Role of Nb 2 O 5 Crystal Phases on the Photocatalytic Conversion of Lignin Model Molecules and Selectivity for Value-Added Products
The photocatalytic conversion in aqueous media of phenol and guaiacol as a lignin model compound using Nb O with different crystal phases was studied. Nb O particles were synthesized using hydrothermal methods, where it was observed that changes in the solvent control their morphology and crystal ph...
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| Published in | ChemSusChem Vol. 17; no. 14; p. e202301594 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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22.07.2024
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| Abstract | The photocatalytic conversion in aqueous media of phenol and guaiacol as a lignin model compound using Nb
O
with different crystal phases was studied. Nb
O
particles were synthesized using hydrothermal methods, where it was observed that changes in the solvent control their morphology and crystal phase. Different photocatalytic behavior of Nb
O
was observed with the selected model compounds, indicating that its selection directly impacts the resulting conversion and selectivity rates as well as the reaction pathway, highlighting the relevance of model molecule selection. Photocatalytic conversion of phenol showed conversion rate (C%) up to 25 % after 2 h irradiation and high selectivity (S%) to pyrogallol (up to 50 %). Orthorhombic Nb
O
spheres favored conversion through free hydroxyl radicals while monoclinic rods did not convert phenol. Guaiacol photocatalytic oxidation showed high conversion rate but lower selectivity. Orthorhombic and monoclinic Nb
O
favored the formation of resorcinol with S % ~0.43 % (C % ~33 %) and ~13 % (C % ~27 %) respectively. The mixture of both phases enhanced the guaiacol conversion rate to ~55 % with ~17 % of selectivity to salicylaldehyde. The use of radical scavengers provided information to elucidate the reaction pathway for these model compounds, showing that different reaction pathways may be obtained for the same photocatalyst if the model compound is changed. |
|---|---|
| AbstractList | The photocatalytic conversion in aqueous media of phenol and guaiacol as a lignin model compound using Nb
O
with different crystal phases was studied. Nb
O
particles were synthesized using hydrothermal methods, where it was observed that changes in the solvent control their morphology and crystal phase. Different photocatalytic behavior of Nb
O
was observed with the selected model compounds, indicating that its selection directly impacts the resulting conversion and selectivity rates as well as the reaction pathway, highlighting the relevance of model molecule selection. Photocatalytic conversion of phenol showed conversion rate (C%) up to 25 % after 2 h irradiation and high selectivity (S%) to pyrogallol (up to 50 %). Orthorhombic Nb
O
spheres favored conversion through free hydroxyl radicals while monoclinic rods did not convert phenol. Guaiacol photocatalytic oxidation showed high conversion rate but lower selectivity. Orthorhombic and monoclinic Nb
O
favored the formation of resorcinol with S % ~0.43 % (C % ~33 %) and ~13 % (C % ~27 %) respectively. The mixture of both phases enhanced the guaiacol conversion rate to ~55 % with ~17 % of selectivity to salicylaldehyde. The use of radical scavengers provided information to elucidate the reaction pathway for these model compounds, showing that different reaction pathways may be obtained for the same photocatalyst if the model compound is changed. Abstract The photocatalytic conversion in aqueous media of phenol and guaiacol as a lignin model compound using Nb 2 O 5 with different crystal phases was studied. Nb 2 O 5 particles were synthesized using hydrothermal methods, where it was observed that changes in the solvent control their morphology and crystal phase. Different photocatalytic behavior of Nb 2 O 5 was observed with the selected model compounds, indicating that its selection directly impacts the resulting conversion and selectivity rates as well as the reaction pathway, highlighting the relevance of model molecule selection. Photocatalytic conversion of phenol showed conversion rate (C%) up to 25 % after 2 h irradiation and high selectivity (S%) to pyrogallol (up to 50 %). Orthorhombic Nb 2 O 5 spheres favored conversion through free hydroxyl radicals while monoclinic rods did not convert phenol. Guaiacol photocatalytic oxidation showed high conversion rate but lower selectivity. Orthorhombic and monoclinic Nb 2 O 5 favored the formation of resorcinol with S % ~0.43 % (C % ~33 %) and ~13 % (C % ~27 %) respectively. The mixture of both phases enhanced the guaiacol conversion rate to ~55 % with ~17 % of selectivity to salicylaldehyde. The use of radical scavengers provided information to elucidate the reaction pathway for these model compounds, showing that different reaction pathways may be obtained for the same photocatalyst if the model compound is changed. |
| Author | Rafaela, Gabriela Rojas, Susana D Espinoza-Villalobos, Nicole Escalona, Néstor Barrientos, Lorena Salazar-González, Ricardo Caceres-Jensen, Lizethly Diaz-Droguett, Donovan E |
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| Keywords | high value products crystal phase photocatalytic conversion hydroxyl radical lignin model compounds |
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with different crystal phases was studied. Nb
O... Abstract The photocatalytic conversion in aqueous media of phenol and guaiacol as a lignin model compound using Nb 2 O 5 with different crystal phases was... |
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| Title | Role of Nb 2 O 5 Crystal Phases on the Photocatalytic Conversion of Lignin Model Molecules and Selectivity for Value-Added Products |
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