Selective and Energy Efficient Electrocatalytic CO 2 ‐to‐Ethanol Conversion through Anion Modulation
Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO 2 reduction. However, achieving high ethanol selectivity and energy efficiency at industrial current densities remains challenging. In this study, we employed a blended anion modu...
Saved in:
| Published in | Angewandte Chemie International Edition Vol. 64; no. 35; p. e202506867 |
|---|---|
| Main Authors | , , , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
25.08.2025
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO 2 reduction. However, achieving high ethanol selectivity and energy efficiency at industrial current densities remains challenging. In this study, we employed a blended anion modulation strategy to enhance the selectivity and energy efficiency of CO 2 ‐to‐ethanol conversion. The Cu 2 (OH) 3 F pre‐catalyst achieved Faradaic efficiencies of 50% and 93% for ethanol and C 2+ , respectively, at 700 mA cm −2 in a blended electrolyte consisting of 2 M KOH and 1 M KCl. Comprehensive electrochemical tests, combined with in situ characterizations and theoretical analysis, revealed that chloride and hydroxide increased *CO coverage for efficient C─C coupling. Moreover, hydroxide stabilizes the *CHCOH intermediate through hydrogen bonding with the adsorbed hydroxide on the catalyst surface, while Cl synergistically enhances its reactivity by promoting water dissociation toward the ethanol pathway. |
|---|---|
| AbstractList | Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO 2 reduction. However, achieving high ethanol selectivity and energy efficiency at industrial current densities remains challenging. In this study, we employed a blended anion modulation strategy to enhance the selectivity and energy efficiency of CO 2 ‐to‐ethanol conversion. The Cu 2 (OH) 3 F pre‐catalyst achieved Faradaic efficiencies of 50% and 93% for ethanol and C 2+ , respectively, at 700 mA cm −2 in a blended electrolyte consisting of 2 M KOH and 1 M KCl. Comprehensive electrochemical tests, combined with in situ characterizations and theoretical analysis, revealed that chloride and hydroxide increased *CO coverage for efficient C─C coupling. Moreover, hydroxide stabilizes the *CHCOH intermediate through hydrogen bonding with the adsorbed hydroxide on the catalyst surface, while Cl synergistically enhances its reactivity by promoting water dissociation toward the ethanol pathway. Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO reduction. However, achieving high ethanol selectivity and energy efficiency at industrial current densities remains challenging. In this study, we employed a blended anion modulation strategy to enhance the selectivity and energy efficiency of CO -to-ethanol conversion. The Cu (OH) F pre-catalyst achieved Faradaic efficiencies of 50% and 93% for ethanol and C , respectively, at 700 mA cm in a blended electrolyte consisting of 2 M KOH and 1 M KCl. Comprehensive electrochemical tests, combined with in situ characterizations and theoretical analysis, revealed that chloride and hydroxide increased *CO coverage for efficient C─C coupling. Moreover, hydroxide stabilizes the *CHCOH intermediate through hydrogen bonding with the adsorbed hydroxide on the catalyst surface, while Cl synergistically enhances its reactivity by promoting water dissociation toward the ethanol pathway. |
| Author | Xiao, Yukun Ji, Chenrui Wang, Meng Da, Yumin Chen, Jie Xi, Shibo Zhu, Tong Chen, Xiang Chen, Wei Lum, Yanwei Fan, Lei Chen, Ganwen Jin, Hongqiang Wang, Lei Zhang, Hanqian Jiang, Rui Tian, Zhangliu Zhang, Jia |
| Author_xml | – sequence: 1 givenname: Yumin surname: Da fullname: Da, Yumin organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 2 givenname: Jie surname: Chen fullname: Chen, Jie organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore, Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University, Binhai New City Fuzhou 350207 China, Institute of High Performance Computing (IHPC) Agency for Science, Technology, and Research (ASTAR) 1 Fusionopolis Way, #16‐16 Connexis Singapore 138632 Singapore – sequence: 3 givenname: Lei surname: Fan fullname: Fan, Lei organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 4 givenname: Rui surname: Jiang fullname: Jiang, Rui organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 5 givenname: Yukun surname: Xiao fullname: Xiao, Yukun organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore, Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University, Binhai New City Fuzhou 350207 China – sequence: 6 givenname: Meng surname: Wang fullname: Wang, Meng organization: Department of Chemical and Biomolecular Engineering National University of Singapore Engineering Drive 4 Singapore 117585 Singapore – sequence: 7 givenname: Ganwen surname: Chen fullname: Chen, Ganwen organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore, Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University, Binhai New City Fuzhou 350207 China – sequence: 8 givenname: Zhangliu surname: Tian fullname: Tian, Zhangliu organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 9 givenname: Hanqian surname: Zhang fullname: Zhang, Hanqian organization: Agency for Science, Technology and Research (ASTAR) Advanced Remanufacturing and Technology Centre (ARTC) 3 CleanTech Loop, CleanTech Two Singapore 637143 Singapore – sequence: 10 givenname: Hongqiang surname: Jin fullname: Jin, Hongqiang organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 11 givenname: Xiang surname: Chen fullname: Chen, Xiang organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 12 givenname: Chenrui surname: Ji fullname: Ji, Chenrui organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore – sequence: 13 givenname: Shibo surname: Xi fullname: Xi, Shibo organization: Institute of Sustainability for Chemicals Energy and Environment ASTAR 1 Pesek Road Singapore 627833 Singapore – sequence: 14 givenname: Yanwei surname: Lum fullname: Lum, Yanwei organization: Department of Chemical and Biomolecular Engineering National University of Singapore Engineering Drive 4 Singapore 117585 Singapore – sequence: 15 givenname: Lei surname: Wang fullname: Wang, Lei organization: Department of Chemical and Biomolecular Engineering National University of Singapore Engineering Drive 4 Singapore 117585 Singapore – sequence: 16 givenname: Tong surname: Zhu fullname: Zhu, Tong organization: AI for Science Institute Beijing 100080 China – sequence: 17 givenname: Jia surname: Zhang fullname: Zhang, Jia organization: Institute of High Performance Computing (IHPC) Agency for Science, Technology, and Research (ASTAR) 1 Fusionopolis Way, #16‐16 Connexis Singapore 138632 Singapore – sequence: 18 givenname: Wei orcidid: 0000-0002-1131-3585 surname: Chen fullname: Chen, Wei organization: Department of Chemistry National University of Singapore Singapore 117551 Singapore, Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University, Binhai New City Fuzhou 350207 China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/40582984$$D View this record in MEDLINE/PubMed |
| BookMark | eNo9kMtOwzAQRS1URB-wZYn8Ayl-xIm7rKJQkIq6oPvI8aMxSu3KcSt1xyfwjXwJiQrdzNyrORrp3ikYOe80AI8YzTFC5Fk4q-cEEYYynuU3YIIZwQnNczrqdUppknOGx2DadZ89zznK7sA4RYyTBU8noPnQrZbRnjQUTsHS6bA7w9IYK612EZbDNXgpomjP0UpYbCCBP1_f0fejjI1wvoWFdycdOusdjE3wx10Dl25w714dWxF7eQ9ujWg7_fC3Z2D7Um6L12S9Wb0Vy3UiM5Imi5prWSuD-kiIpbhmCuE6zyQT3DCT1SxlSvSMzhkSVGZ4oemQXhHFkeF0Bp4ubw_Heq9VdQh2L8K5-k_cA_MLIIPvuqDNFcGoGiqthkqra6X0F8Mca_A |
| Cites_doi | 10.1126/sciadv.adi6119 10.1002/adma.201803111 10.1021/jacs.3c02130 10.1016/j.joule.2020.12.011 10.1021/acscatal.2c03833 10.1073/pnas.2118166119 10.1126/science.abg6582 10.1038/s41565-023-01543-8 10.1038/s41467-022-32740-z 10.1021/jacs.1c00880 10.1038/s41467-024-51928-z 10.1002/anie.201802055 10.1016/0009-2614(95)00385-1 10.1038/s41929-020-0450-0 10.1126/science.aas9100 10.1016/j.joule.2021.12.002 10.1002/anie.202407748 10.1002/anie.202100011 10.1038/s41929-020-00504-x 10.1038/s41560-023-01389-3 10.1038/s41467-024-49247-4 10.1021/jacs.3c08927 10.1021/jacs.2c04081 10.1073/pnas.2218987120 10.1002/anie.202111167 10.1016/j.cej.2021.131704 10.1038/s41467-024-49308-8 10.1021/acscatal.3c03797 10.1016/j.jallcom.2021.161424 10.1021/acscatal.2c03650 10.1038/s41467-024-45538-y 10.1016/j.joule.2023.07.010 10.1021/jacs.0c06779 10.1038/s41467-020-16998-9 10.1021/jacs.3c08748 10.1039/D1EE03861C 10.1126/science.1117756 10.1038/s41929-019-0383-7 10.1038/s41929-024-01179-4 10.1039/D1NJ02091A 10.1002/adma.202106028 10.1021/jacs.9b07415 10.1002/anie.202004846 10.1021/jacs.2c01098 10.1038/s41467-024-47498-9 10.1002/anie.202313796 10.1021/acs.iecr.1c03592 10.1038/s41560-020-0607-8 10.1073/pnas.2400546121 10.1002/anie.202114080 10.1038/s41929-021-00655-5 10.1002/ange.202016332 10.1016/j.jelechem.2016.12.016 10.1016/j.isci.2021.102813 10.1021/jacs.9b02945 10.1038/s41467-022-30262-2 10.1016/j.colsurfa.2013.03.007 10.1002/anie.202102657 10.1002/advs.202204579 10.1126/sciadv.aay3111 10.1021/jacs.3c13602 10.1039/D4SC02056A 10.1038/s41560-024-01633-4 10.1021/jacs.4c14299 10.1016/j.joule.2021.08.013 10.1038/s41467-022-31427-9 10.1021/jacs.2c13384 10.1063/1.480653 10.1021/acscatal.1c01486 10.1021/jacs.3c03426 10.1038/s44286-023-00018-w 10.1021/acscatal.3c01009 10.1002/adma.202312204 10.1038/s41467-019-13833-8 10.1002/aenm.202203896 10.1038/s41467-024-48052-3 10.1021/jacs.6b07612 10.1002/anie.202205909 10.1021/acscatal.3c06014 10.1002/anie.202302096 10.1038/s41929-022-00761-y 10.1002/adma.202208996 10.1021/jacs.0c13427 10.1038/s41467-024-51397-4 10.1039/c3cp51762d 10.1002/anie.202116706 10.1016/j.seppur.2024.128012 10.1002/anie.202007567 10.1002/anie.202110657 |
| ContentType | Journal Article |
| Copyright | 2025 Wiley‐VCH GmbH. |
| Copyright_xml | – notice: 2025 Wiley‐VCH GmbH. |
| DBID | AAYXX CITATION NPM |
| DOI | 10.1002/anie.202506867 |
| DatabaseName | CrossRef PubMed |
| DatabaseTitle | CrossRef PubMed |
| DatabaseTitleList | CrossRef PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1521-3773 |
| ExternalDocumentID | 40582984 10_1002_anie_202506867 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: National Research Foundation Investigatorship grantid: NRF-NRFI08-2022-0009 – fundername: National Research Foundation, Prime Minister's Office, Singapore grantid: 370184872 – fundername: Agency for Science, Technology and Research grantid: U2102d2002 – fundername: AISI-NUS Joint Research Initiative Fund grantid: A-8003323-00-00 |
| GroupedDBID | --- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 23M 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 5GY 5RE 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHQN AAMNL AANLZ AAONW AAXRX AAYCA AAYXX AAZKR ABCQN ABCUV ABDBF ABEML ABIJN ABJNI ABLJU ABPPZ ABPVW ACAHQ ACCZN ACFBH ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEIGN AEIMD AEUYR AEYWJ AFBPY AFFNX AFFPM AFGKR AFRAH AFWVQ AFZJQ AGHNM AGYGG AHBTC AHMBA AITYG AIURR AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BTSUX BY8 CITATION CS3 D-E D-F D0L DCZOG DPXWK DR1 DR2 DRFUL DRSTM EBS F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RNS ROL RX1 RYL SUPJJ TN5 UB1 UPT UQL V2E W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WXSBR WYISQ XG1 XPP XSW XV2 YZZ ZZTAW ~IA ~KM ~WT NPM |
| ID | FETCH-LOGICAL-c624-9b8ecbdf02020541b5d01b76c5a8f5f6b545da8ece750a3c619e30250d2d80f83 |
| ISSN | 1433-7851 |
| IngestDate | Thu Aug 28 04:48:35 EDT 2025 Wed Aug 27 16:38:43 EDT 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 35 |
| Keywords | Ethanol CO2 electroreduction Anion modulation |
| Language | English |
| License | 2025 Wiley‐VCH GmbH. |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c624-9b8ecbdf02020541b5d01b76c5a8f5f6b545da8ece750a3c619e30250d2d80f83 |
| ORCID | 0000-0002-1131-3585 |
| PMID | 40582984 |
| ParticipantIDs | pubmed_primary_40582984 crossref_primary_10_1002_anie_202506867 |
| PublicationCentury | 2000 |
| PublicationDate | 2025-08-25 2025-Aug-25 |
| PublicationDateYYYYMMDD | 2025-08-25 |
| PublicationDate_xml | – month: 08 year: 2025 text: 2025-08-25 day: 25 |
| PublicationDecade | 2020 |
| PublicationPlace | Germany |
| PublicationPlace_xml | – name: Germany |
| PublicationTitle | Angewandte Chemie International Edition |
| PublicationTitleAlternate | Angew Chem Int Ed Engl |
| PublicationYear | 2025 |
| References | e_1_2_7_5_1 e_1_2_7_3_1 e_1_2_7_9_1 e_1_2_7_7_1 e_1_2_7_19_1 e_1_2_7_60_1 e_1_2_7_83_1 e_1_2_7_17_1 e_1_2_7_62_1 e_1_2_7_81_1 e_1_2_7_15_1 e_1_2_7_41_1 e_1_2_7_64_1 e_1_2_7_87_1 e_1_2_7_1_1 e_1_2_7_13_1 e_1_2_7_43_1 e_1_2_7_66_1 e_1_2_7_85_1 e_1_2_7_11_1 e_1_2_7_45_1 e_1_2_7_68_1 e_1_2_7_47_1 e_1_2_7_89_1 e_1_2_7_26_1 e_1_2_7_49_1 e_1_2_7_28_1 e_1_2_7_90_1 e_1_2_7_73_1 e_1_2_7_94_1 e_1_2_7_50_1 e_1_2_7_71_1 e_1_2_7_25_1 e_1_2_7_31_1 e_1_2_7_52_1 e_1_2_7_77_1 e_1_2_7_23_1 e_1_2_7_33_1 e_1_2_7_54_1 e_1_2_7_75_1 e_1_2_7_35_1 e_1_2_7_56_1 e_1_2_7_37_1 e_1_2_7_58_1 e_1_2_7_79_1 e_1_2_7_39_1 e_1_2_7_6_1 e_1_2_7_4_1 e_1_2_7_80_1 e_1_2_7_8_1 e_1_2_7_18_1 e_1_2_7_84_1 e_1_2_7_16_1 e_1_2_7_40_1 e_1_2_7_61_1 e_1_2_7_82_1 e_1_2_7_2_1 e_1_2_7_14_1 e_1_2_7_42_1 e_1_2_7_63_1 e_1_2_7_88_1 Zhong D. (e_1_2_7_69_1) 2025 e_1_2_7_12_1 e_1_2_7_44_1 e_1_2_7_65_1 e_1_2_7_86_1 e_1_2_7_10_1 e_1_2_7_46_1 e_1_2_7_67_1 e_1_2_7_48_1 e_1_2_7_27_1 e_1_2_7_29_1 Zhou J. (e_1_2_7_92_1) 2024 Zhang X. (e_1_2_7_21_1) 2024 e_1_2_7_91_1 e_1_2_7_72_1 e_1_2_7_95_1 Fu W. (e_1_2_7_59_1) 2024 e_1_2_7_51_1 e_1_2_7_70_1 e_1_2_7_93_1 e_1_2_7_30_1 e_1_2_7_53_1 e_1_2_7_76_1 e_1_2_7_24_1 e_1_2_7_32_1 e_1_2_7_55_1 e_1_2_7_74_1 e_1_2_7_22_1 e_1_2_7_34_1 e_1_2_7_57_1 e_1_2_7_20_1 e_1_2_7_36_1 e_1_2_7_78_1 e_1_2_7_38_1 |
| References_xml | – ident: e_1_2_7_11_1 doi: 10.1126/sciadv.adi6119 – ident: e_1_2_7_18_1 doi: 10.1002/adma.201803111 – ident: e_1_2_7_27_1 doi: 10.1021/jacs.3c02130 – ident: e_1_2_7_29_1 doi: 10.1016/j.joule.2020.12.011 – ident: e_1_2_7_60_1 doi: 10.1021/acscatal.2c03833 – ident: e_1_2_7_70_1 doi: 10.1073/pnas.2118166119 – ident: e_1_2_7_32_1 doi: 10.1126/science.abg6582 – ident: e_1_2_7_30_1 doi: 10.1038/s41565-023-01543-8 – ident: e_1_2_7_64_1 doi: 10.1038/s41467-022-32740-z – ident: e_1_2_7_85_1 doi: 10.1021/jacs.1c00880 – ident: e_1_2_7_25_1 doi: 10.1038/s41467-024-51928-z – ident: e_1_2_7_51_1 doi: 10.1002/anie.201802055 – ident: e_1_2_7_89_1 doi: 10.1016/0009-2614(95)00385-1 – ident: e_1_2_7_19_1 doi: 10.1038/s41929-020-0450-0 – ident: e_1_2_7_40_1 doi: 10.1126/science.aas9100 – ident: e_1_2_7_10_1 doi: 10.1016/j.joule.2021.12.002 – ident: e_1_2_7_13_1 doi: 10.1002/anie.202407748 – ident: e_1_2_7_84_1 doi: 10.1002/anie.202100011 – ident: e_1_2_7_94_1 doi: 10.1038/s41929-020-00504-x – ident: e_1_2_7_8_1 doi: 10.1038/s41560-023-01389-3 – ident: e_1_2_7_57_1 doi: 10.1038/s41467-024-49247-4 – ident: e_1_2_7_5_1 doi: 10.1021/jacs.3c08927 – ident: e_1_2_7_81_1 doi: 10.1021/jacs.2c04081 – year: 2025 ident: e_1_2_7_69_1 publication-title: Angew. Chem. Int. Ed. – ident: e_1_2_7_95_1 doi: 10.1073/pnas.2218987120 – ident: e_1_2_7_90_1 doi: 10.1002/anie.202111167 – ident: e_1_2_7_48_1 doi: 10.1016/j.cej.2021.131704 – ident: e_1_2_7_77_1 doi: 10.1038/s41467-024-49308-8 – ident: e_1_2_7_16_1 doi: 10.1021/acscatal.3c03797 – ident: e_1_2_7_47_1 doi: 10.1016/j.jallcom.2021.161424 – ident: e_1_2_7_41_1 doi: 10.1021/acscatal.2c03650 – ident: e_1_2_7_73_1 doi: 10.1038/s41467-024-45538-y – ident: e_1_2_7_15_1 doi: 10.1016/j.joule.2023.07.010 – ident: e_1_2_7_37_1 doi: 10.1021/jacs.0c06779 – ident: e_1_2_7_39_1 doi: 10.1038/s41467-020-16998-9 – ident: e_1_2_7_42_1 doi: 10.1021/jacs.3c08748 – ident: e_1_2_7_66_1 doi: 10.1039/D1EE03861C – ident: e_1_2_7_88_1 doi: 10.1126/science.1117756 – ident: e_1_2_7_2_1 doi: 10.1038/s41929-019-0383-7 – ident: e_1_2_7_34_1 doi: 10.1038/s41929-024-01179-4 – ident: e_1_2_7_49_1 doi: 10.1039/D1NJ02091A – ident: e_1_2_7_56_1 doi: 10.1002/adma.202106028 – ident: e_1_2_7_72_1 doi: 10.1021/jacs.9b07415 – ident: e_1_2_7_93_1 doi: 10.1002/anie.202004846 – ident: e_1_2_7_14_1 doi: 10.1021/jacs.2c01098 – ident: e_1_2_7_6_1 doi: 10.1038/s41467-024-47498-9 – ident: e_1_2_7_50_1 doi: 10.1002/anie.202313796 – ident: e_1_2_7_54_1 doi: 10.1021/acs.iecr.1c03592 – ident: e_1_2_7_1_1 doi: 10.1038/s41560-020-0607-8 – ident: e_1_2_7_91_1 doi: 10.1073/pnas.2400546121 – year: 2024 ident: e_1_2_7_92_1 publication-title: Angew. Chem. Int. Ed. – ident: e_1_2_7_76_1 doi: 10.1002/anie.202114080 – ident: e_1_2_7_35_1 doi: 10.1038/s41929-021-00655-5 – ident: e_1_2_7_52_1 doi: 10.1002/ange.202016332 – ident: e_1_2_7_83_1 doi: 10.1016/j.jelechem.2016.12.016 – ident: e_1_2_7_55_1 doi: 10.1016/j.isci.2021.102813 – ident: e_1_2_7_4_1 doi: 10.1021/jacs.9b02945 – ident: e_1_2_7_65_1 doi: 10.1038/s41467-022-30262-2 – ident: e_1_2_7_46_1 doi: 10.1016/j.colsurfa.2013.03.007 – ident: e_1_2_7_12_1 doi: 10.1073/pnas.2218987120 – ident: e_1_2_7_43_1 doi: 10.1002/anie.202102657 – ident: e_1_2_7_17_1 doi: 10.1002/advs.202204579 – ident: e_1_2_7_22_1 doi: 10.1126/sciadv.aay3111 – ident: e_1_2_7_36_1 doi: 10.1021/jacs.3c13602 – ident: e_1_2_7_75_1 doi: 10.1039/D4SC02056A – ident: e_1_2_7_78_1 doi: 10.1038/s41560-024-01633-4 – ident: e_1_2_7_80_1 doi: 10.1021/jacs.4c14299 – ident: e_1_2_7_9_1 doi: 10.1016/j.joule.2021.08.013 – ident: e_1_2_7_23_1 doi: 10.1038/s41467-022-31427-9 – ident: e_1_2_7_38_1 doi: 10.1021/jacs.2c13384 – ident: e_1_2_7_87_1 doi: 10.1063/1.480653 – year: 2024 ident: e_1_2_7_59_1 publication-title: Angew. Chem. Int. Ed. – ident: e_1_2_7_74_1 doi: 10.1021/acscatal.1c01486 – ident: e_1_2_7_67_1 doi: 10.1021/jacs.3c03426 – ident: e_1_2_7_28_1 doi: 10.1038/s44286-023-00018-w – ident: e_1_2_7_58_1 doi: 10.1021/acscatal.3c01009 – ident: e_1_2_7_61_1 doi: 10.1002/adma.202312204 – ident: e_1_2_7_3_1 doi: 10.1038/s41467-019-13833-8 – ident: e_1_2_7_63_1 doi: 10.1002/aenm.202203896 – ident: e_1_2_7_7_1 doi: 10.1038/s41467-024-48052-3 – ident: e_1_2_7_33_1 doi: 10.1021/jacs.6b07612 – ident: e_1_2_7_24_1 doi: 10.1002/anie.202205909 – ident: e_1_2_7_68_1 doi: 10.1021/acscatal.3c06014 – ident: e_1_2_7_62_1 doi: 10.1002/anie.202302096 – ident: e_1_2_7_31_1 doi: 10.1038/s41929-022-00761-y – ident: e_1_2_7_20_1 doi: 10.1002/adma.202208996 – year: 2024 ident: e_1_2_7_21_1 publication-title: Adv. Mater. – ident: e_1_2_7_26_1 doi: 10.1021/jacs.0c13427 – ident: e_1_2_7_53_1 – ident: e_1_2_7_79_1 doi: 10.1038/s41467-024-51397-4 – ident: e_1_2_7_86_1 doi: 10.1039/c3cp51762d – ident: e_1_2_7_44_1 doi: 10.1002/anie.202116706 – ident: e_1_2_7_45_1 doi: 10.1016/j.seppur.2024.128012 – ident: e_1_2_7_82_1 doi: 10.1002/anie.202007567 – ident: e_1_2_7_71_1 doi: 10.1002/anie.202110657 |
| SSID | ssj0028806 |
| Score | 2.485602 |
| Snippet | Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO 2 reduction. However, achieving high... Ethanol, with its high market value and stable global demand, stands out as an attractive product of electrocatalytic CO reduction. However, achieving high... |
| SourceID | pubmed crossref |
| SourceType | Index Database |
| StartPage | e202506867 |
| Title | Selective and Energy Efficient Electrocatalytic CO 2 ‐to‐Ethanol Conversion through Anion Modulation |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/40582984 |
| Volume | 64 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9wwELa29NBeKvqE0lY-VOphFZo4j_UeVyEIVaJIdJHgtIpju-RAglC2VXuCf8Bv5Jd0xna8j3KgvURZK4-V59NkZuzvG0I-xlqHYlSJQLJSBBDfhgGqPqFBBHJ1I25KA4dfs4OT5MtpejoY3CyzSzqxW_2-l1fyP1aFMbArsmT_wbL-oTAA52BfOIKF4fggG38zTWxw7w-WvwtL4yuMKAQu8Re2xY2p0PxCYdb8aMiGfntD1_rTAgvoLZYRmh-2gOYb-Ewa_HXYStfnazmanTTf1c8SCQFDIzyg1gqMhayX1_n3TKB6Nr-o_VDek0NqD7B9x4ZQtd_dU7ui9vG8Xq5SsBTLrpbR7BxrEsfBiDtxWeWcLYvAwdlWJr03tprmDnVWyeQvL29VY5GCv4vvQpbLaPE969fw1z5zfvOhFWpmM7x_5u9_RB4zyDSwCcbesVcgY-DeLEHN_f1e9zNkn1ffvxLXrGQoJlKZbpJnLsWgE4uX52SgmhfkSd539ntJzj1uKBiPWtxQjxu6jhuaH1FG765vuxYODit0gRXqsEINVugCK6_IdL-Y5geB67gRVBlLgrHgqhJSQwrBIJSPRCrDSIyyKi25TnUmINyWJVyjIM4s4wqSbxXjBEgmeah5_JpsNG2jtgiNxmWqcEI1JPhRpMdxpiEYTSRkDDyr1Db51E_X7NLqqszuN8w2eWNn018HOQZnY568ffAzdsjTBSjfkY3uaq7eQzDZiQ_G3H8AyBty1Q |
| linkProvider | Wiley-Blackwell |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Selective+and+Energy+Efficient+Electrocatalytic+CO+2+%E2%80%90to%E2%80%90Ethanol+Conversion+through+Anion+Modulation&rft.jtitle=Angewandte+Chemie+International+Edition&rft.au=Da%2C+Yumin&rft.au=Chen%2C+Jie&rft.au=Fan%2C+Lei&rft.au=Jiang%2C+Rui&rft.date=2025-08-25&rft.issn=1433-7851&rft.eissn=1521-3773&rft.volume=64&rft.issue=35&rft_id=info:doi/10.1002%2Fanie.202506867&rft.externalDBID=n%2Fa&rft.externalDocID=10_1002_anie_202506867 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1433-7851&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1433-7851&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1433-7851&client=summon |