Entropy-driven formation of large icosahedral colloidal clusters by spherical confinement
Experiments with colloidal nano- and microparticles and computer simulations show that, unexpectedly, confinement and entropy are sufficient for the formation of icosahedral crystalline clusters of up to about 100,000 particles. Icosahedral symmetry, which is not compatible with truly long-range ord...
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Published in | Nature materials Vol. 14; no. 1; pp. 56 - 60 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
London
Nature Publishing Group UK
01.01.2015
Nature Publishing Group |
Subjects | |
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Abstract | Experiments with colloidal nano- and microparticles and computer simulations show that, unexpectedly, confinement and entropy are sufficient for the formation of icosahedral crystalline clusters of up to about 100,000 particles.
Icosahedral symmetry, which is not compatible with truly long-range order, can be found in many systems, such as liquids, glasses, atomic clusters, quasicrystals and virus-capsids
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. To obtain arrangements with a high degree of icosahedral order from tens of particles or more, interparticle attractive interactions are considered to be essential
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. Here, we report that entropy and spherical confinement suffice for the formation of icosahedral clusters consisting of up to 100,000 particles. Specifically, by using real-space measurements on nanometre- and micrometre-sized colloids, as well as computer simulations, we show that tens of thousands of hard spheres compressed under spherical confinement spontaneously crystallize into icosahedral clusters that are entropically favoured over the bulk face-centred cubic crystal structure
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. Our findings provide insights into the interplay between confinement and crystallization and into how these are connected to the formation of icosahedral structures. |
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AbstractList | Icosahedral symmetry, which is not compatible with truly long-range order, can be found in many systems, such as liquids, glasses, atomic clusters, quasicrystals and virus-capsids. To obtain arrangements with a high degree of icosahedral order from tens of particles or more, interparticle attractive interactions are considered to be essential. Here, we report that entropy and spherical confinement suffice for the formation of icosahedral clusters consisting of up to 100,000 particles. Specifically, by using real-space measurements on nanometre- and micrometre-sized colloids, as well as computer simulations, we show that tens of thousands of hard spheres compressed under spherical confinement spontaneously crystallize into icosahedral clusters that are entropically favoured over the bulk face-centred cubic crystal structure. Our findings provide insights into the interplay between confinement and crystallization and into how these are connected to the formation of icosahedral structures. Experiments with colloidal nano- and microparticles and computer simulations show that, unexpectedly, confinement and entropy are sufficient for the formation of icosahedral crystalline clusters of up to about 100,000 particles. De Nijs et al report that entropy and spherical confinement suffice for the formation of icosahedral clusters consisting of up to 100,000 particles. Experiments with colloidal nano- and microparticles and computer simulations show that, unexpectedly, confinement and entropy are sufficient for the formation of icosahedral crystalline clusters of up to about 100,000 particles. Icosahedral symmetry, which is not compatible with truly long-range order, can be found in many systems, such as liquids, glasses, atomic clusters, quasicrystals and virus-capsids 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 . To obtain arrangements with a high degree of icosahedral order from tens of particles or more, interparticle attractive interactions are considered to be essential 1 , 3 , 6 , 7 , 8 , 9 , 10 , 11 , 12 . Here, we report that entropy and spherical confinement suffice for the formation of icosahedral clusters consisting of up to 100,000 particles. Specifically, by using real-space measurements on nanometre- and micrometre-sized colloids, as well as computer simulations, we show that tens of thousands of hard spheres compressed under spherical confinement spontaneously crystallize into icosahedral clusters that are entropically favoured over the bulk face-centred cubic crystal structure 13 , 14 . Our findings provide insights into the interplay between confinement and crystallization and into how these are connected to the formation of icosahedral structures. |
Author | Groenendijk, Dirk J. de Nijs, Bart Imhof, Arnout Dussi, Simone Meeldijk, Johannes D. Smallenburg, Frank van Blaaderen, Alfons Filion, Laura Dijkstra, Marjolein |
Author_xml | – sequence: 1 givenname: Bart surname: de Nijs fullname: de Nijs, Bart organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 2 givenname: Simone surname: Dussi fullname: Dussi, Simone organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 3 givenname: Frank surname: Smallenburg fullname: Smallenburg, Frank organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 4 givenname: Johannes D. surname: Meeldijk fullname: Meeldijk, Johannes D. organization: Electron Microscopy Group, Utrecht University – sequence: 5 givenname: Dirk J. surname: Groenendijk fullname: Groenendijk, Dirk J. organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 6 givenname: Laura surname: Filion fullname: Filion, Laura organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 7 givenname: Arnout surname: Imhof fullname: Imhof, Arnout organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 8 givenname: Alfons surname: van Blaaderen fullname: van Blaaderen, Alfons email: A.vanBlaaderen@uu.nl organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University – sequence: 9 givenname: Marjolein surname: Dijkstra fullname: Dijkstra, Marjolein email: M.Dijkstra1@uu.nl organization: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25173580$$D View this record in MEDLINE/PubMed |
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PublicationPlace | London |
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PublicationTitle | Nature materials |
PublicationTitleAbbrev | Nature Mater |
PublicationTitleAlternate | Nat Mater |
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Publisher | Nature Publishing Group UK Nature Publishing Group |
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Snippet | Experiments with colloidal nano- and microparticles and computer simulations show that, unexpectedly, confinement and entropy are sufficient for the formation... Icosahedral symmetry, which is not compatible with truly long-range order, can be found in many systems, such as liquids, glasses, atomic clusters,... |
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SubjectTerms | 639/766/119/1002 639/925/357/354 Biomaterials Clusters Colloids Condensed Matter Physics Confinement Crystallization Crystals Entropy Formations Icosahedral phase letter Long range order Materials Science Nanoparticles Nanostructure Nanotechnology Optical and Electronic Materials |
Title | Entropy-driven formation of large icosahedral colloidal clusters by spherical confinement |
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