Ln 3+ Induced Thermally Activated Delayed Fluorescence of Chiral Heterometallic Clusters Ln 2 Ag 28

• Published in: Angewandte Chemie International Edition Vol. 63; no. 40; p. e202410414
• Main Authors: Wang, Xue-Tao, He, Sheng-Rong, Lv, Fang-Wen, Wang, Xue-Ting, Hong, Mei-Xin, Cao, Lingyun, Zhuang, Gui-Lin, Chen, Cheng, Zheng, Jun, Long, La-Sheng, Zheng, Xiu-Ying
• Format: Journal Article
• Language: English
• Published: Germany 01.10.2024
• Subjects: Cluster; Lanthanide; Thermally Activated Delayed Fluorescence; Chiral

A series of TADF-active compounds: 0D chiral Ln-Ag(I) clusters L-/D-Ln Ag -0D (Ln=Eu/Gd) and 2D chiral Ln-Ag(I) cluster-based frameworks L-/D-Ln Ag -2D (Ln=Gd) has been synthesized. Atomic-level structural analysis showed that the chiral Ag(I) cluster units {Ag S } in L-/D-Ln Ag -0D and L-/D-Ln Ag -...