Formation kinetics and thermodynamic stability of the Aurivillius compounds in Bi 4 Ti 3 O 12 –BiFeO 3 system
Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have attracted particular interest. Formation kinetics and thermodynamic stability are the fundamental knowledge needed for modeling and predicting the t...
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| Published in | Journal of the American Ceramic Society Vol. 107; no. 10; pp. 6574 - 6582 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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United States
Wiley-Blackwell
01.10.2024
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| Abstract | Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have attracted particular interest. Formation kinetics and thermodynamic stability are the fundamental knowledge needed for modeling and predicting the temporal microstructure and property evolution during materials processing but have not yet been addressed by quantitative experimental measurement. This article focuses on the Bi n +1 Fe n –3 Ti 3 O 3 n +3 Aurivillius compounds on the Bi 4 Ti 3 O 12 –BiFeO 3 tie‐line to elucidate the mechanisms and thermodynamic controls responsible for phase formation of compounds with various perovskite‐like layers. Five high‐purity Aurivillius compounds Bi 4 Ti 3 O 12 , Bi 5 FeTi 3 O 15 , Bi 6 Fe 2 Ti 3 O 18 , Bi 7 Fe 3 Ti 3 O 21 , and Bi 8 Fe 4 Ti 3 O 24 with integer n = 3–7 values were synthesized and their phase transformation properties and enthalpies of formation were studied by X‐ray diffraction in situ, high temperature differential scanning calorimetry, and high temperature oxide melt solution calorimetry. Thermodynamic stability of the compounds decreases with increasing n , and formation kinetics gradually slow down, demonstrating the inherent difficulty to synthesize pure Aurivillius compounds with n larger than 8. This difficulty was confirmed by an impurity phase coexisting with Bi 9 Fe 5 Ti 3 O 27 . |
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| AbstractList | Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have attracted particular interest. Formation kinetics and thermodynamic stability are the fundamental knowledge needed for modeling and predicting the temporal microstructure and property evolution during materials processing but have not yet been addressed by quantitative experimental measurement. This article focuses on the Bi n +1 Fe n –3 Ti 3 O 3 n +3 Aurivillius compounds on the Bi 4 Ti 3 O 12 –BiFeO 3 tie‐line to elucidate the mechanisms and thermodynamic controls responsible for phase formation of compounds with various perovskite‐like layers. Five high‐purity Aurivillius compounds Bi 4 Ti 3 O 12 , Bi 5 FeTi 3 O 15 , Bi 6 Fe 2 Ti 3 O 18 , Bi 7 Fe 3 Ti 3 O 21 , and Bi 8 Fe 4 Ti 3 O 24 with integer n = 3–7 values were synthesized and their phase transformation properties and enthalpies of formation were studied by X‐ray diffraction in situ, high temperature differential scanning calorimetry, and high temperature oxide melt solution calorimetry. Thermodynamic stability of the compounds decreases with increasing n , and formation kinetics gradually slow down, demonstrating the inherent difficulty to synthesize pure Aurivillius compounds with n larger than 8. This difficulty was confirmed by an impurity phase coexisting with Bi 9 Fe 5 Ti 3 O 27 . Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have attracted particular interest. Formation kinetics and thermodynamic stability are the fundamental knowledge needed for modeling and predicting the temporal microstructure and property evolution during materials processing but have not yet been addressed by quantitative experimental measurement. This article focuses on the Bi n +1 Fe n –3 Ti 3 O 3 n +3 Aurivillius compounds on the Bi 4 Ti 3 O 12 –BiFeO 3 tie‐line to elucidate the mechanisms and thermodynamic controls responsible for phase formation of compounds with various perovskite‐like layers. Five high‐purity Aurivillius compounds Bi 4 Ti 3 O 12 , Bi 5 FeTi 3 O 15 , Bi 6 Fe 2 Ti 3 O 18 , Bi 7 Fe 3 Ti 3 O 21 , and Bi 8 Fe 4 Ti 3 O 24 with integer n = 3–7 values were synthesized and their phase transformation properties and enthalpies of formation were studied by X‐ray diffraction in situ, high temperature differential scanning calorimetry, and high temperature oxide melt solution calorimetry. Thermodynamic stability of the compounds decreases with increasing n , and formation kinetics gradually slow down, demonstrating the inherent difficulty to synthesize pure Aurivillius compounds with n larger than 8. This difficulty was confirmed by an impurity phase coexisting with Bi 9 Fe 5 Ti 3 O 27 . |
| Author | Li, Kai Gong, Weiping Zhang, Duoduo Xiao, Lang Wang, Ting Zhao, Jiahui Scharrer, Manuel Zhao, Zhentin Navrotsky, Alexandra |
| Author_xml | – sequence: 1 givenname: Weiping orcidid: 0000-0002-3761-2671 surname: Gong fullname: Gong, Weiping organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 2 givenname: Duoduo surname: Zhang fullname: Zhang, Duoduo organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 3 givenname: Lang surname: Xiao fullname: Xiao, Lang organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China, School of Materials Science and Engineering Xiangtan University Xiangtan Hunan China – sequence: 4 givenname: Jiahui surname: Zhao fullname: Zhao, Jiahui organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 5 givenname: Ting surname: Wang fullname: Wang, Ting organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 6 givenname: Kai surname: Li fullname: Li, Kai organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 7 givenname: Zhentin surname: Zhao fullname: Zhao, Zhentin organization: Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices Huizhou University Huizhou Guangdong China – sequence: 8 givenname: Manuel surname: Scharrer fullname: Scharrer, Manuel organization: School of Molecular Sciences and Navrotsky Eyring Center for Materials of the Universe Arizona State University Tempe Arizona USA – sequence: 9 givenname: Alexandra orcidid: 0000-0002-3260-0364 surname: Navrotsky fullname: Navrotsky, Alexandra organization: School of Molecular Sciences and Navrotsky Eyring Center for Materials of the Universe Arizona State University Tempe Arizona USA |
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| Snippet | Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have... Abstract The Aurivillius compounds in the Bi 2 O 3 –Fe 2 O 3 –TiO 2 system, combining ferroelectric, semiconducting, and ferromagnetic properties, have... |
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| Title | Formation kinetics and thermodynamic stability of the Aurivillius compounds in Bi 4 Ti 3 O 12 –BiFeO 3 system |
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