Ultra-high thermal stability of sputtering reconstructed Cu-based catalysts
The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nan...
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| Published in | Nature communications Vol. 12; no. 1; pp. 7209 - 10 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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London
Nature Publishing Group UK
10.12.2021
Nature Publishing Group Nature Portfolio |
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| Abstract | The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO
2
support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals.
Applications of Cu catalysts at high-temperature is a long-sought goal but limited by their serious deactivation due to low copper’s Tammann temperature. Here, the authors introduce an encapsulation layer to improve thermal stability at 800 °C by reconstructing electronic structure of Cu atoms. |
|---|---|
| AbstractList | The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO
2
support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals.
Applications of Cu catalysts at high-temperature is a long-sought goal but limited by their serious deactivation due to low copper’s Tammann temperature. Here, the authors introduce an encapsulation layer to improve thermal stability at 800 °C by reconstructing electronic structure of Cu atoms. The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO2 support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals.Applications of Cu catalysts at high-temperature is a long-sought goal but limited by their serious deactivation due to low copper’s Tammann temperature. Here, the authors introduce an encapsulation layer to improve thermal stability at 800 °C by reconstructing electronic structure of Cu atoms. The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO 2 support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals. The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals. The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO2 support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals.The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a barrier on the metal surface by the classical strong metal-support interaction (SMSI) is supposed to be an efficient way for immobilizing nanoparticles. However, Cu particles were regarded as impossible to form classical SMSI before irreversible sintering. Herein, we fabricate the SMSI between sputtering reconstructed Cu and flame-made LaTiO2 support at a mild reduction temperature, exhibiting an ultra-stable performance for more than 500 h at 600 °C. The sintering of Cu nanoparticles is effectively suppressed even at as high as 800 °C. The critical factors to success are reconstructing the electronic structure of Cu atoms in parallel with enhancing the support reducibility, which makes them adjustable by sputtering power or decorated supports. This strategy will extremely broaden the applications of Cu-based catalysts at more severe conditions and shed light on establishing SMSI on other metals. Applications of Cu catalysts at high-temperature is a long-sought goal but limited by their serious deactivation due to low copper’s Tammann temperature. Here, the authors introduce an encapsulation layer to improve thermal stability at 800 °C by reconstructing electronic structure of Cu atoms. |
| ArticleNumber | 7209 |
| Author | Liu, Yuefeng Li, Shiyan Yu, Jiafeng Tong, Xin Tsubaki, Noritatsu Abe, Takayuki Li, Jie Zhang, Jixin Sun, Xingtao Sun, Jian |
| Author_xml | – sequence: 1 givenname: Jiafeng surname: Yu fullname: Yu, Jiafeng organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 2 givenname: Xingtao surname: Sun fullname: Sun, Xingtao organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences – sequence: 3 givenname: Xin surname: Tong fullname: Tong, Xin organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences – sequence: 4 givenname: Jixin surname: Zhang fullname: Zhang, Jixin organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 5 givenname: Jie surname: Li fullname: Li, Jie organization: School of Chemistry and Chemical Engineering, Yangzhou University – sequence: 6 givenname: Shiyan surname: Li fullname: Li, Shiyan organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences – sequence: 7 givenname: Yuefeng orcidid: 0000-0001-9823-3811 surname: Liu fullname: Liu, Yuefeng email: yuefeng.liu@dicp.ac.cn organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 8 givenname: Noritatsu orcidid: 0000-0001-6786-5058 surname: Tsubaki fullname: Tsubaki, Noritatsu email: tsubaki@eng.u-toyama.ac.jp organization: Department of Applied Chemistry, School of Engineering, University of Toyama, Gofuku 3190 – sequence: 9 givenname: Takayuki surname: Abe fullname: Abe, Takayuki organization: Hydrogen Isotope Research Center, University of Toyama, Gofuku 3190 – sequence: 10 givenname: Jian orcidid: 0000-0002-4191-578X surname: Sun fullname: Sun, Jian email: sunj@dicp.ac.cn organization: Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/34893618$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/j.apsusc.2012.09.039 10.1016/S0926-860X(00)00854-1 10.1021/acs.chemmater.6b04213 10.1021/acs.chemrev.5b00482 10.1021/acsanm.9b00569 10.1126/sciadv.1700231 10.1021/ja3034153 10.1002/anie.201601823 10.1016/S0368-2048(03)00126-9 10.1021/acscatal.5b00188 10.1126/science.211.4487.1121 10.1021/jp014487p 10.1016/0021-9517(78)90182-3 10.1016/j.susc.2014.08.029 10.1016/j.electacta.2014.11.203 10.1016/0021-9517(91)90334-Z 10.1002/adma.201901905 10.1002/anie.201400290 10.1038/s41929-019-0364-x 10.1021/jacs.8b08246 10.1107/S0909049505012719 10.1002/anie.201903298 10.1016/j.apsusc.2008.05.325 10.1002/anie.201201283 10.1007/s10853-013-7836-1 10.1021/jp106648c 10.1007/s11671-010-9591-4 10.1016/j.apcatb.2014.12.011 10.1023/A:1023567718303 10.1016/j.apcatb.2016.05.050 10.1007/s10562-004-0768-2 10.1016/j.micromeso.2012.06.029 10.1021/acs.nanolett.6b01769 10.1016/j.jechem.2017.07.006 10.1021/jacs.5b11306 10.1021/jacs.8b10864 10.1039/C9CC00297A 10.1021/ja00469a029 10.1103/PhysRevB.69.144103 10.1002/cctc.201100090 10.1021/jp046091u 10.1039/C5CP02158H 10.1021/acscatal.6b02991 10.1126/sciadv.aau3275 10.1039/C8SC00729B 10.1016/j.apcatb.2021.120410 10.1021/jp057053t 10.1103/PhysRev.76.388 10.1038/nchem.2607 10.1016/j.jece.2021.105790 10.1038/s41929-021-00611-3 10.1039/b718956g |
| ContentType | Journal Article |
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| References | Van Der Grift (CR50) 1991; 131 Yano (CR47) 2003; 131-132 Ren (CR36) 2008; 254 Huang (CR28) 2010; 5 Matsubu (CR41) 2017; 9 Góra-Marek (CR43) 2012; 162 Su (CR37) 2017; 26 Twigg, Spencer (CR2) 2001; 212 Zhang (CR30) 2016; 16 Wang (CR22) 2021; 4 Anderson (CR23) 1949; 76 Zhang (CR18) 2019; 141 Wang (CR35) 2015; 153 Kuwauchi (CR27) 2012; 51 Willinger (CR14) 2014; 53 Sun (CR25) 2018; 4 Dong (CR21) 2018; 140 Fu (CR40) 2021; 9 Tang (CR20) 2016; 55 Zhang (CR3) 2017; 7 Khalid (CR33) 2012; 263 Figueiredo (CR11) 2019; 2 Zhu (CR12) 2019; 58 Tauster (CR8) 1978; 100 Reddy (CR34) 2002; 106 Liu (CR49) 2011; 3 Kumar (CR44) 2006; 110 Zhang (CR32) 2010; 114 Tang (CR19) 2016; 138 Tang (CR17) 2017; 3 Gawande (CR1) 2016; 116 CR16 Haisheng (CR52) 2015; 5 Schumann (CR42) 2015; 5 Pauly (CR46) 2014; 630 Twigg, Spencer (CR5) 2003; 22 Yu (CR48) 2016; 198 Tauster, Fung (CR13) 1978; 55 Andrievski (CR4) 2014; 49 Goodman (CR10) 2005; 99 Gong (CR51) 2012; 134 Kim (CR24) 2017; 29 Fu (CR15) 2005; 109 Yu (CR38) 2019; 55 Liu (CR31) 2015; 168-169 Ravel, Newville (CR53) 2005; 12 Wang (CR7) 2019; 31 van Deelen (CR6) 2019; 2 Sun (CR45) 2015; 17 Chen (CR39) 2021; 297 Zhang (CR29) 2004; 69 Tauster (CR9) 1981; 211 Zhang (CR26) 2018; 9 TW van Deelen (27557_CR6) 2019; 2 H Tang (27557_CR20) 2016; 55 Y Liu (27557_CR31) 2015; 168-169 H Tang (27557_CR19) 2016; 138 M Ren (27557_CR36) 2008; 254 H Wang (27557_CR22) 2021; 4 F Wang (27557_CR35) 2015; 153 MV Twigg (27557_CR2) 2001; 212 Y Yu (27557_CR38) 2019; 55 Z Zhang (27557_CR29) 2004; 69 C Sun (27557_CR45) 2015; 17 J Zhang (27557_CR18) 2019; 141 J Gong (27557_CR51) 2012; 134 Y Haisheng (27557_CR52) 2015; 5 Y Kuwauchi (27557_CR27) 2012; 51 C-N Huang (27557_CR28) 2010; 5 T Yano (27557_CR47) 2003; 131-132 PA Anderson (27557_CR23) 1949; 76 RA Andrievski (27557_CR4) 2014; 49 BM Reddy (27557_CR34) 2002; 106 SJ Tauster (27557_CR13) 1978; 55 JC Matsubu (27557_CR41) 2017; 9 Y Fu (27557_CR40) 2021; 9 X Su (27557_CR37) 2017; 26 MB Gawande (27557_CR1) 2016; 116 Z Zhang (27557_CR26) 2018; 9 J Chen (27557_CR39) 2021; 297 SJ Tauster (27557_CR9) 1981; 211 DW Goodman (27557_CR10) 2005; 99 S Zhang (27557_CR30) 2016; 16 MG Willinger (27557_CR14) 2014; 53 27557_CR16 MV Twigg (27557_CR5) 2003; 22 N Pauly (27557_CR46) 2014; 630 L Wang (27557_CR7) 2019; 31 HK Kim (27557_CR24) 2017; 29 SJ Tauster (27557_CR8) 1978; 100 CJG Van Der Grift (27557_CR50) 1991; 131 WT Figueiredo (27557_CR11) 2019; 2 J Dong (27557_CR21) 2018; 140 J Sun (27557_CR25) 2018; 4 X Zhang (27557_CR3) 2017; 7 B Ravel (27557_CR53) 2005; 12 K Góra-Marek (27557_CR43) 2012; 162 Q Fu (27557_CR15) 2005; 109 H Tang (27557_CR17) 2017; 3 J Schumann (27557_CR42) 2015; 5 J Liu (27557_CR49) 2011; 3 M Zhu (27557_CR12) 2019; 58 NR Khalid (27557_CR33) 2012; 263 J Zhang (27557_CR32) 2010; 114 J Yu (27557_CR48) 2016; 198 CP Kumar (27557_CR44) 2006; 110 |
| References_xml | – volume: 263 start-page: 254 year: 2012 end-page: 259 ident: CR33 article-title: Synthesis and photocatalytic properties of visible light responsive La/TiO2-graphene composites publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2012.09.039 – volume: 212 start-page: 161 year: 2001 end-page: 174 ident: CR2 article-title: Deactivation of supported copper metal catalysts for hydrogenation reactions publication-title: Appl. Catal. A Gen. doi: 10.1016/S0926-860X(00)00854-1 – volume: 29 start-page: 3403 year: 2017 end-page: 3411 ident: CR24 article-title: Reduction of the work function of gold by N-heterocyclic carbenes publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.6b04213 – volume: 116 start-page: 3722 year: 2016 end-page: 3811 ident: CR1 article-title: Cu and Cu-based nanoparticles: synthesis and applications in catalysis publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.5b00482 – volume: 2 start-page: 2559 year: 2019 end-page: 2573 ident: CR11 article-title: Understanding the strong metal–support interaction (SMSI) effect in CuxNi1–x/CeO2 (0 < x < 1) nanoparticles for enhanced catalysis publication-title: ACS Appl. Nano Mater. doi: 10.1021/acsanm.9b00569 – volume: 3 start-page: e1700231 year: 2017 ident: CR17 article-title: Classical strong metal–support interactions between gold nanoparticles and titanium dioxide publication-title: Sci. Adv. doi: 10.1126/sciadv.1700231 – ident: CR16 – volume: 134 start-page: 13922 year: 2012 end-page: 13925 ident: CR51 article-title: Synthesis of ethanol via syngas on Cu/SiO2 catalysts with balanced Cu0–Cu+ sites publication-title: J. Am. Chem. Soc. doi: 10.1021/ja3034153 – volume: 55 start-page: 10606 year: 2016 end-page: 10611 ident: CR20 article-title: Ultrastable hydroxyapatite/titanium-dioxide-supported gold nanocatalyst with strong metal–support interaction for carbon monoxide oxidation publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201601823 – volume: 131-132 start-page: 133 year: 2003 end-page: 144 ident: CR47 article-title: Anomalous chemical shifts of Cu 2p and Cu LMM Auger spectra of silicate glasses publication-title: J. Electron Spectrosc. doi: 10.1016/S0368-2048(03)00126-9 – volume: 5 start-page: 3260 year: 2015 end-page: 3270 ident: CR42 article-title: Promoting strong metal support interaction: doping ZnO for enhanced activity of Cu/ZnO:M (M = Al, Ga, Mg) catalysts publication-title: ACS Catal. doi: 10.1021/acscatal.5b00188 – volume: 211 start-page: 1121 year: 1981 end-page: 1125 ident: CR9 article-title: Strong interactions in supported-metal catalysts publication-title: Science doi: 10.1126/science.211.4487.1121 – volume: 106 start-page: 5695 year: 2002 end-page: 5700 ident: CR34 article-title: Surface characterization of La2O3−TiO2 and V2O5/La2O3−TiO2 catalysts publication-title: J. Phys. Chem. B doi: 10.1021/jp014487p – volume: 55 start-page: 29 year: 1978 end-page: 35 ident: CR13 article-title: Strong metal-support interactions: occurrence among the binary oxides of groups IIA–VB publication-title: J. Catal. doi: 10.1016/0021-9517(78)90182-3 – volume: 630 start-page: 294 year: 2014 end-page: 299 ident: CR46 article-title: LMM Auger primary excitation spectra of copper publication-title: Surf. Sci. doi: 10.1016/j.susc.2014.08.029 – volume: 153 start-page: 170 year: 2015 end-page: 174 ident: CR35 article-title: Fabrication of La-doped TiO2 film electrode and investigation of its electrocatalytic activity for furfural reduction publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2014.11.203 – volume: 131 start-page: 178 year: 1991 end-page: 189 ident: CR50 article-title: Effect of the reduction treatment on the structure and reactivity of silica-supported copper particles publication-title: J. Catal. doi: 10.1016/0021-9517(91)90334-Z – volume: 31 start-page: 1901905 year: 2019 ident: CR7 article-title: New strategies for the preparation of sinter-resistant metal-nanoparticle-based catalysts publication-title: Adv. Mater. doi: 10.1002/adma.201901905 – volume: 53 start-page: 5998 year: 2014 end-page: 6001 ident: CR14 article-title: A case of strong metal–support interactions: combining advanced microscopy and model systems to elucidate the atomic structure of interfaces publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201400290 – volume: 2 start-page: 955 year: 2019 end-page: 970 ident: CR6 article-title: Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity publication-title: Nat. Catal. doi: 10.1038/s41929-019-0364-x – volume: 140 start-page: 13808 year: 2018 end-page: 13816 ident: CR21 article-title: Carbide-supported Au catalysts for water–gas shift reactions: a new territory for the strong metal–support interaction effect publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b08246 – volume: 12 start-page: 537 year: 2005 end-page: 541 ident: CR53 article-title: ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT publication-title: J. Synchrotron Radiat. doi: 10.1107/S0909049505012719 – volume: 58 start-page: 9083 year: 2019 end-page: 9087 ident: CR12 article-title: Strong metal–support interactions between copper and iron oxide during the high-temperature water-gas shift reaction publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201903298 – volume: 254 start-page: 7314 year: 2008 end-page: 7320 ident: CR36 article-title: Evolution of TiO2 coating layers on lamellar sericite in the presence of La3+ and the pigmentary properties publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2008.05.325 – volume: 51 start-page: 7729 year: 2012 end-page: 7733 ident: CR27 article-title: Intrinsic catalytic structure of gold nanoparticles supported on TiO2 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201201283 – volume: 49 start-page: 1449 year: 2014 end-page: 1460 ident: CR4 article-title: Review of thermal stability of nanomaterials publication-title: J. Mater. Sci. doi: 10.1007/s10853-013-7836-1 – volume: 114 start-page: 18396 year: 2010 end-page: 18400 ident: CR32 article-title: Increasing the oxygen vacancy density on the TiO2 surface by La-doping for dye-sensitized solar cells publication-title: J. Phys. Chem. C doi: 10.1021/jp106648c – volume: 5 year: 2010 ident: CR28 article-title: Nonstoichiometric titanium oxides via pulsed laser ablation in water publication-title: Nanoscale Res. Lett. doi: 10.1007/s11671-010-9591-4 – volume: 5 start-page: 6 year: 2015 end-page: 12 ident: CR52 article-title: The XAFS beamline of SSRF publication-title: Nucl. Sci. Tech. – volume: 168-169 start-page: 125 year: 2015 end-page: 131 ident: CR31 article-title: Photocatalytic reduction of CO2 with water vapor on surface La-modified TiO2 nanoparticles with enhanced CH4 selectivity publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2014.12.011 – volume: 22 start-page: 191 year: 2003 end-page: 203 ident: CR5 article-title: Deactivation of copper metal catalysts for methanol decomposition, methanol steam reforming and methanol synthesis publication-title: Top. Catal. doi: 10.1023/A:1023567718303 – volume: 198 start-page: 171 year: 2016 end-page: 179 ident: CR48 article-title: Facile synthesis of highly active Rh/Al2O3 steam reforming catalysts with preformed support by flame spray pyrolysis publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2016.05.050 – volume: 99 start-page: 1 year: 2005 end-page: 4 ident: CR10 article-title: “Catalytically active Au on Titania:” yet another example of a strong metal support interaction (SMSI)? publication-title: Catal. Lett. doi: 10.1007/s10562-004-0768-2 – volume: 162 start-page: 175 year: 2012 ident: CR43 article-title: Copper sites in zeolites - quantitative IR studies publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2012.06.029 – volume: 16 start-page: 4528 year: 2016 end-page: 4534 ident: CR30 article-title: Dynamical observation and detailed description of catalysts under strong metal–support interaction publication-title: Nano Lett. doi: 10.1021/acs.nanolett.6b01769 – volume: 26 start-page: 854 year: 2017 end-page: 867 ident: CR37 article-title: Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions publication-title: J. Energy Chem. doi: 10.1016/j.jechem.2017.07.006 – volume: 138 start-page: 56 year: 2016 end-page: 59 ident: CR19 article-title: Strong metal–support interactions between gold nanoparticles and nonoxides publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b11306 – volume: 141 start-page: 2975 year: 2019 end-page: 2983 ident: CR18 article-title: Wet-chemistry strong metal–support interactions in titania-supported Au catalysts publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b10864 – volume: 55 start-page: 4178 year: 2019 end-page: 4181 ident: CR38 article-title: Highly active and stable copper catalysts derived from copper silicate double-shell nanofibers with strong metal–support interactions for the RWGS reaction publication-title: Chem. Commun. doi: 10.1039/C9CC00297A – volume: 100 start-page: 170 year: 1978 end-page: 175 ident: CR8 article-title: Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00469a029 – volume: 69 start-page: 144103 year: 2004 ident: CR29 article-title: HRTEM and EELS study of screw dislocation cores in SrTiO3 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.69.144103 – volume: 3 start-page: 934 year: 2011 end-page: 948 ident: CR49 article-title: Advanced electron microscopy of metal–support interactions in supported metal catalysts publication-title: ChemCatChem doi: 10.1002/cctc.201100090 – volume: 109 start-page: 944 year: 2005 end-page: 951 ident: CR15 article-title: Metal-oxide interfacial reactions: encapsulation of Pd on TiO2 (110) publication-title: J. Phys. Chem. B doi: 10.1021/jp046091u – volume: 17 start-page: 15996 year: 2015 end-page: 16006 ident: CR45 article-title: Effects of different manganese precursors as promoters on catalytic performance of CuO–MnOx/TiO2 catalysts for NO removal by CO publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C5CP02158H – volume: 7 start-page: 912 year: 2017 end-page: 918 ident: CR3 article-title: Highly dispersed copper over β-Mo2C as an efficient and stable catalyst for the reverse water gas shift (RWGS) reaction publication-title: ACS Catal. doi: 10.1021/acscatal.6b02991 – volume: 4 start-page: eaau3275 year: 2018 ident: CR25 article-title: Freezing copper as a noble metal-like catalyst for preliminary hydrogenation publication-title: Sci. Adv. doi: 10.1126/sciadv.aau3275 – volume: 9 start-page: 3386 year: 2018 end-page: 3394 ident: CR26 article-title: Tailored metastable Ce-Zr oxides with highly distorted lattice oxygen for accelerating redox cycles publication-title: Chem. Sci. doi: 10.1039/C8SC00729B – volume: 297 start-page: 120410 year: 2021 ident: CR39 article-title: Strong metal-support interaction assisted redispersion strategy for obtaining ultrafine and stable IrO2/Ir active sites with exceptional methane oxidation activity publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2021.120410 – volume: 110 start-page: 5223 year: 2006 end-page: 5229 ident: CR44 article-title: EPR investigation of TiO2 nanoparticles with temperature-dependent properties publication-title: J. Phys. Chem. B doi: 10.1021/jp057053t – volume: 76 start-page: 388 year: 1949 end-page: 390 ident: CR23 article-title: The work function of copper publication-title: Phys. Rev. doi: 10.1103/PhysRev.76.388 – volume: 9 start-page: 120 year: 2017 end-page: 127 ident: CR41 article-title: Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts publication-title: Nat. Chem. doi: 10.1038/nchem.2607 – volume: 9 start-page: 105790 year: 2021 ident: CR40 article-title: In situ redispersion of rhodium nanocatalyst for CO2 reforming of CH4 publication-title: J. Environ. Chem. Eng. doi: 10.1016/j.jece.2021.105790 – volume: 4 start-page: 418 year: 2021 end-page: 424 ident: CR22 article-title: Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier’s principle publication-title: Nat. Catal. doi: 10.1038/s41929-021-00611-3 – volume: 5 year: 2010 ident: 27557_CR28 publication-title: Nanoscale Res. Lett. doi: 10.1007/s11671-010-9591-4 – volume: 49 start-page: 1449 year: 2014 ident: 27557_CR4 publication-title: J. Mater. Sci. doi: 10.1007/s10853-013-7836-1 – volume: 5 start-page: 3260 year: 2015 ident: 27557_CR42 publication-title: ACS Catal. doi: 10.1021/acscatal.5b00188 – volume: 114 start-page: 18396 year: 2010 ident: 27557_CR32 publication-title: J. Phys. Chem. C doi: 10.1021/jp106648c – volume: 2 start-page: 2559 year: 2019 ident: 27557_CR11 publication-title: ACS Appl. Nano Mater. doi: 10.1021/acsanm.9b00569 – volume: 212 start-page: 161 year: 2001 ident: 27557_CR2 publication-title: Appl. Catal. A Gen. doi: 10.1016/S0926-860X(00)00854-1 – volume: 9 start-page: 120 year: 2017 ident: 27557_CR41 publication-title: Nat. Chem. doi: 10.1038/nchem.2607 – volume: 297 start-page: 120410 year: 2021 ident: 27557_CR39 publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2021.120410 – volume: 76 start-page: 388 year: 1949 ident: 27557_CR23 publication-title: Phys. Rev. doi: 10.1103/PhysRev.76.388 – volume: 12 start-page: 537 year: 2005 ident: 27557_CR53 publication-title: J. Synchrotron Radiat. doi: 10.1107/S0909049505012719 – volume: 31 start-page: 1901905 year: 2019 ident: 27557_CR7 publication-title: Adv. Mater. doi: 10.1002/adma.201901905 – volume: 53 start-page: 5998 year: 2014 ident: 27557_CR14 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201400290 – volume: 254 start-page: 7314 year: 2008 ident: 27557_CR36 publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2008.05.325 – volume: 2 start-page: 955 year: 2019 ident: 27557_CR6 publication-title: Nat. Catal. doi: 10.1038/s41929-019-0364-x – volume: 3 start-page: e1700231 year: 2017 ident: 27557_CR17 publication-title: Sci. Adv. doi: 10.1126/sciadv.1700231 – volume: 116 start-page: 3722 year: 2016 ident: 27557_CR1 publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.5b00482 – volume: 109 start-page: 944 year: 2005 ident: 27557_CR15 publication-title: J. Phys. Chem. B doi: 10.1021/jp046091u – volume: 5 start-page: 6 year: 2015 ident: 27557_CR52 publication-title: Nucl. Sci. Tech. – volume: 69 start-page: 144103 year: 2004 ident: 27557_CR29 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.69.144103 – volume: 3 start-page: 934 year: 2011 ident: 27557_CR49 publication-title: ChemCatChem doi: 10.1002/cctc.201100090 – volume: 168-169 start-page: 125 year: 2015 ident: 27557_CR31 publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2014.12.011 – volume: 99 start-page: 1 year: 2005 ident: 27557_CR10 publication-title: Catal. Lett. doi: 10.1007/s10562-004-0768-2 – volume: 106 start-page: 5695 year: 2002 ident: 27557_CR34 publication-title: J. Phys. Chem. B doi: 10.1021/jp014487p – volume: 17 start-page: 15996 year: 2015 ident: 27557_CR45 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C5CP02158H – volume: 630 start-page: 294 year: 2014 ident: 27557_CR46 publication-title: Surf. Sci. doi: 10.1016/j.susc.2014.08.029 – volume: 131-132 start-page: 133 year: 2003 ident: 27557_CR47 publication-title: J. Electron Spectrosc. doi: 10.1016/S0368-2048(03)00126-9 – volume: 4 start-page: 418 year: 2021 ident: 27557_CR22 publication-title: Nat. Catal. doi: 10.1038/s41929-021-00611-3 – volume: 110 start-page: 5223 year: 2006 ident: 27557_CR44 publication-title: J. Phys. Chem. B doi: 10.1021/jp057053t – volume: 16 start-page: 4528 year: 2016 ident: 27557_CR30 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.6b01769 – volume: 58 start-page: 9083 year: 2019 ident: 27557_CR12 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201903298 – volume: 51 start-page: 7729 year: 2012 ident: 27557_CR27 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201201283 – volume: 7 start-page: 912 year: 2017 ident: 27557_CR3 publication-title: ACS Catal. doi: 10.1021/acscatal.6b02991 – volume: 162 start-page: 175 year: 2012 ident: 27557_CR43 publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2012.06.029 – volume: 131 start-page: 178 year: 1991 ident: 27557_CR50 publication-title: J. Catal. doi: 10.1016/0021-9517(91)90334-Z – volume: 141 start-page: 2975 year: 2019 ident: 27557_CR18 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b10864 – volume: 263 start-page: 254 year: 2012 ident: 27557_CR33 publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2012.09.039 – volume: 55 start-page: 4178 year: 2019 ident: 27557_CR38 publication-title: Chem. Commun. doi: 10.1039/C9CC00297A – ident: 27557_CR16 doi: 10.1039/b718956g – volume: 134 start-page: 13922 year: 2012 ident: 27557_CR51 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja3034153 – volume: 55 start-page: 10606 year: 2016 ident: 27557_CR20 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201601823 – volume: 4 start-page: eaau3275 year: 2018 ident: 27557_CR25 publication-title: Sci. Adv. doi: 10.1126/sciadv.aau3275 – volume: 211 start-page: 1121 year: 1981 ident: 27557_CR9 publication-title: Science doi: 10.1126/science.211.4487.1121 – volume: 9 start-page: 3386 year: 2018 ident: 27557_CR26 publication-title: Chem. Sci. doi: 10.1039/C8SC00729B – volume: 29 start-page: 3403 year: 2017 ident: 27557_CR24 publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.6b04213 – volume: 22 start-page: 191 year: 2003 ident: 27557_CR5 publication-title: Top. Catal. doi: 10.1023/A:1023567718303 – volume: 55 start-page: 29 year: 1978 ident: 27557_CR13 publication-title: J. Catal. doi: 10.1016/0021-9517(78)90182-3 – volume: 140 start-page: 13808 year: 2018 ident: 27557_CR21 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b08246 – volume: 26 start-page: 854 year: 2017 ident: 27557_CR37 publication-title: J. Energy Chem. doi: 10.1016/j.jechem.2017.07.006 – volume: 9 start-page: 105790 year: 2021 ident: 27557_CR40 publication-title: J. Environ. Chem. Eng. doi: 10.1016/j.jece.2021.105790 – volume: 100 start-page: 170 year: 1978 ident: 27557_CR8 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00469a029 – volume: 198 start-page: 171 year: 2016 ident: 27557_CR48 publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2016.05.050 – volume: 138 start-page: 56 year: 2016 ident: 27557_CR19 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b11306 – volume: 153 start-page: 170 year: 2015 ident: 27557_CR35 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2014.11.203 |
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| Snippet | The rational design of high-temperature endurable Cu-based catalysts is a long-sought goal since they are suffering from significant sintering. Establishing a... Applications of Cu catalysts at high-temperature is a long-sought goal but limited by their serious deactivation due to low copper’s Tammann temperature. Here,... |
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| SubjectTerms | 140/146 147/143 639/166/898 639/638/77/884 639/638/77/887 Catalysts Copper Deactivation Electronic structure Heavy metals High temperature Humanities and Social Sciences Metal surfaces multidisciplinary Nanoparticles Science Science (multidisciplinary) Sintering Sputtering Thermal stability |
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| Title | Ultra-high thermal stability of sputtering reconstructed Cu-based catalysts |
| URI | https://link.springer.com/article/10.1038/s41467-021-27557-1 https://www.ncbi.nlm.nih.gov/pubmed/34893618 https://www.proquest.com/docview/2608620709 https://www.proquest.com/docview/2609456790 https://pubmed.ncbi.nlm.nih.gov/PMC8664808 https://doaj.org/article/98cfaaa88e384c4d9e0eb06426264807 |
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