Understanding volumetric capacitance in conducting polymers
ABSTRACT Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from t...
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| Published in | Journal of polymer science. Part B, Polymer physics Vol. 54; no. 15; pp. 1433 - 1436 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken
Blackwell Publishing Ltd
01.08.2016
Wiley Subscription Services, Inc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | ABSTRACT
Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from the electrolyte replace holes that are extracted from the film by a metal contact. We propose that volumetric capacitance is inversely proportional to the average distance between these sites. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 1433–1436
A simple model is presented that shows how volumetric capacitance in conducting polymer films arises through the processes of cation injection and hole extraction. It is in agreement with recent measurements of volumetric capacitance in PEDOT:PSS. |
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| AbstractList | Recent measurements in poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from the electrolyte replace holes that are extracted from the film by a metal contact. We propose that volumetric capacitance is inversely proportional to the average distance between these sites. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 1433-1436 A simple model is presented that shows how volumetric capacitance in conducting polymer films arises through the processes of cation injection and hole extraction. It is in agreement with recent measurements of volumetric capacitance in PEDOT:PSS. ABSTRACT Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from the electrolyte replace holes that are extracted from the film by a metal contact. We propose that volumetric capacitance is inversely proportional to the average distance between these sites. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 1433–1436 A simple model is presented that shows how volumetric capacitance in conducting polymer films arises through the processes of cation injection and hole extraction. It is in agreement with recent measurements of volumetric capacitance in PEDOT:PSS. Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from the electrolyte replace holes that are extracted from the film by a metal contact. We propose that volumetric capacitance is inversely proportional to the average distance between these sites. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 1433–1436 Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the ramifications of this finding and propose a simple model that describes capacitance in terms of sites in which ions injected from the electrolyte replace holes that are extracted from the film by a metal contact. We propose that volumetric capacitance is inversely proportional to the average distance between these sites. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54 , 1433–1436 |
| Author | Rivnay, Jonathan Proctor, Christopher M. Malliaras, George G. |
| Author_xml | – sequence: 1 givenname: Christopher M. surname: Proctor fullname: Proctor, Christopher M. organization: Department of Bioelectronics, Ecole Nationale Supérieure des Mines, CMP-EMSE, MOC, 13541, Gardanne, France – sequence: 2 givenname: Jonathan surname: Rivnay fullname: Rivnay, Jonathan organization: Department of Bioelectronics, Ecole Nationale Supérieure des Mines, CMP-EMSE, MOC, 13541, Gardanne, France – sequence: 3 givenname: George G. surname: Malliaras fullname: Malliaras, George G. email: malliaras@emse.fr organization: Department of Bioelectronics, Ecole Nationale Supérieure des Mines, CMP-EMSE, MOC, 13541, Gardanne, France |
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| Snippet | ABSTRACT
Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We... Recent measurements in poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the... Recent measurements in poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films show that capacitance scales with film volume. We discuss the... |
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| SubjectTerms | Balances (scales) bioelectronics Capacitance Conducting polymers Contact electrochemical impedance Electrolytes Extraction ions Mathematical models mixed conductivity organic bioelectronics Polymer physics polymers styrene |
| Title | Understanding volumetric capacitance in conducting polymers |
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