通过聚苯的磺化和碳化制备酸性树脂-碳复合材料

O643; 用浓硫酸在170℃下处理聚苯,发生了磺化和碳化过程,生成了一种酸性树脂-碳复合材料.其比表面积为14 m2/g,与磺酸基相关的强酸量为1.2 mmol/g,氨吸附量热测定的起始吸附热较高,表明表面磺酸基没有形成焦硫酸根;部分磺酸基在400℃以上才开始分解,表现出很高的热稳定性.该强酸性复合材料在异戊烯与甲醇醚化生成甲基叔戊基醚的反应中显示出较高的催化活性,优于用葡萄糖碳化和磺化得到的强酸性碳材料....

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Published inChinese journal of catalysis Vol. 32; no. 4; pp. 688 - 692
Main Author 赵鹬 冯宏枢 谢建新 沈俭一
Format Journal Article
LanguageChinese
Published 南京大学化学化工学院,教育部介观化学重点实验室,江苏南京,210093 2011
Subjects
甲基叔戊基醚
碳化
磺化
聚苯
酸性树脂-碳材料
醚化
磺化
聚苯
碳化
醚化
甲基叔戊基醚
酸性树脂-碳材料
Online AccessGet full text
ISSN0253-9837
1872-2067
DOI10.3724/SP.J.1088.2011.01204

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Abstract O643; 用浓硫酸在170℃下处理聚苯,发生了磺化和碳化过程,生成了一种酸性树脂-碳复合材料.其比表面积为14 m2/g,与磺酸基相关的强酸量为1.2 mmol/g,氨吸附量热测定的起始吸附热较高,表明表面磺酸基没有形成焦硫酸根;部分磺酸基在400℃以上才开始分解,表现出很高的热稳定性.该强酸性复合材料在异戊烯与甲醇醚化生成甲基叔戊基醚的反应中显示出较高的催化活性,优于用葡萄糖碳化和磺化得到的强酸性碳材料.
AbstractList O643; 用浓硫酸在170℃下处理聚苯,发生了磺化和碳化过程,生成了一种酸性树脂-碳复合材料.其比表面积为14 m2/g,与磺酸基相关的强酸量为1.2 mmol/g,氨吸附量热测定的起始吸附热较高,表明表面磺酸基没有形成焦硫酸根;部分磺酸基在400℃以上才开始分解,表现出很高的热稳定性.该强酸性复合材料在异戊烯与甲醇醚化生成甲基叔戊基醚的反应中显示出较高的催化活性,优于用葡萄糖碳化和磺化得到的强酸性碳材料.
用浓硫酸在170℃下处理聚苯,发生了磺化和碳化过程,生成了一种酸性树脂-碳复合材料.其比表面积为14m2/g,与磺酸基相关的强酸量为1.2mmol/g,氨吸附量热测定的起始吸附热较高,表明表面磺酸基没有形成焦硫酸根;部分磺酸基在400℃以上才开始分解,表现出很高的热稳定性.该强酸性复合材料在异戊烯与甲醇醚化生成甲基叔戊基醚的反应中显示出较高的催化活性,优于用葡萄糖碳化和磺化得到的强酸性碳材料.
Author 赵鹬 冯宏枢 谢建新 沈俭一
AuthorAffiliation 南京大学化学化工学院,教育部介观化学重点实验室,江苏南京210093
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FENG Hongshu
ZHAO Yu
XIE Jianxin
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Keywords 磺化
聚苯
碳化
醚化
甲基叔戊基醚
酸性树脂-碳材料
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O643; 用浓硫酸在170℃下处理聚苯,发生了磺化和碳化过程,生成了一种酸性树脂-碳复合材料.其比表面积为14 m2/g,与磺酸基相关的强酸量为1.2...
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SubjectTerms 甲基叔戊基醚
碳化
磺化
聚苯
酸性树脂-碳材料
醚化
Title 通过聚苯的磺化和碳化制备酸性树脂-碳复合材料
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