Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries

Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) ha...

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Published inAdvanced science Vol. 5; no. 3; pp. 1700592 - n/a
Main Authors Zheng, Mingbo, Tang, Hao, Li, Lulu, Hu, Qin, Zhang, Li, Xue, Huaiguo, Pang, Huan
Format Journal Article
LanguageEnglish
Published Germany John Wiley & Sons, Inc 01.03.2018
John Wiley and Sons Inc
Wiley
Subjects
Efficiency
Electrodes
Electrolytes
Energy
Energy storage
hierarchical nanostructures
Innovations
Lithium
lithium‐ion batteries
Metal oxides
Morphology
Nanostructured materials
Review
Reviews
Scanning electron microscopy
Science
transition metal oxides
China
transition metal oxides
hierarchical nanostructures
lithium‐ion batteries
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Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed. Hierarchical nanostructures have been extensively investigated in the field of lithium‐ion batteries because they can provide numerous accessible electroactive sites, shorten the ion diffusion pathway, and accommodate volume expansion. Research progress on hierarchically nanostructured transition metal oxides as electrode materials for lithium‐ion batteries is summarized and evaluated.
AbstractList Lithium-ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li-ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed.
Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed.
Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed. Hierarchical nanostructures have been extensively investigated in the field of lithium‐ion batteries because they can provide numerous accessible electroactive sites, shorten the ion diffusion pathway, and accommodate volume expansion. Research progress on hierarchically nanostructured transition metal oxides as electrode materials for lithium‐ion batteries is summarized and evaluated.
Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed.
Author Hu, Qin
Li, Lulu
Zhang, Li
Pang, Huan
Xue, Huaiguo
Zheng, Mingbo
Tang, Hao
AuthorAffiliation 1 School of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. China
AuthorAffiliation_xml – name: 1 School of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. China
Author_xml – sequence: 1
  givenname: Mingbo
  surname: Zheng
  fullname: Zheng, Mingbo
  organization: Yangzhou University
– sequence: 2
  givenname: Hao
  surname: Tang
  fullname: Tang, Hao
  organization: Yangzhou University
– sequence: 3
  givenname: Lulu
  surname: Li
  fullname: Li, Lulu
  organization: Yangzhou University
– sequence: 4
  givenname: Qin
  surname: Hu
  fullname: Hu, Qin
  organization: Yangzhou University
– sequence: 5
  givenname: Li
  surname: Zhang
  fullname: Zhang, Li
  organization: Yangzhou University
– sequence: 6
  givenname: Huaiguo
  surname: Xue
  fullname: Xue, Huaiguo
  organization: Yangzhou University
– sequence: 7
  givenname: Huan
  orcidid: 0000-0002-5319-0480
  surname: Pang
  fullname: Pang, Huan
  email: huanpangchem@hotmail.com, panghuan@yzu.edu.cn
  organization: Yangzhou University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/29593962$$D View this record in MEDLINE/PubMed
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Issue 3
Keywords transition metal oxides
hierarchical nanostructures
lithium‐ion batteries
Language English
License Attribution
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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PublicationDate March 2018
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Snippet Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To...
Lithium-ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To...
Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling...
Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling...
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SubjectTerms Efficiency
Electrodes
Electrolytes
Energy
Energy storage
hierarchical nanostructures
Innovations
Lithium
lithium‐ion batteries
Metal oxides
Morphology
Nanostructured materials
Review
Reviews
Scanning electron microscopy
Science
transition metal oxides
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Title Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fadvs.201700592
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