Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles
Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved partic...
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| Published in | Nature communications Vol. 8; no. 1; pp. 1855 - 8 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
30.11.2017
Nature Publishing Group Nature Portfolio |
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| Online Access | Get full text |
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| Abstract | Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity.
Metal nanoparticles prepared by exsolution at the surface of perovskite oxides are key species in catalysis and energy fields. Here, the authors develop a chemistry at a point concept by tracking individual nanoparticles with excellent activity and stability throughout various chemical transformations. |
|---|---|
| AbstractList | Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity.
Metal nanoparticles prepared by exsolution at the surface of perovskite oxides are key species in catalysis and energy fields. Here, the authors develop a chemistry at a point concept by tracking individual nanoparticles with excellent activity and stability throughout various chemical transformations. Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity.Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity. Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity. Metal nanoparticles prepared by exsolution at the surface of perovskite oxides are key species in catalysis and energy fields. Here, the authors develop a chemistry at a point concept by tracking individual nanoparticles with excellent activity and stability throughout various chemical transformations. |
| ArticleNumber | 1855 |
| Author | Ménard, Hervé Neagu, Dragos Umar, Ahmed Murdoch, Billy J. Metcalfe, Ian S. Miller, David N. Ramli, Wan K. W. Irvine, John T. S. Cumpson, Peter J. Barlow, Anders J. Papaioannou, Evangelos I. |
| Author_xml | – sequence: 1 givenname: Dragos orcidid: 0000-0001-7208-1055 surname: Neagu fullname: Neagu, Dragos organization: School of Chemistry, University of St Andrews – sequence: 2 givenname: Evangelos I. surname: Papaioannou fullname: Papaioannou, Evangelos I. organization: School of Engineering, Newcastle University – sequence: 3 givenname: Wan K. W. surname: Ramli fullname: Ramli, Wan K. W. organization: School of Engineering, Newcastle University, School of Bioprocess Engineering, University Malaysia Perlis – sequence: 4 givenname: David N. surname: Miller fullname: Miller, David N. organization: School of Chemistry, University of St Andrews – sequence: 5 givenname: Billy J. surname: Murdoch fullname: Murdoch, Billy J. organization: National EPSRC XPS Users’ Service (NEXUS), School of Mechanical and Systems Engineering, Newcastle University – sequence: 6 givenname: Hervé surname: Ménard fullname: Ménard, Hervé organization: Sasol (UK) Ltd – sequence: 7 givenname: Ahmed surname: Umar fullname: Umar, Ahmed organization: School of Chemistry, University of St Andrews – sequence: 8 givenname: Anders J. surname: Barlow fullname: Barlow, Anders J. organization: National EPSRC XPS Users’ Service (NEXUS), School of Mechanical and Systems Engineering, Newcastle University – sequence: 9 givenname: Peter J. surname: Cumpson fullname: Cumpson, Peter J. organization: National EPSRC XPS Users’ Service (NEXUS), School of Mechanical and Systems Engineering, Newcastle University – sequence: 10 givenname: John T. S. orcidid: 0000-0002-8394-3359 surname: Irvine fullname: Irvine, John T. S. email: jtsi@st-and.ac.uk organization: School of Chemistry, University of St Andrews – sequence: 11 givenname: Ian S. surname: Metcalfe fullname: Metcalfe, Ian S. email: ian.metcalfe@newcastle.ac.uk organization: School of Engineering, Newcastle University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29187751$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/j.nanoen.2016.07.013 10.1016/j.jcat.2016.01.020 10.1021/acscatal.5b02296 10.1126/science.1096566 10.1016/j.apcatb.2017.03.047 10.1002/anie.200503938 10.1021/jp402939e 10.1038/nature00893 10.1039/c3nr02877a 10.1038/nmat3159 10.1021/acscatal.6b01555 10.1039/C7TA00349H 10.1016/j.apcata.2012.04.006 10.1016/j.cplett.2008.12.066 10.1016/S0021-9517(02)93738-3 10.1038/nature19090 10.1038/nchem.1773 10.1016/j.jpowsour.2006.12.080 10.1021/acscatal.6b03604 10.1016/S0968-4328(99)00139-0 10.1038/nmat4465 10.1016/0021-9517(85)90092-2 10.1038/nature22086 10.1038/ncomms9120 10.1021/acscatal.6b01466 10.1021/acscatal.5b01452 10.1021/acscatal.6b00081 10.1016/j.jcat.2012.06.017 10.1038/ncomms14785 10.1021/cr500032a 10.1039/a701383c 10.1002/cctc.201000378 10.1021/ja110073u 10.1126/science.1240148 10.1039/C6TA06365A 10.1016/j.nanoen.2014.12.001 10.1126/science.1184087 10.1021/acs.nanolett.5b04160 10.1021/ja4088743 10.1038/nchem.623 10.1007/s12274-010-1040-2 10.1038/srep05156 10.1021/acs.jpclett.5b02292 |
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| References | Nishihata (CR2) 2002; 418 Neagu (CR5) 2015; 6 Myung, Neagu, Miller, Irvine (CR19) 2016; 537 Asano, Kawamura, Sasakawa, Todoroki, Wadayama (CR29) 2016; 6 Royer (CR41) 2014; 114 Shiozaki (CR1) 1997; 93 Yin (CR23) 2004; 304 Liu, Liu, Luo (CR12) 2016; 6 Yang (CR7) 2015; 11 Kim, Qi, Dahlberg, Li (CR40) 2010; 327 Zubenko, Singh, Rosen (CR14) 2017; 209 Sun, Li, Zhang, Hua, Luo (CR8) 2016; 6 An (CR27) 2013; 135 Strasser (CR31) 2010; 2 Royer, Duprez (CR35) 2011; 3 Allian (CR38) 2011; 133 Herz, Sell (CR39) 1985; 94 Alvarez, Ivanova, Centeno, Odriozola (CR36) 2012; 431–432 Liu, Chuang, Luo (CR6) 2015; 6 Wei (CR13) 2014; 4 Dai, Zhang, Katz, Graham, Pan (CR22) 2017; 7 Jansson (CR37) 2002; 211 Sadasivan, Bellabarba, Tooze (CR25) 2013; 5 Li (CR30) 2016; 15 Neagu, Tsekouras, Miller, Ménard, Irvine (CR4) 2013; 5 Iablokov (CR32) 2015; 5 Madsen, Kobsiriphat, Wang, Marks, Barnett (CR3) 2007; 166 Ye (CR18) 2017; 8 Zhu (CR9) 2016; 16 Hu, Sun, Peng, Xu, Li (CR33) 2010; 3 Wang, Yin, Jiang (CR43) 2000; 31 Anenberg (CR26) 2017; 545 Thalinger (CR17) 2016; 337 Cargnello (CR34) 2013; 341 Gao, Chen, Saccoccio, Lu, Ciucci (CR10) 2016; 27 Ha, Moreau, Honrao, Hennig, Robinson (CR24) 2013; 117 Liu, Liu, Luo (CR11) 2016; 4 Gao, Wang, Lyu, Lam, Ciucci (CR15) 2017; 5 Katz (CR21) 2012; 293 Greiner (CR42) 2012; 11 McClure, Goodman (CR28) 2009; 469 Tanaka (CR20) 2006; 45 Oh (CR16) 2015; 6 S Sadasivan (1880_CR25) 2013; 5 D Neagu (1880_CR5) 2015; 6 Y Gao (1880_CR10) 2016; 27 R Thalinger (1880_CR17) 2016; 337 MT Greiner (1880_CR42) 2012; 11 H Tanaka (1880_CR20) 2006; 45 L Hu (1880_CR33) 2010; 3 RK Herz (1880_CR39) 1985; 94 A Alvarez (1880_CR36) 2012; 431–432 AD Allian (1880_CR38) 2011; 133 L Ye (1880_CR18) 2017; 8 V Iablokov (1880_CR32) 2015; 5 D Zubenko (1880_CR14) 2017; 209 S Liu (1880_CR11) 2016; 4 MB Katz (1880_CR21) 2012; 293 S Royer (1880_CR41) 2014; 114 CH Kim (1880_CR40) 2010; 327 M Asano (1880_CR29) 2016; 6 S Dai (1880_CR22) 2017; 7 H Li (1880_CR30) 2016; 15 R Shiozaki (1880_CR1) 1997; 93 Y Zhu (1880_CR9) 2016; 16 Y Gao (1880_CR15) 2017; 5 P Strasser (1880_CR31) 2010; 2 S Royer (1880_CR35) 2011; 3 SM McClure (1880_CR28) 2009; 469 Y Nishihata (1880_CR2) 2002; 418 YF Sun (1880_CR8) 2016; 6 S Liu (1880_CR6) 2015; 6 S Liu (1880_CR12) 2016; 6 Y Yin (1880_CR23) 2004; 304 ZL Wang (1880_CR43) 2000; 31 D Neagu (1880_CR4) 2013; 5 C Yang (1880_CR7) 2015; 11 BD Madsen (1880_CR3) 2007; 166 J Jansson (1880_CR37) 2002; 211 DH Ha (1880_CR24) 2013; 117 H Wei (1880_CR13) 2014; 4 TS Oh (1880_CR16) 2015; 6 SC Anenberg (1880_CR26) 2017; 545 M Cargnello (1880_CR34) 2013; 341 J Myung (1880_CR19) 2016; 537 K An (1880_CR27) 2013; 135 |
| References_xml | – volume: 27 start-page: 499 year: 2016 end-page: 508 ident: CR10 article-title: From material design to mechanism study: nanoscale Ni exsolution on a highly active A-site deficient anode material for solid oxide fuel cells publication-title: Nano Energy doi: 10.1016/j.nanoen.2016.07.013 – volume: 337 start-page: 26 year: 2016 end-page: 35 ident: CR17 article-title: Ni–perovskite interaction and its structural and catalytic consequences in methane steam reforming and methanation reactions publication-title: J. Catal. doi: 10.1016/j.jcat.2016.01.020 – volume: 6 start-page: 760 year: 2015 end-page: 768 ident: CR6 article-title: Double-layered perovskite anode with in situ exsolution of a Co–Fe alloy to cogenerate ethylene and electricity in a proton-conducting ethane fuel cell publication-title: ACS Catal. doi: 10.1021/acscatal.5b02296 – volume: 304 start-page: 711 year: 2004 end-page: 714 ident: CR23 article-title: Formation of hollow nanocrystals through the nanoscale Kirkendall effect publication-title: Science doi: 10.1126/science.1096566 – volume: 209 start-page: 711 year: 2017 end-page: 719 ident: CR14 article-title: Exsolution of Re-alloy catalysts with enhanced stability for methane dry reforming publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2017.03.047 – volume: 45 start-page: 5998 year: 2006 end-page: 6002 ident: CR20 article-title: Self-regenerating Rh- and Pt-based perovskite catalysts for automotive-emissions control publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200503938 – volume: 117 start-page: 14303 year: 2013 end-page: 14312 ident: CR24 article-title: The oxidation of cobalt nanoparticles into Kirkendall-hollowed CoO and Co3O4: the diffusion mechanisms and atomic structural transformations publication-title: J. Phys. Chem. C doi: 10.1021/jp402939e – volume: 418 start-page: 164 year: 2002 end-page: 167 ident: CR2 article-title: Self-regeneration of a Pd-perovskite catalyst for automotive emissions control publication-title: Nature doi: 10.1038/nature00893 – volume: 5 start-page: 11139 year: 2013 end-page: 11146 ident: CR25 article-title: Size dependent reduction–oxidation–reduction behaviour of cobalt oxide nanocrystals publication-title: Nanoscale doi: 10.1039/c3nr02877a – volume: 11 start-page: 76 year: 2012 end-page: 81 ident: CR42 article-title: Universal energy-level alignment of molecules on metal oxides publication-title: Nat. Mater. doi: 10.1038/nmat3159 – volume: 6 start-page: 6219 year: 2016 end-page: 6228 ident: CR12 article-title: Highly stable and efficient catalyst with in situ exsolved Fe–Ni alloy nanospheres socketed on an oxygen deficient perovskite for direct CO2 electrolysis publication-title: ACS Catal. doi: 10.1021/acscatal.6b01555 – volume: 5 start-page: 6399 year: 2017 end-page: 6404 ident: CR15 article-title: In situ growth of Pt3Ni nanoparticles on an A-site deficient perovskite with enhanced activity for the oxygen reduction reaction publication-title: J. Mater. Chem. A doi: 10.1039/C7TA00349H – volume: 431–432 start-page: 9 year: 2012 end-page: 17 ident: CR36 article-title: Sub-ambient CO oxidation over mesoporous Co3O4: effect of morphology on its reduction behavior and catalytic performance publication-title: Appl. Catal. Gen. doi: 10.1016/j.apcata.2012.04.006 – volume: 469 start-page: 1 year: 2009 end-page: 13 ident: CR28 article-title: New insights into catalytic CO oxidation on Pt-group metals at elevated pressures publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2008.12.066 – volume: 211 start-page: 387 year: 2002 end-page: 397 ident: CR37 article-title: On the catalytic activity of Co3O4 in low-temperature CO oxidation publication-title: J. Catal. doi: 10.1016/S0021-9517(02)93738-3 – volume: 537 start-page: 528 year: 2016 end-page: 531 ident: CR19 article-title: Switching on electrocatalytic activity in solid oxide cells publication-title: Nature doi: 10.1038/nature19090 – volume: 5 start-page: 916 year: 2013 end-page: 923 ident: CR4 article-title: In situ growth of nanoparticles through control of non-stoichiometry publication-title: Nat. Chem. doi: 10.1038/nchem.1773 – volume: 166 start-page: 64 year: 2007 end-page: 67 ident: CR3 article-title: Nucleation of nanometer-scale electrocatalyst particles in solid oxide fuel cell anodes publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2006.12.080 – volume: 7 start-page: 1579 year: 2017 end-page: 1582 ident: CR22 article-title: In situ observation of Rh-CaTiO3 catalysts during reduction and oxidation treatments by transmission electron microscopy publication-title: ACS Catal. doi: 10.1021/acscatal.6b03604 – volume: 31 start-page: 571 year: 2000 end-page: 580 ident: CR43 article-title: EELS analysis of cation valence states and oxygen vacancies in magnetic oxides publication-title: Micron doi: 10.1016/S0968-4328(99)00139-0 – volume: 15 start-page: 48 year: 2016 end-page: 53 ident: CR30 article-title: Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies publication-title: Nat. Mater. doi: 10.1038/nmat4465 – volume: 94 start-page: 166 year: 1985 end-page: 174 ident: CR39 article-title: Dynamic behavior of automotive catalysts publication-title: J. Catal. doi: 10.1016/0021-9517(85)90092-2 – volume: 545 start-page: 467 year: 2017 end-page: 471 ident: CR26 article-title: Impacts and mitigation of excess diesel-related NOx emissions in 11 major vehicle markets publication-title: Nature doi: 10.1038/nature22086 – volume: 6 year: 2015 ident: CR5 article-title: Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution publication-title: Nat. Commun. doi: 10.1038/ncomms9120 – volume: 6 start-page: 5285 year: 2016 end-page: 5289 ident: CR29 article-title: Oxygen reduction reaction activity for strain-controlled Pt-based model alloy catalysts: surface strains and direct electronic effects induced by alloying elements publication-title: ACS Catal. doi: 10.1021/acscatal.6b01466 – volume: 5 start-page: 5714 year: 2015 end-page: 5718 ident: CR32 article-title: Catalytic CO oxidation over well-defined cobalt oxide nanoparticles: size-reactivity correlation publication-title: ACS Catal. doi: 10.1021/acscatal.5b01452 – volume: 6 start-page: 2710 year: 2016 end-page: 2714 ident: CR8 article-title: Bifunctional catalyst of core–shell nanoparticles socketed on oxygen-deficient layered perovskite for soot combustion: in situ observation of synergistic dual active sites publication-title: ACS Catal. doi: 10.1021/acscatal.6b00081 – volume: 293 start-page: 145 year: 2012 end-page: 148 ident: CR21 article-title: Reversible precipitation/dissolution of precious-metal clusters in perovskite-based catalyst materials: bulk versus surface re-dispersion publication-title: J. Catal. doi: 10.1016/j.jcat.2012.06.017 – volume: 8 year: 2017 ident: CR18 article-title: Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures publication-title: Nat. Commun. doi: 10.1038/ncomms14785 – volume: 114 start-page: 10292 year: 2014 end-page: 10368 ident: CR41 article-title: Perovskites as substitutes of noble metals for heterogeneous catalysis: dream or reality publication-title: Chem. Rev. doi: 10.1021/cr500032a – volume: 93 start-page: 3235 year: 1997 end-page: 3242 ident: CR1 article-title: Partial oxidation of methane over a Ni/BaTiO catalyst prepared by solid phasecrystallization publication-title: J. Chem. Soc. Faraday Trans. doi: 10.1039/a701383c – volume: 3 start-page: 24 year: 2011 end-page: 65 ident: CR35 article-title: Catalytic oxidation of carbon monoxide over transition metal oxides publication-title: ChemCatChem doi: 10.1002/cctc.201000378 – volume: 133 start-page: 4498 year: 2011 end-page: 4517 ident: CR38 article-title: Chemisorption of CO and mechanism of CO oxidation on supported platinum nanoclusters publication-title: J. Am. Chem. Soc. doi: 10.1021/ja110073u – volume: 341 start-page: 771 year: 2013 end-page: 773 ident: CR34 article-title: Control of metal nanocrystal size reveals metal-support interface role for ceria catalysts publication-title: Science doi: 10.1126/science.1240148 – volume: 4 start-page: 17521 year: 2016 end-page: 17528 ident: CR11 article-title: CO2-to-CO conversion on layered perovskite with in situ exsolved Co–Fe alloy nanoparticles: an active and stable cathode for solid oxide electrolysis cells publication-title: J. Mater. Chem. A doi: 10.1039/C6TA06365A – volume: 11 start-page: 704 year: 2015 end-page: 710 ident: CR7 article-title: In situ fabrication of CoFe alloy nanoparticles structured (Pr Sr ) (Fe Nb ) O ceramic anode for direct hydrocarbon solid oxide fuel cells publication-title: Nano Energy doi: 10.1016/j.nanoen.2014.12.001 – volume: 327 start-page: 1624 year: 2010 end-page: 1627 ident: CR40 article-title: Strontium-doped perovskites rival platinum catalysts for treating NOx in simulated diesel exhaust publication-title: Science doi: 10.1126/science.1184087 – volume: 16 start-page: 512 year: 2016 end-page: 518 ident: CR9 article-title: Promotion of oxygen reduction by exsolved silver nanoparticles on a perovskite scaffold for low-temperature solid oxide fuel cells publication-title: Nano Lett. doi: 10.1021/acs.nanolett.5b04160 – volume: 135 start-page: 16689 year: 2013 end-page: 16696 ident: CR27 article-title: Enhanced CO oxidation rates at the interface of mesoporous oxides and Pt nanoparticles publication-title: J. Am. Chem. Soc. doi: 10.1021/ja4088743 – volume: 2 start-page: 454 year: 2010 end-page: 460 ident: CR31 article-title: Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts publication-title: Nat. Chem. doi: 10.1038/nchem.623 – volume: 3 start-page: 363 year: 2010 end-page: 368 ident: CR33 article-title: Surface active sites on Co3O4 nanobelt and nanocube model catalysts for CO oxidation publication-title: Nano Res. doi: 10.1007/s12274-010-1040-2 – volume: 4 year: 2014 ident: CR13 article-title: In situ growth of Ni Cu alloy nanocatalysts on redox-reversible rutile (Nb,Ti)O4 towards high-temperature carbon dioxide electrolysis publication-title: Sci. Rep. doi: 10.1038/srep05156 – volume: 6 start-page: 5106 year: 2015 end-page: 5110 ident: CR16 article-title: Evidence and model for strain-driven release of metal nanocatalysts from perovskites during exsolution publication-title: J. Phys. Chem. Lett. doi: 10.1021/acs.jpclett.5b02292 – volume: 6 start-page: 6219 year: 2016 ident: 1880_CR12 publication-title: ACS Catal. doi: 10.1021/acscatal.6b01555 – volume: 5 start-page: 11139 year: 2013 ident: 1880_CR25 publication-title: Nanoscale doi: 10.1039/c3nr02877a – volume: 211 start-page: 387 year: 2002 ident: 1880_CR37 publication-title: J. Catal. doi: 10.1016/S0021-9517(02)93738-3 – volume: 4 start-page: 17521 year: 2016 ident: 1880_CR11 publication-title: J. Mater. Chem. A doi: 10.1039/C6TA06365A – volume: 418 start-page: 164 year: 2002 ident: 1880_CR2 publication-title: Nature doi: 10.1038/nature00893 – volume: 11 start-page: 76 year: 2012 ident: 1880_CR42 publication-title: Nat. Mater. doi: 10.1038/nmat3159 – volume: 93 start-page: 3235 year: 1997 ident: 1880_CR1 publication-title: J. Chem. Soc. Faraday Trans. doi: 10.1039/a701383c – volume: 7 start-page: 1579 year: 2017 ident: 1880_CR22 publication-title: ACS Catal. doi: 10.1021/acscatal.6b03604 – volume: 209 start-page: 711 year: 2017 ident: 1880_CR14 publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2017.03.047 – volume: 6 start-page: 5285 year: 2016 ident: 1880_CR29 publication-title: ACS Catal. doi: 10.1021/acscatal.6b01466 – volume: 341 start-page: 771 year: 2013 ident: 1880_CR34 publication-title: Science doi: 10.1126/science.1240148 – volume: 337 start-page: 26 year: 2016 ident: 1880_CR17 publication-title: J. Catal. doi: 10.1016/j.jcat.2016.01.020 – volume: 431–432 start-page: 9 year: 2012 ident: 1880_CR36 publication-title: Appl. Catal. Gen. doi: 10.1016/j.apcata.2012.04.006 – volume: 327 start-page: 1624 year: 2010 ident: 1880_CR40 publication-title: Science doi: 10.1126/science.1184087 – volume: 545 start-page: 467 year: 2017 ident: 1880_CR26 publication-title: Nature doi: 10.1038/nature22086 – volume: 16 start-page: 512 year: 2016 ident: 1880_CR9 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.5b04160 – volume: 5 start-page: 916 year: 2013 ident: 1880_CR4 publication-title: Nat. Chem. doi: 10.1038/nchem.1773 – volume: 6 start-page: 2710 year: 2016 ident: 1880_CR8 publication-title: ACS Catal. doi: 10.1021/acscatal.6b00081 – volume: 11 start-page: 704 year: 2015 ident: 1880_CR7 publication-title: Nano Energy doi: 10.1016/j.nanoen.2014.12.001 – volume: 304 start-page: 711 year: 2004 ident: 1880_CR23 publication-title: Science doi: 10.1126/science.1096566 – volume: 5 start-page: 5714 year: 2015 ident: 1880_CR32 publication-title: ACS Catal. doi: 10.1021/acscatal.5b01452 – volume: 31 start-page: 571 year: 2000 ident: 1880_CR43 publication-title: Micron doi: 10.1016/S0968-4328(99)00139-0 – volume: 293 start-page: 145 year: 2012 ident: 1880_CR21 publication-title: J. Catal. doi: 10.1016/j.jcat.2012.06.017 – volume: 8 year: 2017 ident: 1880_CR18 publication-title: Nat. Commun. doi: 10.1038/ncomms14785 – volume: 114 start-page: 10292 year: 2014 ident: 1880_CR41 publication-title: Chem. Rev. doi: 10.1021/cr500032a – volume: 45 start-page: 5998 year: 2006 ident: 1880_CR20 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200503938 – volume: 3 start-page: 24 year: 2011 ident: 1880_CR35 publication-title: ChemCatChem doi: 10.1002/cctc.201000378 – volume: 135 start-page: 16689 year: 2013 ident: 1880_CR27 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja4088743 – volume: 469 start-page: 1 year: 2009 ident: 1880_CR28 publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2008.12.066 – volume: 537 start-page: 528 year: 2016 ident: 1880_CR19 publication-title: Nature doi: 10.1038/nature19090 – volume: 166 start-page: 64 year: 2007 ident: 1880_CR3 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2006.12.080 – volume: 6 start-page: 760 year: 2015 ident: 1880_CR6 publication-title: ACS Catal. doi: 10.1021/acscatal.5b02296 – volume: 133 start-page: 4498 year: 2011 ident: 1880_CR38 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja110073u – volume: 27 start-page: 499 year: 2016 ident: 1880_CR10 publication-title: Nano Energy doi: 10.1016/j.nanoen.2016.07.013 – volume: 117 start-page: 14303 year: 2013 ident: 1880_CR24 publication-title: J. Phys. Chem. C doi: 10.1021/jp402939e – volume: 6 year: 2015 ident: 1880_CR5 publication-title: Nat. Commun. doi: 10.1038/ncomms9120 – volume: 4 year: 2014 ident: 1880_CR13 publication-title: Sci. Rep. doi: 10.1038/srep05156 – volume: 6 start-page: 5106 year: 2015 ident: 1880_CR16 publication-title: J. Phys. Chem. Lett. doi: 10.1021/acs.jpclett.5b02292 – volume: 2 start-page: 454 year: 2010 ident: 1880_CR31 publication-title: Nat. Chem. doi: 10.1038/nchem.623 – volume: 15 start-page: 48 year: 2016 ident: 1880_CR30 publication-title: Nat. Mater. doi: 10.1038/nmat4465 – volume: 3 start-page: 363 year: 2010 ident: 1880_CR33 publication-title: Nano Res. doi: 10.1007/s12274-010-1040-2 – volume: 5 start-page: 6399 year: 2017 ident: 1880_CR15 publication-title: J. Mater. Chem. A doi: 10.1039/C7TA00349H – volume: 94 start-page: 166 year: 1985 ident: 1880_CR39 publication-title: J. Catal. doi: 10.1016/0021-9517(85)90092-2 |
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| Snippet | Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy... Metal nanoparticles prepared by exsolution at the surface of perovskite oxides are key species in catalysis and energy fields. Here, the authors develop a... |
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| SubjectTerms | 639/301/357/354 639/638/77/884 639/638/77/887 Catalysis Energy conversion Energy storage Humanities and Social Sciences multidisciplinary Nanoparticles Oxidation Oxides Platinum Science Science (multidisciplinary) Transformations |
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| Title | Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles |
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