丁腈橡胶热氧老化与防护的研究进展及反应机理探讨
综述了国内外丁腈橡胶（NBR）热氧老化及防护的研究进展，探讨了NBR热氧老化及2种防护类型的化学反应机理。NBR生胶热氧老化后使得分子链断裂生成带有醛、酮等基团的聚合物，并产生HCN、NH，等小分子化合物。胺类是抗热氧老化最佳的链终止型防老剂，酚类、烷基苯基亚磷酸酯类和硫酯类化合物的单一组分或复合体系是破坏氢化过氧化物型防老剂，硫酯类防老剂具有高效的抗热氧老化效果。...
Saved in:
| Published in | 合成橡胶工业 Vol. 40; no. 3; pp. 240 - 245 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
清华大学化工系,北京100084%中国石油兰州石化公司生产技术处,兰州,730060%清华大学化工系,北京,100084%中国石油兰州石化公司合成橡胶厂,兰州,730060%中国石油兰州石化公司乙烯厂,兰州,730060
2017
中国石油兰州石化公司合成橡胶厂,兰州730060 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-1255 |
Cover
| Abstract | 综述了国内外丁腈橡胶（NBR）热氧老化及防护的研究进展，探讨了NBR热氧老化及2种防护类型的化学反应机理。NBR生胶热氧老化后使得分子链断裂生成带有醛、酮等基团的聚合物，并产生HCN、NH，等小分子化合物。胺类是抗热氧老化最佳的链终止型防老剂，酚类、烷基苯基亚磷酸酯类和硫酯类化合物的单一组分或复合体系是破坏氢化过氧化物型防老剂，硫酯类防老剂具有高效的抗热氧老化效果。 |
|---|---|
| AbstractList | TQ333.7; 综述了国内外丁腈橡胶(NBR)热氧老化及防护的研究进展,探讨了NBR热氧老化及2种防护类型的化学反应机理.NBR生胶热氧老化后使得分子链断裂生成带有醛、酮等基团的聚合物,并产生HCN、NH3等小分子化合物.胺类是抗热氧老化最佳的链终止型防老剂,酚类、烷基苯基亚磷酸酯类和硫酯类化合物的单一组分或复合体系是破坏氢化过氧化物型防老剂,硫酯类防老剂具有高效的抗热氧老化效果. 综述了国内外丁腈橡胶（NBR）热氧老化及防护的研究进展，探讨了NBR热氧老化及2种防护类型的化学反应机理。NBR生胶热氧老化后使得分子链断裂生成带有醛、酮等基团的聚合物，并产生HCN、NH，等小分子化合物。胺类是抗热氧老化最佳的链终止型防老剂，酚类、烷基苯基亚磷酸酯类和硫酯类化合物的单一组分或复合体系是破坏氢化过氧化物型防老剂，硫酯类防老剂具有高效的抗热氧老化效果。 |
| Abstract_FL | The research progress of thermal oxidation aging and protection for nitrile rubber were reviewed with 17 references,the thermal oxidation reactions and the chemical reaction mechanisms of two kinds of protection were discussed.After thermal oxidation aging of nitrile rubber,the ldehyde and ketone groups were formed when the polymer chain was broken,meanwhile,some small molecules such as HCN,NH3 generated.The antioxidants as amines,phenols,alkyl phenyl phosphite esters and thioesters compounds,used singlely or mixed in nitrile rubber,were effectively to termminate chain radicals and destruct hydrogen peroxide.Thioesters was more effctive for antioxidation. |
| Author | 张守汉 高艳 于建 郑彩琴 高志兴 李晓军 |
| AuthorAffiliation | 中国石油兰州石化公司合成橡胶厂,兰州730060 中国石油兰州石化公司生产技术处,兰州730060 中国石油兰州石化公司乙烯厂,兰州730060 清华大学化工系,北京100084 |
| AuthorAffiliation_xml | – name: 中国石油兰州石化公司合成橡胶厂,兰州730060;清华大学化工系,北京100084%中国石油兰州石化公司生产技术处,兰州,730060%清华大学化工系,北京,100084%中国石油兰州石化公司合成橡胶厂,兰州,730060%中国石油兰州石化公司乙烯厂,兰州,730060 |
| Author_FL | GAO Zhi-xing LI Xiao-jun YU Jian ZHANG Shou-han GAO Yan ZHENG Cai-qin |
| Author_FL_xml | – sequence: 1 fullname: ZHANG Shou-han – sequence: 2 fullname: GAO Yan – sequence: 3 fullname: YU Jian – sequence: 4 fullname: ZHENG Cai-qin – sequence: 5 fullname: GAO Zhi-xing – sequence: 6 fullname: LI Xiao-jun |
| Author_xml | – sequence: 1 fullname: 张守汉 高艳 于建 郑彩琴 高志兴 李晓军 |
| BookMark | eNrjYmDJy89LZWHgNDQwMNA1NDI15WDgKi7OMjAwtjSztOBkcH2yo_FFa8ezlQtfNG973rz22YblLxoan_ZMe7Kj7-WMTc-6ljyf1fJ8wZTnK7e92D_76capT_u7nvb3Pt015dmcXc8ntD3rW_Ri3QoeBta0xJziVF4ozc0Q4uYa4uyh6-Pv7uns6KObbGppqmuRlpiampKYZGZskGyUYpCcbGJhkWJobpBmYGRgmGKUnJZqYZCSnJRonGqWmGxiZmmUamRobJxkbGJsZGiYmGZszM2gDjG2PDEvLTEvPT4rv7QoD2hhfEZyRVZ6JdAYcwNjA0NToEoliMrkjPy89MJMoNqCoszcxKLKeDNzI0MjSwMLS2MAVH5r1A |
| ClassificationCodes | TQ333.7 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DatabaseName | 中文期刊服务平台 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Research progress and discussion on reaction mechanism of thermal oxidation aging and protection for nitrile rubber |
| DocumentTitle_FL | Research progress and discussion on reaction mechanism of thermal oxidation aging and protection for nitrile rubber |
| EndPage | 245 |
| ExternalDocumentID | hcxjgy201703015 672129089 |
| GroupedDBID | -02 2B. 2C0 2RA 5XA 5XC 92H 92I 92L ACGFS ALMA_UNASSIGNED_HOLDINGS CCEZO CDRFL CQIGP CW9 GROUPED_DOAJ TCJ TGT U1G U5L W92 ~WA 4A8 93N ABJNI PSX |
| ID | FETCH-LOGICAL-c595-8faeedab630c2d0cc488d170f0201d2cfe80dcba3e6ac4692e2133b343211af33 |
| ISSN | 1000-1255 |
| IngestDate | Thu May 29 03:53:54 EDT 2025 Wed Feb 14 10:03:57 EST 2024 |
| IsPeerReviewed | false |
| IsScholarly | true |
| Issue | 3 |
| Keywords | 防老剂 antioxidant nitrile rubber 丁腈橡胶 热氧老化 反应机理 reaction mechanism review thermal oxidation aging 综述 |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c595-8faeedab630c2d0cc488d170f0201d2cfe80dcba3e6ac4692e2133b343211af33 |
| Notes | The research progress of thermal oxida- tion aging and protection for nitrile rubber were re- viewed with 17 references, the thermal oxidation re- actions and the chemical reaction mechanisms of two kinds of protection were discussed. After thermal oxidation aging of nitrile rubber , the ldehyde and ketone groups were formed when the polymer chain was broken, meanwhile, some small molecules such as HCN, NHa generated. The antioxidants as amines, phenols, alkyl phenyl phosphite esters and thioesters compounds, used singlely or mixed in ni- trile rubber, were effectively to termminate chain radicals and destruct hydrogen peroxide. Thioesters was more effetive for antioxidation. nitrile rubber; thermal oxidationaging; antioxidant ; reaction mechanism ; review 62-1036/TQ ZHANG Shou-han1,4, GAO Yan2, YU Jian4, ZHENG Cai-qin1, GAO Zhi-xing1, LI Xiao-jun3 （ 1. a. Synthetic Rubber Plant ; b. Department of Production ＆ Technology ; c. Ethylene Plant, Lanzhou Petrcchemical Company, PetroChina, Lanzhou 730060, China ; 2. D |
| PageCount | 6 |
| ParticipantIDs | wanfang_journals_hcxjgy201703015 chongqing_primary_672129089 |
| PublicationCentury | 2000 |
| PublicationDate | 2017 |
| PublicationDateYYYYMMDD | 2017-01-01 |
| PublicationDate_xml | – year: 2017 text: 2017 |
| PublicationDecade | 2010 |
| PublicationTitle | 合成橡胶工业 |
| PublicationTitleAlternate | China Synthetic Rubber Industry |
| PublicationTitle_FL | China Synthetic Rubber Industry |
| PublicationYear | 2017 |
| Publisher | 清华大学化工系,北京100084%中国石油兰州石化公司生产技术处,兰州,730060%清华大学化工系,北京,100084%中国石油兰州石化公司合成橡胶厂,兰州,730060%中国石油兰州石化公司乙烯厂,兰州,730060 中国石油兰州石化公司合成橡胶厂,兰州730060 |
| Publisher_xml | – name: 中国石油兰州石化公司合成橡胶厂,兰州730060 – name: 清华大学化工系,北京100084%中国石油兰州石化公司生产技术处,兰州,730060%清华大学化工系,北京,100084%中国石油兰州石化公司合成橡胶厂,兰州,730060%中国石油兰州石化公司乙烯厂,兰州,730060 |
| SSID | ssj0039698 ssib002263290 ssib046728776 ssib051370708 ssib001104941 |
| Score | 2.060879 |
| Snippet | ... TQ333.7;... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 240 |
| SubjectTerms | 丁腈橡胶 反应机理 热氧老化 综述 防老剂 |
| Title | 丁腈橡胶热氧老化与防护的研究进展及反应机理探讨 |
| URI | http://lib.cqvip.com/qk/92553X/201703/672129089.html https://d.wanfangdata.com.cn/periodical/hcxjgy201703015 |
| Volume | 40 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV29b9QwFLdOnWBAfIpSQDfgqQpK4jhnj85dThUSTIfU7ZQ4uTsxXIFeJehEVUCogpahIAQMgJCgAwgYqqoL_0zvg40_gfeckMtQIWCx3sV-P_v5OfHPTp6PkEu6E9sJEHFLR7ZnwaBwLenpxNJO4gsNBFkKjHe-es1fuO5dWeSLlcrP0ldLK4P4sl49NK7kf7wK18CvGCX7D54tQOECyOBfSMHDkP6Vj2no0UAAGaQhpJwKQUOfKklVdoXRwKdhDQXVwKzApqpmsmyjBSp1Kv3fOCENJZWCBi4WFooqD9WlosIIyqYyE6RBhpJNKgPECRwquQFsomIuNEyWMlo-lXWUERBq900VIVUu4igQRJkooyIWMxZBCvIhpgE4NIbn7ZfFaDQ5dWwvCICdwUAbhZxHG1WAZiIOGMLmjb4y9oNeALIpBZVI00lBA2vOGh54ZQRueqBm7OVZHtjZMFAgQG8ykwdyUN5gySJJ89kAw-6BAfLydJGdLpXfFqz87M9z0vwXn06xxYePPiy4XXzVCqQBqKEo7QEY_urgcT0lPoWn6U9fY8KkBgvcKX_kDqvBI7t4bcakL7PYz7zdeGBIb6nfvQU0yESl9TtRv1siUK3j5Fi-8qmqbBifIJXV3klytHQe5ikSHuytTR48Gu28nazvjtc_jb58mNxbGz5-frC3-ePFt9HG-_HL--M32-Od3cn3V8Ovz4ZbG8OtJ8P97dHr_fHTh6PNd5PPH0-TVjNs1Res_H8-LM0lt0QnAqIWxT6ztZvYWsOckjg1uwMrGSdxdScVdqLjiKV-pD1fuqnrMBZjRLTjRB3GzpCZ_lI_PUuqSSIiph0omcZe4sUydjggulEMC-84dmfJXNEf7ZvZcS7twiezpJr3UDu_yZfbPX3nRvcuDgvcO-Dn_ggwR45gyWyH7jyZGdxeSS8AZx3EF42ffwFVNHXM |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E4%B8%81%E8%85%88%E6%A9%A1%E8%83%B6%E7%83%AD%E6%B0%A7%E8%80%81%E5%8C%96%E4%B8%8E%E9%98%B2%E6%8A%A4%E7%9A%84%E7%A0%94%E7%A9%B6%E8%BF%9B%E5%B1%95%E5%8F%8A%E5%8F%8D%E5%BA%94%E6%9C%BA%E7%90%86%E6%8E%A2%E8%AE%A8&rft.jtitle=%E5%90%88%E6%88%90%E6%A9%A1%E8%83%B6%E5%B7%A5%E4%B8%9A&rft.au=%E5%BC%A0%E5%AE%88%E6%B1%89+%E9%AB%98%E8%89%B3+%E4%BA%8E%E5%BB%BA+%E9%83%91%E5%BD%A9%E7%90%B4+%E9%AB%98%E5%BF%97%E5%85%B4+%E6%9D%8E%E6%99%93%E5%86%9B&rft.date=2017&rft.issn=1000-1255&rft.volume=40&rft.issue=3&rft.spage=240&rft.epage=245&rft.externalDocID=672129089 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F92553X%2F92553X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fhcxjgy%2Fhcxjgy.jpg |