Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)

Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in t...

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Published inPure and applied chemistry Vol. 87; no. 11; pp. 1139 - 1150
Main Authors Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merényi, Gábor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, Wardman, Peter
Format Journal Article
LanguageEnglish
Published Berlin De Gruyter 01.12.2015
Walter de Gruyter GmbH
de Gruyter
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Online AccessGet full text
ISSN0033-4545
1365-3075
1365-3075
DOI10.1515/pac-2014-0502

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Abstract Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
AbstractList Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degree C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa's, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p K a ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK(a)'s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
Author Merényi, Gábor
Ruscic, Branko
Huie, Robert E.
Stanbury, David M.
Steenken, Steen
Wardman, Peter
Armstrong, David A.
Lymar, Sergei V.
Neta, Pedatsur
Koppenol, Willem H.
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  givenname: David A.
  surname: Armstrong
  fullname: Armstrong, David A.
  organization: Department of Chemistry, University of Calgary, Alberta, Canada
– sequence: 2
  givenname: Robert E.
  surname: Huie
  fullname: Huie, Robert E.
  organization: National Institute of Standards and Technology, Formerly of the Physical and Chemical Properties Division, Gaithersburg, MD 20899, USA
– sequence: 3
  givenname: Willem H.
  surname: Koppenol
  fullname: Koppenol, Willem H.
  organization: Institute of Inorganic Chemistry, Swiss Federal Institute of Technology, CH-8093 Zürich, Switzerland
– sequence: 4
  givenname: Sergei V.
  surname: Lymar
  fullname: Lymar, Sergei V.
  organization: Brookhaven National Laboratory, Chemistry Department, Upton NY 11973, USA
– sequence: 5
  givenname: Gábor
  surname: Merényi
  fullname: Merényi, Gábor
  organization: The Royal Institute of Technology, Department of Applied Physical Chemistry, S-10044, Stockholm 70, Sweden
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  surname: Neta
  fullname: Neta, Pedatsur
  organization: National Institute of Standards and Technology, Physical and Chemical Properties Division, Gaithersburg, MD 20899, USA
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  givenname: Branko
  surname: Ruscic
  fullname: Ruscic, Branko
  organization: Argonne National Laboratory, Chemical Sciences and Engineering Division, Argonne, IL, 60439, USA, and Computation Institute, University of Chicago, Chicago, IL, 60637, USA
– sequence: 8
  givenname: David M.
  surname: Stanbury
  fullname: Stanbury, David M.
  email: stanbdm@auburn.edu
  organization: Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849, USA
– sequence: 9
  givenname: Steen
  surname: Steenken
  fullname: Steenken, Steen
  organization: Formerly of Max-Planck-Institute für Strahlenchemie, D-45413 Mülheim, Germany
– sequence: 10
  givenname: Peter
  surname: Wardman
  fullname: Wardman, Peter
  organization: 0Gray Cancer Institute, Department of Oncology, Formerly of the University of Oxford, Old Road Campus Research Building, Roosevelt Drive, Oxford OX3 7DQ, UK
BackLink https://www.osti.gov/biblio/1236950$$D View this record in Osti.gov
https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-180120$$DView record from Swedish Publication Index
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10.1021/jp803230c
10.1063/1.555843
10.1515/irm-2013-0005
10.1351/pac200072030437
10.1016/S0898-8838(08)60194-4
10.1002/qua.24605
10.1021/cr100085k
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Snippet Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a...
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degree C. These recommendations are based on a...
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a...
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SubjectTerms Active Thermochemical Tables
Aqueous solutions
aqueous thermochemistry
Chemical equilibrium
chemical thermodynamics
Chemistry
Data sheets
Derivation
electrode potentials
enthalpy of formation
Free energy
Heat of formation
inorganic chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
IUPAC Physical and Biophysical Chemistry Division
Literature reviews
oxidation
Radicals
Recommendations
standard electrode potentials
Tables
Thermochemical Network
thermochemistry
Title Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
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