Reversal Circularly Polarized Luminescence of AIE-Active Chiral Binaphthyl Molecules from Solution to Aggregation
Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the differe...
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| Published in | Chemistry : a European journal Vol. 21; no. 38; pp. 13196 - 13200 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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WILEY-VCH Verlag
14.09.2015
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| Abstract | Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis‐conformation in pure THF solution to trans‐conformation in THF/water mixtures.
The closing scene: Four aggregation‐ induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis‐conformation in pure THF solution to trans‐conformation in THF/water mixtures. |
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| AbstractList | Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis‐conformation in pure THF solution to trans‐conformation in THF/water mixtures.
The closing scene: Four aggregation‐ induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis‐conformation in pure THF solution to trans‐conformation in THF/water mixtures. Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures. Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures. The closing scene: Four aggregation- induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures. Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, ( R / S )‐ 1 and ( R / S )‐ 2 , were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis ‐conformation in pure THF solution to trans ‐conformation in THF/water mixtures. |
| Author | Zhang, Hongxing Zhang, Wenjie Zhu, Chengjian Cheng, Yixiang Sheng, Yuan Shen, Dong |
| Author_xml | – sequence: 1 givenname: Yuan surname: Sheng fullname: Sheng, Yuan organization: Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China) – sequence: 2 givenname: Dong surname: Shen fullname: Shen, Dong organization: Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China) – sequence: 3 givenname: Wenjie surname: Zhang fullname: Zhang, Wenjie organization: Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China) – sequence: 4 givenname: Hongxing surname: Zhang fullname: Zhang, Hongxing email: zhanghx@mail.jlu.edu.cn organization: Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China) – sequence: 5 givenname: Chengjian surname: Zhu fullname: Zhu, Chengjian email: yxcheng@nju.edu.cn organization: Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China) – sequence: 6 givenname: Yixiang surname: Cheng fullname: Cheng, Yixiang email: cjzhu@nju.edu.cn organization: Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China) |
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| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | configuration inversion circular dichroism circularly polarized luminescence 1-binaphthol DENSITY 1 INDUCED EMISSION SPECTROSCOPY AXIAL CHIRALITY DICHROISM aggregation-induced emission ENERGY-TRANSFER LUMINOGEN DERIVATIVES 1,1′-binaphthol |
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| Notes | ArticleID:CHEM201502193 ark:/67375/WNG-PC3ZXP7P-T National Natural Science Foundation of China - No. 21174061; No. 51173078; No. 21172106; No. 21474048; No. Beijing National Laboratory for Molecular Sciences istex:09AB47A056C832D1910BBAB54025203736A32D85 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| Snippet | Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, (R/S)‐1 and (R/S)‐2, were designed and synthesized. Interestingly, all of... Four aggregation‐induced emission (AIE)‐active chiral binaphthyl‐based molecules, ( R / S )‐ 1 and ( R / S )‐ 2 , were designed and synthesized. Interestingly,... Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of... |
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| SubjectTerms | 1,1′‐binaphthol 1′-binaphthol Agglomeration aggregation-induced emission Chemistry Chemistry, Multidisciplinary circular dichroism Circularity circularly polarized luminescence configuration inversion Dihedral angle Emission Luminescence Physical Sciences Science & Technology |
| Title | Reversal Circularly Polarized Luminescence of AIE-Active Chiral Binaphthyl Molecules from Solution to Aggregation |
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