Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in t...
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Published in | Pure and applied chemistry Vol. 87; no. 11; pp. 1139 - 1150 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Berlin
De Gruyter
01.12.2015
Walter de Gruyter GmbH de Gruyter |
Subjects | |
Online Access | Get full text |
ISSN | 0033-4545 1365-3075 1365-3075 |
DOI | 10.1515/pac-2014-0502 |
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Abstract | Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p
’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. |
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AbstractList | Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degree C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa's, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p K a ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK(a)'s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations. |
Author | Merényi, Gábor Ruscic, Branko Huie, Robert E. Stanbury, David M. Steenken, Steen Wardman, Peter Armstrong, David A. Lymar, Sergei V. Neta, Pedatsur Koppenol, Willem H. |
Author_xml | – sequence: 1 givenname: David A. surname: Armstrong fullname: Armstrong, David A. organization: Department of Chemistry, University of Calgary, Alberta, Canada – sequence: 2 givenname: Robert E. surname: Huie fullname: Huie, Robert E. organization: National Institute of Standards and Technology, Formerly of the Physical and Chemical Properties Division, Gaithersburg, MD 20899, USA – sequence: 3 givenname: Willem H. surname: Koppenol fullname: Koppenol, Willem H. organization: Institute of Inorganic Chemistry, Swiss Federal Institute of Technology, CH-8093 Zürich, Switzerland – sequence: 4 givenname: Sergei V. surname: Lymar fullname: Lymar, Sergei V. organization: Brookhaven National Laboratory, Chemistry Department, Upton NY 11973, USA – sequence: 5 givenname: Gábor surname: Merényi fullname: Merényi, Gábor organization: The Royal Institute of Technology, Department of Applied Physical Chemistry, S-10044, Stockholm 70, Sweden – sequence: 6 givenname: Pedatsur surname: Neta fullname: Neta, Pedatsur organization: National Institute of Standards and Technology, Physical and Chemical Properties Division, Gaithersburg, MD 20899, USA – sequence: 7 givenname: Branko surname: Ruscic fullname: Ruscic, Branko organization: Argonne National Laboratory, Chemical Sciences and Engineering Division, Argonne, IL, 60439, USA, and Computation Institute, University of Chicago, Chicago, IL, 60637, USA – sequence: 8 givenname: David M. surname: Stanbury fullname: Stanbury, David M. email: stanbdm@auburn.edu organization: Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849, USA – sequence: 9 givenname: Steen surname: Steenken fullname: Steenken, Steen organization: Formerly of Max-Planck-Institute für Strahlenchemie, D-45413 Mülheim, Germany – sequence: 10 givenname: Peter surname: Wardman fullname: Wardman, Peter organization: 0Gray Cancer Institute, Department of Oncology, Formerly of the University of Oxford, Old Road Campus Research Building, Roosevelt Drive, Oxford OX3 7DQ, UK |
BackLink | https://www.osti.gov/biblio/1236950$$D View this record in Osti.gov https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-180120$$DView record from Swedish Publication Index |
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Cites_doi | 10.1021/jp047912y 10.1021/jp803230c 10.1063/1.555843 10.1515/irm-2013-0005 10.1351/pac200072030437 10.1016/S0898-8838(08)60194-4 10.1002/qua.24605 10.1021/cr100085k |
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Snippet | Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a... Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degree C. These recommendations are based on a... Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a... |
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Title | Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report) |
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