One‐Pot Synthesis of Multicentric DIL@PDIL Catalyst for Mild CO 2 Conversion to Cyclic Carbonates
Among the various studies on CO 2 utilization, the sustainable and cost‐effective fixation of CO 2 into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicati...
Saved in:
| Published in | Chemistry : a European journal Vol. 31; no. 14; p. e202404156 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
06.03.2025
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Among the various studies on CO 2 utilization, the sustainable and cost‐effective fixation of CO 2 into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicationic ionic liquid (DIL), DMAP[TMGH]Br, supported on a polymeric dicationic ionic liquid (PDIL), P‐DVB/Im[TMGH]Br. The multicentric high‐ion‐density material was prepared with exceptional efficiency from five readily available starting materials in one pot through simultaneous quaternization, neutralization and polymerization. The structure was characterized using FT‐IR, XPS, SEM, TGA, ICP‐MS and BET, as well as through stepwise synthesis verification. Evaluation of the catalytic performance revealed the ionic liquid composite delivered chloropropylene carbonate (CPC) in excellent yield and selectivity from either pure CO 2 or simulated flue gas at 60 °C and relatively lower pressure. Additionally, the DIL@PDIL catalyst exhibited good recyclability and were applicable to a range of epoxide substrates. The high activity of the the catalyst could be attributed to the abundant [TMGH] + hydrogen bonding donors and Br − anions, which synergistically catalyze the epoxide ring‐opening, as well as the abundant ‐COO − groups and imidazole cations, which facilitate the adsorption and activation of CO 2 . |
|---|---|
| AbstractList | Among the various studies on CO
utilization, the sustainable and cost-effective fixation of CO
into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicationic ionic liquid (DIL), DMAP[TMGH]Br, supported on a polymeric dicationic ionic liquid (PDIL), P-DVB/Im[TMGH]Br. The multicentric high-ion-density material was prepared with exceptional efficiency from five readily available starting materials in one pot through simultaneous quaternization, neutralization and polymerization. The structure was characterized using FT-IR, XPS, SEM, TGA, ICP-MS and BET, as well as through stepwise synthesis verification. Evaluation of the catalytic performance revealed the ionic liquid composite delivered chloropropylene carbonate (CPC) in excellent yield and selectivity from either pure CO
or simulated flue gas at 60 °C and relatively lower pressure. Additionally, the DIL@PDIL catalyst exhibited good recyclability and were applicable to a range of epoxide substrates. The high activity of the the catalyst could be attributed to the abundant [TMGH]
hydrogen bonding donors and Br
anions, which synergistically catalyze the epoxide ring-opening, as well as the abundant -COO
groups and imidazole cations, which facilitate the adsorption and activation of CO
. Among the various studies on CO 2 utilization, the sustainable and cost‐effective fixation of CO 2 into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicationic ionic liquid (DIL), DMAP[TMGH]Br, supported on a polymeric dicationic ionic liquid (PDIL), P‐DVB/Im[TMGH]Br. The multicentric high‐ion‐density material was prepared with exceptional efficiency from five readily available starting materials in one pot through simultaneous quaternization, neutralization and polymerization. The structure was characterized using FT‐IR, XPS, SEM, TGA, ICP‐MS and BET, as well as through stepwise synthesis verification. Evaluation of the catalytic performance revealed the ionic liquid composite delivered chloropropylene carbonate (CPC) in excellent yield and selectivity from either pure CO 2 or simulated flue gas at 60 °C and relatively lower pressure. Additionally, the DIL@PDIL catalyst exhibited good recyclability and were applicable to a range of epoxide substrates. The high activity of the the catalyst could be attributed to the abundant [TMGH] + hydrogen bonding donors and Br − anions, which synergistically catalyze the epoxide ring‐opening, as well as the abundant ‐COO − groups and imidazole cations, which facilitate the adsorption and activation of CO 2 . |
| Author | Zeng, Yanbin Wang, Xiufang Qiu, Jiaxiang Tang, Zhenzhu Wang, Xiaoxia Xie, Guanqun Wang, Yeying |
| Author_xml | – sequence: 1 givenname: Yeying orcidid: 0009-0003-1299-5877 surname: Wang fullname: Wang, Yeying organization: School of Pharmacy Guangdong Pharmaceutical University (China) Guangzhou Guangdong Province China 510006, School of Environment and Civil Engineering Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 2 givenname: Yanbin surname: Zeng fullname: Zeng, Yanbin organization: School of Environment and Civil Engineering Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 3 givenname: Zhenzhu surname: Tang fullname: Tang, Zhenzhu organization: School of Materials Science and Engineering Guangdong Provincial Engineering Technology Research Center of Key Material for High Performance Copper Clad Laminate Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 4 givenname: Jiaxiang surname: Qiu fullname: Qiu, Jiaxiang organization: School of Environment and Civil Engineering Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 5 givenname: Xiaoxia surname: Wang fullname: Wang, Xiaoxia organization: School of Materials Science and Engineering Guangdong Provincial Engineering Technology Research Center of Key Material for High Performance Copper Clad Laminate Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 6 givenname: Guanqun surname: Xie fullname: Xie, Guanqun organization: School of Environment and Civil Engineering Dongguan University of Technology (China) Dongguan Guangdong Province China 523808 – sequence: 7 givenname: Xiufang orcidid: 0000-0003-0822-2890 surname: Wang fullname: Wang, Xiufang organization: School of Pharmacy Guangdong Pharmaceutical University (China) Guangzhou Guangdong Province China 510006 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/39714873$$D View this record in MEDLINE/PubMed |
| BookMark | eNo9kEtOwzAURS1URD8wZYi8gQQ7dpxkBgq_Sq1aic4jx3lWg1K7sl2kzFgCa2QlpCp08u7k3Cu9M0UjYw0gdEtJTAlJ7tUWdnFCEk44TcUFmtA0oRHLRDpCE1LwLBIpK8Zo6v0HIaQQjF2hMSsyyvOMTZBaGfj5-l7bgN97E7bgW4-txstDF1oFJrhW4af54mE9HFzKILveB6ytw8u2a3C5wgkurfkE51trcLC47FU3lErpamtkAH-NLrXsPNz85QxtXp435Vu0WL3Oy8dFpETCojqnWjRFyrlURUPzGuomlYRxwZKG01pSBkJJAUSA1lIQNZC1yJTOc5KDZDN0d5rdH-odNNXetTvp-ur_2QGIT4By1nsH-oxQUh1tVkeb1dkm-wWf1mhQ |
| Cites_doi | 10.1016/j.envres.2022.115135 10.1021/acscatal.0c02930 10.1016/j.fuel.2022.124853 10.1016/j.jes.2023.10.018 10.1016/j.colsurfa.2021.126304 10.1016/j.fuel.2024.132301 10.1016/j.fuel.2021.121495 10.1007/s11164-020-04167-y 10.1021/acssuschemeng.9b00591 10.1007/s13369-022-07502-0 10.1039/D0CS00025F 10.1016/j.molliq.2022.118556 10.1016/j.tplants.2019.04.003 10.1016/j.apcatb.2022.121463 10.1021/acssuschemeng.2c01660 10.1071/CH21182 10.1016/j.gee.2021.02.011 10.1039/D0CP06041K 10.1016/j.apcatb.2020.119620 10.1016/j.seppur.2022.121971 10.1021/acs.iecr.1c01118 10.1016/j.seppur.2022.121273 10.1039/C8CS00502H 10.1016/j.jcou.2022.102294 10.1016/j.apmt.2023.101970 10.1039/C8GC01129J 10.1016/j.seppur.2024.126682 10.1016/j.cej.2023.148129 10.1016/j.gce.2022.06.001 10.1016/j.seppur.2023.123375 10.1039/C9GC00827F 10.1021/acs.chemrev.7b00072 10.1016/j.fuel.2023.128210 10.1021/acscatal.9b02113 10.1039/C8GC01038B 10.1016/j.ccr.2017.11.013 10.1016/j.fuel.2022.126913 10.1021/acssuschemeng.2c07453 10.1039/C9CS00047J 10.1016/j.cej.2019.122765 10.1016/j.jcou.2021.101573 10.1021/acsami.6b02461 |
| ContentType | Journal Article |
| Copyright | 2024 Wiley-VCH GmbH. |
| Copyright_xml | – notice: 2024 Wiley-VCH GmbH. |
| DBID | AAYXX CITATION NPM |
| DOI | 10.1002/chem.202404156 |
| DatabaseName | CrossRef PubMed |
| DatabaseTitle | CrossRef PubMed |
| DatabaseTitleList | PubMed CrossRef |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1521-3765 |
| ExternalDocumentID | 39714873 10_1002_chem_202404156 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: Guangdong Pharmaceutical University grantid: 2024zz07 – fundername: Dongguan Science and Technology Bureau grantid: 20221800500532 – fundername: Dongguan Science and Technology Bureau grantid: 202211819038 |
| GroupedDBID | --- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 29B 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 5GY 5VS 66C 6J9 702 77Q 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHQN AAMNL AANLZ AAONW AAXRX AAYCA AAYXX AAZKR ABCQN ABCUV ABDBF ABIJN ABJNI ABLJU ABPVW ACAHQ ACCZN ACGFS ACIWK ACNCT ACPOU ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEGXH AEIGN AEIMD AEUYR AEYWJ AFBPY AFFPM AFGKR AFRAH AFWVQ AFZJQ AGHNM AGYGG AHBTC AHMBA AITYG AIURR AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BY8 CITATION CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBS F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RNS ROL RX1 RYL SUPJJ TN5 TWZ UB1 UPT V2E V8K W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WXSBR WYISQ XG1 XPP XV2 YZZ ZZTAW ~IA ~WT AAHHS ACCFJ ADZOD AEEZP AEQDE AIWBW AJBDE NPM |
| ID | FETCH-LOGICAL-c623-b81f6d9544ac9d18bebd5a034632d41ba13e6ca6e06effa60c44ab67cf8808ea3 |
| ISSN | 0947-6539 |
| IngestDate | Thu Apr 03 07:06:32 EDT 2025 Thu Jul 24 02:16:32 EDT 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 14 |
| Keywords | CO2 cycloaddition dicationic IL one-pot synthesis composite DIL catalyst |
| Language | English |
| License | 2024 Wiley-VCH GmbH. |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c623-b81f6d9544ac9d18bebd5a034632d41ba13e6ca6e06effa60c44ab67cf8808ea3 |
| ORCID | 0000-0003-0822-2890 0009-0003-1299-5877 |
| PMID | 39714873 |
| ParticipantIDs | pubmed_primary_39714873 crossref_primary_10_1002_chem_202404156 |
| PublicationCentury | 2000 |
| PublicationDate | 2025-03-06 2025-Mar-06 |
| PublicationDateYYYYMMDD | 2025-03-06 |
| PublicationDate_xml | – month: 03 year: 2025 text: 2025-03-06 day: 06 |
| PublicationDecade | 2020 |
| PublicationPlace | Germany |
| PublicationPlace_xml | – name: Germany |
| PublicationTitle | Chemistry : a European journal |
| PublicationTitleAlternate | Chemistry |
| PublicationYear | 2025 |
| References | e_1_2_8_28_2 e_1_2_8_24_1 e_1_2_8_47_1 e_1_2_8_26_1 e_1_2_8_49_1 e_1_2_8_9_2 e_1_2_8_3_1 e_1_2_8_5_2 e_1_2_8_7_2 Liu Q. (e_1_2_8_15_2) 2015; 6 e_1_2_8_43_1 e_1_2_8_20_2 e_1_2_8_41_2 e_1_2_8_45_1 e_1_2_8_22_2 e_1_2_8_1_1 e_1_2_8_17_2 e_1_2_8_19_1 e_1_2_8_36_1 e_1_2_8_13_2 e_1_2_8_38_1 e_1_2_8_30_2 e_1_2_8_11_1 e_1_2_8_34_1 e_1_2_8_32_2 e_1_2_8_29_2 e_1_2_8_23_2 e_1_2_8_25_1 e_1_2_8_46_1 e_1_2_8_27_1 e_1_2_8_48_1 e_1_2_8_2_1 e_1_2_8_4_2 e_1_2_8_6_2 e_1_2_8_8_2 e_1_2_8_42_2 e_1_2_8_21_2 e_1_2_8_44_1 e_1_2_8_40_1 e_1_2_8_16_2 e_1_2_8_18_1 e_1_2_8_39_1 e_1_2_8_12_2 e_1_2_8_14_1 e_1_2_8_35_1 e_1_2_8_37_1 e_1_2_8_31_2 e_1_2_8_10_1 e_1_2_8_33_1 |
| References_xml | – ident: e_1_2_8_2_1 doi: 10.1016/j.envres.2022.115135 – ident: e_1_2_8_16_2 doi: 10.1021/acscatal.0c02930 – ident: e_1_2_8_10_1 doi: 10.1016/j.fuel.2022.124853 – ident: e_1_2_8_14_1 – ident: e_1_2_8_3_1 – ident: e_1_2_8_40_1 – ident: e_1_2_8_35_1 doi: 10.1016/j.jes.2023.10.018 – ident: e_1_2_8_41_2 doi: 10.1016/j.colsurfa.2021.126304 – ident: e_1_2_8_36_1 doi: 10.1016/j.fuel.2024.132301 – ident: e_1_2_8_34_1 doi: 10.1016/j.fuel.2021.121495 – ident: e_1_2_8_37_1 doi: 10.1007/s11164-020-04167-y – ident: e_1_2_8_38_1 doi: 10.1021/acssuschemeng.9b00591 – ident: e_1_2_8_42_2 doi: 10.1007/s13369-022-07502-0 – ident: e_1_2_8_12_2 doi: 10.1039/D0CS00025F – ident: e_1_2_8_21_2 doi: 10.1016/j.molliq.2022.118556 – ident: e_1_2_8_4_2 doi: 10.1016/j.tplants.2019.04.003 – ident: e_1_2_8_46_1 doi: 10.1016/j.apcatb.2022.121463 – ident: e_1_2_8_47_1 doi: 10.1021/acssuschemeng.2c01660 – ident: e_1_2_8_1_1 doi: 10.1071/CH21182 – ident: e_1_2_8_24_1 doi: 10.1016/j.gee.2021.02.011 – ident: e_1_2_8_39_1 doi: 10.1039/D0CP06041K – ident: e_1_2_8_29_2 doi: 10.1016/j.apcatb.2020.119620 – ident: e_1_2_8_13_2 doi: 10.1016/j.seppur.2022.121971 – ident: e_1_2_8_44_1 doi: 10.1021/acs.iecr.1c01118 – ident: e_1_2_8_23_2 doi: 10.1016/j.seppur.2022.121273 – ident: e_1_2_8_7_2 doi: 10.1039/C8CS00502H – ident: e_1_2_8_33_1 doi: 10.1016/j.jcou.2022.102294 – ident: e_1_2_8_32_2 doi: 10.1016/j.apmt.2023.101970 – ident: e_1_2_8_11_1 – ident: e_1_2_8_22_2 doi: 10.1039/C8GC01129J – ident: e_1_2_8_28_2 doi: 10.1016/j.seppur.2024.126682 – ident: e_1_2_8_45_1 doi: 10.1016/j.cej.2023.148129 – ident: e_1_2_8_26_1 doi: 10.1016/j.gce.2022.06.001 – ident: e_1_2_8_20_2 doi: 10.1016/j.seppur.2023.123375 – ident: e_1_2_8_6_2 doi: 10.1039/C9GC00827F – ident: e_1_2_8_17_2 doi: 10.1021/acs.chemrev.7b00072 – ident: e_1_2_8_30_2 doi: 10.1016/j.fuel.2023.128210 – ident: e_1_2_8_9_2 doi: 10.1021/acscatal.9b02113 – ident: e_1_2_8_27_1 – ident: e_1_2_8_48_1 doi: 10.1039/C8GC01038B – ident: e_1_2_8_18_1 doi: 10.1016/j.ccr.2017.11.013 – ident: e_1_2_8_31_2 doi: 10.1016/j.fuel.2022.126913 – ident: e_1_2_8_43_1 doi: 10.1021/acssuschemeng.2c07453 – ident: e_1_2_8_19_1 – volume: 6 start-page: 1 year: 2015 ident: e_1_2_8_15_2 publication-title: Nature Communications. – ident: e_1_2_8_8_2 doi: 10.1039/C9CS00047J – ident: e_1_2_8_49_1 doi: 10.1016/j.cej.2019.122765 – ident: e_1_2_8_25_1 doi: 10.1016/j.jcou.2021.101573 – ident: e_1_2_8_5_2 doi: 10.1021/acsami.6b02461 |
| SSID | ssj0009633 |
| Score | 2.4691505 |
| Snippet | Among the various studies on CO 2 utilization, the sustainable and cost‐effective fixation of CO 2 into cyclic carbonates remains one of the most intriguing... Among the various studies on CO utilization, the sustainable and cost-effective fixation of CO into cyclic carbonates remains one of the most intriguing... |
| SourceID | pubmed crossref |
| SourceType | Index Database |
| StartPage | e202404156 |
| Title | One‐Pot Synthesis of Multicentric DIL@PDIL Catalyst for Mild CO 2 Conversion to Cyclic Carbonates |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/39714873 |
| Volume | 31 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9NAEF5BkaCXimdpeWgPIA6WYb1-1L6BDKggSioIUuES7a5nqSVwqspBpL-e2ZedoCABFydab2Jnv0-TmfHMt4Q8SkrdgKpYrEFggFJpGVdlymIJnMOBFgC2GPPofXH4KXt7kp-Mjwtsd0kvn6qLjX0l_4MqjiGupkv2H5AdvhQH8D3ii0dEGI9_hfGkg_h43kcflx36cV5axLbU2prLVkUv37x7nLFjfDG9fkZ_pLeFhUfttyaqJxE3LX8_XM7MuKH1UhnV61qcS5NW9wWGQckgbA4XuRbptUx-uFmbnHcG5DMswx-jSU2DHxWdbMfyXz_3yyl0F6eLIQ_bLiy_WvET-ft1NTfBc1uc5ZWtvT3libFh-arB9WbfEytbMZ_AjeSaiSk3WnenFotkNhICGybijz_7brFGLwvjPLdJym962uHUZXKFY2hhw_APo-QYGqQ0iHsy_mz9Ytvkavj4mh-zFpFYz2R6nez4kIK-cPy4QS5Bd5NcG8C6RYTnCR14QuearvKEIkGeG5bQwBKKLKGGJbSeUE5HltB-Th1L6MiS22T6-tW0Poz91hqxQn83lmWii6bKs0yoqklKCbLJBUuzIuVNlkiRpFAoUQArQGtRMIUzZXGgNJr7EkR6h2x18w7uEqpZIouGI3KQZ4nIMHxWldZ4BcmkTMo98iSs0-zMCajMnFQ2n5nFnQ2Lu0d23TIO88Ja7__xzD2yPfLuPtnqzxfwAL3EXj60sP4CoQ9l4w |
| linkProvider | Wiley-Blackwell |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=One-Pot+Synthesis+of+Multicentric+DIL%40PDIL+Catalyst+for+Mild+CO+2+Conversion+to+Cyclic+Carbonates&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Wang%2C+Yeying&rft.au=Zeng%2C+Yanbin&rft.au=Tang%2C+Zhenzhu&rft.au=Qiu%2C+Jiaxiang&rft.date=2025-03-06&rft.eissn=1521-3765&rft.volume=31&rft.issue=14&rft.spage=e202404156&rft_id=info:doi/10.1002%2Fchem.202404156&rft_id=info%3Apmid%2F39714873&rft.externalDocID=39714873 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon |