among all tested catalysts, ϵ‐MnO 2 showed the best performance with an excellent yield of 74 % of 2,5‐furandicarboxylic acid at full ‐hydroxymethylfurfural conversion.
Author Centeno, Miguel Ángel
Álvarez-Hernández, Débora
Megías-Sayago, Cristina
Ivanova, Svetlana
Penkova, Anna
Author_xml – sequence: 1
  givenname: Débora
  surname: Álvarez-Hernández
  fullname: Álvarez-Hernández, Débora
  organization: Department of Inorganic Chemistry and Materials Science Institute of Seville, CSIC-US, Universidad de Sevilla, Avda. Americo Vespucio 49, 41092, Sevilla, Spain
– sequence: 2
  givenname: Cristina
  surname: Megías-Sayago
  fullname: Megías-Sayago, Cristina
  organization: Department of Inorganic Chemistry and Instituto de Investigaciones Químicas/Centro de Innovación en Química Avanzada (ORFEO-CINQA), Institution Universidad de Sevilla, Avda. Americo Vespucio 49, 41092, Sevilla, Spain
– sequence: 3
  givenname: Anna
  surname: Penkova
  fullname: Penkova, Anna
  organization: Department of Inorganic Chemistry and Materials Science Institute of Seville, CSIC-US, Universidad de Sevilla, Avda. Americo Vespucio 49, 41092, Sevilla, Spain
– sequence: 4
  givenname: Miguel Ángel
  surname: Centeno
  fullname: Centeno, Miguel Ángel
  organization: Department of Inorganic Chemistry and Materials Science Institute of Seville, CSIC-US, Universidad de Sevilla, Avda. Americo Vespucio 49, 41092, Sevilla, Spain
– sequence: 5
  givenname: Svetlana
  orcidid: 0000-0003-4552-3289
  surname: Ivanova
  fullname: Ivanova, Svetlana
  organization: Department of Inorganic Chemistry and Materials Science Institute of Seville, CSIC-US, Universidad de Sevilla, Avda. Americo Vespucio 49, 41092, Sevilla, Spain
BackLink https://www.ncbi.nlm.nih.gov/pubmed/38442078$$D View this record in MEDLINE/PubMed
BookMark eNo9kEtrAjEUhUNpqY9222XJD-jYvJ0sRbQWrG5cdDfEJLemjBOZjMX59x2xFS7cy-WcA-cboNsqVh6hJ0pGlBD2alOyI0aYIIRSeYP6NFcik0p83l5vTntokNI3IYpope5Rj-dCMDLO-6hahK9d2eIZgLdN-PF4FatsFbelxx_VGjM8NY0p29QkDLHGMlu0ro6ndu-bXVvCse7GlHh9Cs40IVa4iZi9yGzevSsXrKm3nboMFk9scA_oDkyZ_OPfHqLNfLaZLrLl-u19OllmVrE8A6eZ5gK8zj0YQ7XkBBQQubVCyFzBmHMG0HVRjhIQemwYAyatcZpryfgQjS6xto4p1R6KQx32pm4LSoozt-LMrbhy6wzPF8PhuN17d5X_g-K_ZNxrXA
Cites_doi 10.1016/j.apcata.2014.03.020
10.1039/C9CY01968E
10.1016/j.apcata.2018.05.001
10.1002/cctc.201901742
10.1016/j.apcatb.2010.10.034
10.1021/ja1055615
10.1016/j.apcata.2016.01.005
10.1002/smll.202300394
10.1016/j.jcis.2021.02.030
10.1021/acscatal.7b01913
10.1007/s11144-014-0689-z
10.1039/D2NJ01207C
10.3390/nano7050117
10.1002/slct.201600797
10.1039/C9CY01298B
10.1016/j.est.2018.11.021
10.1021/jp0774995
10.1016/j.fuel.2020.118362
10.1002/cssc.201601443
10.1021/acssuschemeng.9b00010
10.1016/j.cattod.2018.04.024
10.1016/j.apsusc.2021.149905
10.1002/cssc.201900833
10.1021/acscatal.8b02522
10.1002/adma.202004862
10.1016/j.apcata.2012.05.016
10.1016/j.catcom.2013.12.031
10.1126/sciadv.1700782
10.1016/j.cattod.2010.03.010
10.1021/ie501098e
10.1039/c1gc15355b
10.1016/j.fuel.2022.124474
10.1039/C8GC02680G
10.1039/C6GC00438E
10.1016/j.apcatb.2019.118150
10.1021/cm00057a003
10.1016/S1872-2067(17)62922-X
10.1016/S1872-2067(17)62915-2
10.1116/11.20020401
10.3389/fchem.2020.00585
10.1016/j.apsusc.2021.150989
10.1002/jccs.201200193
10.1016/j.cattod.2020.10.037
10.1039/C7GC00027H
10.1016/j.jallcom.2018.02.260
10.1002/chem.202100478
ContentType Journal Article
Copyright 2024 Wiley-VCH GmbH.
Copyright_xml – notice: 2024 Wiley-VCH GmbH.
DBID NPM
AAYXX
CITATION
DOI 10.1002/cssc.202400115
DatabaseName PubMed
CrossRef
DatabaseTitle PubMed
CrossRef
DatabaseTitleList PubMed
CrossRef
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1864-564X
ExternalDocumentID 10_1002_cssc_202400115
38442078
Genre Journal Article
GrantInformation_xml – fundername: Spanish Ministerio de Ciencia e Innovación
  grantid: MCIN/AEI/10.13039/501100011033/
– fundername: FEDER Funds una manera de hacer Europa
  grantid: PID2020-113809RB-C32
GroupedDBID ---
05W
0R~
1OC
29B
33P
4.4
5GY
5VS
66C
77Q
8-1
A00
AAESR
AAHHS
AAIHA
AANLZ
AAXRX
AAZKR
ABCUV
ACAHQ
ACCFJ
ACCZN
ACGFS
ACIWK
ACPOU
ACXBN
ACXQS
ADKYN
ADOZA
ADXAS
ADZMN
ADZOD
AEEZP
AEIGN
AENEX
AEQDE
AEUYR
AFBPY
AFFPM
AFZJQ
AHBTC
AHMBA
AITYG
AIURR
AIWBW
AJBDE
ALMA_UNASSIGNED_HOLDINGS
ALUQN
AMYDB
AZVAB
BDRZF
BFHJK
BRXPI
CS3
DCZOG
DR2
DRFUL
DRSTM
DU5
EBS
F5P
G-S
HGLYW
HZ~
IX1
LATKE
LAW
LEEKS
LITHE
LOXES
LUTES
LYRES
MEWTI
MY~
NPM
O9-
OIG
P2W
P4E
PQQKQ
ROL
SUPJJ
W99
WBKPD
WOHZO
WXSBR
WYJ
XV2
ZZTAW
~S-
AAYXX
CITATION
ID FETCH-LOGICAL-c628-fd92934fe98efaa19530f6f05bc44586f7332ff9666d10f497a22f25cad939523
ISSN 1864-5631
IngestDate Wed Aug 28 12:34:29 EDT 2024
Sat Nov 02 12:29:58 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 14
Keywords MnO2
crystal structure
2,5-furandicarboxylic acid
5-hydroxymethylfurfural oxidation
Language English
License 2024 Wiley-VCH GmbH.
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c628-fd92934fe98efaa19530f6f05bc44586f7332ff9666d10f497a22f25cad939523
ORCID 0000-0003-4552-3289
PMID 38442078
ParticipantIDs crossref_primary_10_1002_cssc_202400115
pubmed_primary_38442078
PublicationCentury 2000
PublicationDate 2024-Jul-22
2024-07-22
PublicationDateYYYYMMDD 2024-07-22
PublicationDate_xml – month: 07
  year: 2024
  text: 2024-Jul-22
  day: 22
PublicationDecade 2020
PublicationPlace Germany
PublicationPlace_xml – name: Germany
PublicationTitle ChemSusChem
PublicationTitleAlternate ChemSusChem
PublicationYear 2024
References e_1_2_8_28_1
e_1_2_8_24_1
e_1_2_8_47_1
e_1_2_8_26_1
e_1_2_8_49_1
e_1_2_8_3_1
e_1_2_8_5_1
e_1_2_8_7_1
e_1_2_8_9_1
e_1_2_8_20_1
e_1_2_8_43_1
e_1_2_8_22_1
e_1_2_8_45_1
e_1_2_8_1_1
e_1_2_8_17_1
e_1_2_8_19_1
e_1_2_8_13_1
e_1_2_8_36_1
e_1_2_8_15_1
e_1_2_8_38_1
Hayashi E. (e_1_2_8_41_1) 2019; 141
e_1_2_8_32_1
e_1_2_8_11_1
e_1_2_8_34_1
e_1_2_8_30_1
e_1_2_8_29_1
e_1_2_8_25_1
e_1_2_8_46_1
e_1_2_8_27_1
e_1_2_8_48_1
e_1_2_8_2_1
e_1_2_8_4_1
e_1_2_8_6_1
e_1_2_8_8_1
e_1_2_8_21_1
e_1_2_8_42_1
e_1_2_8_23_1
e_1_2_8_44_1
e_1_2_8_40_1
e_1_2_8_18_1
e_1_2_8_39_1
e_1_2_8_14_1
e_1_2_8_35_1
e_1_2_8_16_1
e_1_2_8_37_1
e_1_2_8_10_1
e_1_2_8_31_1
e_1_2_8_12_1
e_1_2_8_33_1
e_1_2_8_50_1
References_xml – ident: e_1_2_8_7_1
  doi: 10.1016/j.apcata.2014.03.020
– ident: e_1_2_8_35_1
  doi: 10.1039/C9CY01968E
– ident: e_1_2_8_45_1
  doi: 10.1016/j.apcata.2018.05.001
– ident: e_1_2_8_9_1
  doi: 10.1002/cctc.201901742
– ident: e_1_2_8_3_1
– ident: e_1_2_8_30_1
  doi: 10.1016/j.apcatb.2010.10.034
– ident: e_1_2_8_28_1
  doi: 10.1021/ja1055615
– ident: e_1_2_8_31_1
  doi: 10.1016/j.apcata.2016.01.005
– ident: e_1_2_8_32_1
  doi: 10.1002/smll.202300394
– ident: e_1_2_8_17_1
  doi: 10.1016/j.jcis.2021.02.030
– ident: e_1_2_8_46_1
  doi: 10.1021/acscatal.7b01913
– ident: e_1_2_8_12_1
  doi: 10.1007/s11144-014-0689-z
– ident: e_1_2_8_11_1
  doi: 10.1016/j.apcata.2014.03.020
– ident: e_1_2_8_10_1
  doi: 10.1039/D2NJ01207C
– ident: e_1_2_8_21_1
  doi: 10.3390/nano7050117
– ident: e_1_2_8_42_1
  doi: 10.1002/slct.201600797
– ident: e_1_2_8_16_1
  doi: 10.1039/C9CY01298B
– ident: e_1_2_8_19_1
  doi: 10.1016/j.est.2018.11.021
– ident: e_1_2_8_25_1
  doi: 10.1021/jp0774995
– ident: e_1_2_8_15_1
  doi: 10.1016/j.fuel.2020.118362
– ident: e_1_2_8_18_1
  doi: 10.1002/cssc.201601443
– ident: e_1_2_8_40_1
  doi: 10.1021/acssuschemeng.9b00010
– ident: e_1_2_8_14_1
  doi: 10.1016/j.cattod.2018.04.024
– ident: e_1_2_8_37_1
  doi: 10.1016/j.apsusc.2021.149905
– ident: e_1_2_8_6_1
  doi: 10.1002/cssc.201900833
– ident: e_1_2_8_50_1
  doi: 10.1021/acscatal.8b02522
– ident: e_1_2_8_23_1
  doi: 10.1002/adma.202004862
– ident: e_1_2_8_24_1
  doi: 10.1016/j.apcata.2012.05.016
– ident: e_1_2_8_1_1
– ident: e_1_2_8_47_1
  doi: 10.1016/j.catcom.2013.12.031
– ident: e_1_2_8_2_1
  doi: 10.1126/sciadv.1700782
– ident: e_1_2_8_49_1
  doi: 10.1016/j.cattod.2010.03.010
– ident: e_1_2_8_38_1
  doi: 10.1021/ie501098e
– ident: e_1_2_8_29_1
  doi: 10.1039/c1gc15355b
– ident: e_1_2_8_8_1
  doi: 10.1016/j.fuel.2022.124474
– volume: 141
  start-page: 899
  year: 2019
  ident: e_1_2_8_41_1
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Hayashi E.
– ident: e_1_2_8_5_1
  doi: 10.1039/C8GC02680G
– ident: e_1_2_8_36_1
  doi: 10.1039/C6GC00438E
– ident: e_1_2_8_48_1
  doi: 10.1016/j.apcatb.2019.118150
– ident: e_1_2_8_26_1
  doi: 10.1021/cm00057a003
– ident: e_1_2_8_44_1
  doi: 10.1016/S1872-2067(17)62922-X
– ident: e_1_2_8_22_1
  doi: 10.1016/S1872-2067(17)62915-2
– ident: e_1_2_8_39_1
  doi: 10.1116/11.20020401
– ident: e_1_2_8_4_1
  doi: 10.3389/fchem.2020.00585
– ident: e_1_2_8_33_1
  doi: 10.1016/j.apsusc.2021.150989
– ident: e_1_2_8_27_1
  doi: 10.1002/jccs.201200193
– ident: e_1_2_8_43_1
  doi: 10.1016/j.cattod.2020.10.037
– ident: e_1_2_8_13_1
  doi: 10.1039/C7GC00027H
– ident: e_1_2_8_20_1
  doi: 10.1016/j.jallcom.2018.02.260
– ident: e_1_2_8_34_1
  doi: 10.1002/chem.202100478
SSID ssj0060966
Score 2.468423
Snippet Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve...
Abstract Noble metal‐free catalyst or catalytic oxidation of 5‐hydroxymethylfurfural into 2,5‐furandicarboxylic acid are proposed in this study as a proposal...
SourceID crossref
pubmed
SourceType Aggregation Database
Index Database
StartPage e202400115
Title Highly Effective Non-Noble MnO 2 Catalysts for 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid
URI https://www.ncbi.nlm.nih.gov/pubmed/38442078
Volume 17
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3da9swEBdZB1tfxr7XfaGHwR48dbYsyfZjaVfCICmsGfQtKLYUQjOlJE5Z-u_sH92dVDvJSGHbix0kxTZ3P06n0-l3hHyAOdjaysLaRGWcCZ5UTMPEzTIleVaqslA5Hk7u9VX3u_h6IS86nV8bWUvLenRY3uw8V_I_WoU20Cuekv0HzbYPhQb4DfqFK2gYrn-lY0zSmK6iwECMKUD9mWN9rBAT9dxZxPF8H3KO1J50IZKsu6owbQXLRq-mdjm3nnTj7OckVFZCR5SD0CU7hQ6HWzjzEYxHIuyjcrJV0xOZBs6XC7w1SsNN9zyZXuu5uWFdM3d-Fz5potQnYVMeQdeq2Yx944lesHO90uMQuPWGx-m12XaXs-sQAHbrZgxMG185POpNxkszjcIHNGm6TTCDC4yShnPJhyYY4FwJJlXI2mwtdLaJRLFhbw0-xLu1O6eDQC9bLhZIVrljIKjz6ocHR5oLweNQTegPAu6m6x65z8Ga-VyAby1HmYI1oGrYQGP-eftl--RB8_ctx2drCeNdmcFj8uh2DUKPAqCekI5xT8nD46b03zPiArBoCyzaAosCsCinLbAoAIveASzaAovWM8o_7YAVRVg9J4PTL4PjLrstzMFKxXNmK_CpU2FNkRurNW7ExlbZWI5KIWSubJam3FqQi6qS2Ioi05xbLktdFWkhefqC7LmZM68IFTrPk6zKEmNLIWOupa7AZa5gnTuqElsckI-N0IZXgX5lGIi2-RAlPWwlfUBeBpm24xrBv76z5w3ZX4PwLdmr50vzDnzMevTe6_g3K5t4EQ
link.rule.ids 315,783,787,27936,27937
linkProvider Wiley-Blackwell
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Highly+Effective+Non-Noble+MnO+2+Catalysts+for+5-Hydroxymethylfurfural+Oxidation+to+2%2C5-Furandicarboxylic+Acid&rft.jtitle=ChemSusChem&rft.au=%C3%81lvarez-Hern%C3%A1ndez%2C+D%C3%A9bora&rft.au=Meg%C3%ADas-Sayago%2C+Cristina&rft.au=Penkova%2C+Anna&rft.au=Centeno%2C+Miguel+%C3%81ngel&rft.date=2024-07-22&rft.eissn=1864-564X&rft.volume=17&rft.issue=14&rft.spage=e202400115&rft_id=info:doi/10.1002%2Fcssc.202400115&rft_id=info%3Apmid%2F38442078&rft.externalDocID=38442078
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1864-5631&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1864-5631&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1864-5631&client=summon