Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence

Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhan...

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Published inLight, science & applications Vol. 11; no. 1; pp. 223 - 29
Main Authors Zhang, Xuan, Xu, Yiyi, Valenzuela, Cristian, Zhang, Xinfang, Wang, Ling, Feng, Wei, Li, Quan
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 14.07.2022
Springer Nature B.V
Nature Publishing Group
Subjects
639/624/399/354
639/624/399/919
Catalysis
Chirality
Circular dichroism
Lasers
Luminescence
Microwaves
Nanomaterials
Nanotechnology
Optical and Electronic Materials
Optical Devices
Optics
Photonics
Physics
Physics and Astronomy
Review
Review Article
Reviews
RF and Optical Engineering
Online AccessGet full text

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Abstract Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond. This review focuses on liquid crystal-templated chiral functional nanomaterials, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, introducing their underlying mechanisms, chiroptical properties, and potential applications.
AbstractList Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond.Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond.
Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond.
Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond. This review focuses on liquid crystal-templated chiral functional nanomaterials, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, introducing their underlying mechanisms, chiroptical properties, and potential applications.
This review focuses on liquid crystal-templated chiral functional nanomaterials, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, introducing their underlying mechanisms, chiroptical properties, and potential applications.
Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond.This review focuses on liquid crystal-templated chiral functional nanomaterials, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, introducing their underlying mechanisms, chiroptical properties, and potential applications.
ArticleNumber 223
Author Xu, Yiyi
Li, Quan
Zhang, Xuan
Feng, Wei
Valenzuela, Cristian
Zhang, Xinfang
Wang, Ling
Author_xml – sequence: 1
  givenname: Xuan
  surname: Zhang
  fullname: Zhang, Xuan
  organization: School of Materials Science and Engineering, Tianjin University
– sequence: 2
  givenname: Yiyi
  surname: Xu
  fullname: Xu, Yiyi
  organization: Institute of Advanced Materials and School of Chemistry and Chemical Engineering, Southeast University
– sequence: 3
  givenname: Cristian
  surname: Valenzuela
  fullname: Valenzuela, Cristian
  organization: School of Materials Science and Engineering, Tianjin University
– sequence: 4
  givenname: Xinfang
  surname: Zhang
  fullname: Zhang, Xinfang
  organization: Advanced Materials and Liquid Crystal Institute and Chemical Physics Interdisciplinary Program, Kent State University
– sequence: 5
  givenname: Ling
  orcidid: 0000-0003-1035-5633
  surname: Wang
  fullname: Wang, Ling
  email: lwang17@tju.edu.cn
  organization: School of Materials Science and Engineering, Tianjin University
– sequence: 6
  givenname: Wei
  orcidid: 0000-0002-5816-7343
  surname: Feng
  fullname: Feng, Wei
  email: weifeng@tju.edu.cn
  organization: School of Materials Science and Engineering, Tianjin University
– sequence: 7
  givenname: Quan
  orcidid: 0000-0002-9042-360X
  surname: Li
  fullname: Li, Quan
  email: quanli3273@gmail.com
  organization: Institute of Advanced Materials and School of Chemistry and Chemical Engineering, Southeast University, Advanced Materials and Liquid Crystal Institute and Chemical Physics Interdisciplinary Program, Kent State University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/35835737$$D View this record in MEDLINE/PubMed
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Snippet Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse...
This review focuses on liquid crystal-templated chiral functional nanomaterials, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials,...
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SubjectTerms 639/624/399/354
639/624/399/919
Catalysis
Chirality
Circular dichroism
Lasers
Luminescence
Microwaves
Nanomaterials
Nanotechnology
Optical and Electronic Materials
Optical Devices
Optics
Photonics
Physics
Physics and Astronomy
Review
Review Article
Reviews
RF and Optical Engineering
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Title Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence
URI https://link.springer.com/article/10.1038/s41377-022-00913-6
https://www.ncbi.nlm.nih.gov/pubmed/35835737
https://www.proquest.com/docview/2689410102
https://www.proquest.com/docview/2691053626
https://pubmed.ncbi.nlm.nih.gov/PMC9283403
https://doaj.org/article/a41c554290a04b099e273f987397b2d3
Volume 11
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