Development of a separation method for molybdenum from zirconium, niobium, and major elements of rubble samples
•Simple separation of Mo from Zr, Nb, and major elements in rubble was achieved.•No loss of Mo during digestion of rubble was confirmed.•Extraction of Fe and Cr on the TEVA resin was suppressed by ascorbic acid.•Kd values for Zr, Nb, and Mo in HF-HCl and HF-HNO3 medias were obtained. A method for se...
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| Published in | Journal of Chromatography A Vol. 1371; pp. 163 - 167 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
05.12.2014
Elsevier |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0021-9673 1873-3778 |
| DOI | 10.1016/j.chroma.2014.10.053 |
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| Abstract | •Simple separation of Mo from Zr, Nb, and major elements in rubble was achieved.•No loss of Mo during digestion of rubble was confirmed.•Extraction of Fe and Cr on the TEVA resin was suppressed by ascorbic acid.•Kd values for Zr, Nb, and Mo in HF-HCl and HF-HNO3 medias were obtained.
A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to enable 93Mo assay of the rubble samples. Although 93Mo analysis has been reported in a few studies, the known separation method is tedious and time consuming, or the target is a simple material. Therefore, a simple and rapid protocol for the separation of a complex material, i.e., the rubble sample, was developed in this study. Firstly, loss of Mo during the digestion of simulated rubble samples was evaluated. Next, weight distribution coefficients (Kd's) of Zr, Nb, and Mo between an extraction chromatographic resin (tetra valent actinide resin, TEVA resin) and acid solutions (HF-HCl and HF-HNO3 solutions) were determined to obtain suitable solution conditions for the separation of Mo from Zr and Nb. Based on the obtained Kd's, a chromatographic separation scheme was designed and applied to the digested solution of the simulated rubble sample. Consequently, Mo was successfully separated from Zr, Nb and other major metal ions of the simulated rubble sample. |
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| AbstractList | A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to enable 93Mo assay of the rubble samples. Although (93)Mo analysis has been reported in a few studies, the known separation method is tedious and time consuming, or the target is a simple material. Therefore, a simple and rapid protocol for the separation of a complex material, i.e., the rubble sample, was developed in this study. Firstly, loss of Mo during the digestion of simulated rubble samples was evaluated. Next, weight distribution coefficients (Kd's) of Zr, Nb, and Mo between an extraction chromatographic resin (tetra valent actinide resin, TEVA resin) and acid solutions (HF-HCl and HF-HNO3 solutions) were determined to obtain suitable solution conditions for the separation of Mo from Zr and Nb. Based on the obtained Kd's, a chromatographic separation scheme was designed and applied to the digested solution of the simulated rubble sample. Consequently, Mo was successfully separated from Zr, Nb and other major metal ions of the simulated rubble sample. •Simple separation of Mo from Zr, Nb, and major elements in rubble was achieved.•No loss of Mo during digestion of rubble was confirmed.•Extraction of Fe and Cr on the TEVA resin was suppressed by ascorbic acid.•Kd values for Zr, Nb, and Mo in HF-HCl and HF-HNO3 medias were obtained. A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to enable 93Mo assay of the rubble samples. Although 93Mo analysis has been reported in a few studies, the known separation method is tedious and time consuming, or the target is a simple material. Therefore, a simple and rapid protocol for the separation of a complex material, i.e., the rubble sample, was developed in this study. Firstly, loss of Mo during the digestion of simulated rubble samples was evaluated. Next, weight distribution coefficients (Kd's) of Zr, Nb, and Mo between an extraction chromatographic resin (tetra valent actinide resin, TEVA resin) and acid solutions (HF-HCl and HF-HNO3 solutions) were determined to obtain suitable solution conditions for the separation of Mo from Zr and Nb. Based on the obtained Kd's, a chromatographic separation scheme was designed and applied to the digested solution of the simulated rubble sample. Consequently, Mo was successfully separated from Zr, Nb and other major metal ions of the simulated rubble sample. A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to enable ⁹³Mo assay of the rubble samples. Although ⁹³Mo analysis has been reported in a few studies, the known separation method is tedious and time consuming, or the target is a simple material. Therefore, a simple and rapid protocol for the separation of a complex material, i.e., the rubble sample, was developed in this study. Firstly, loss of Mo during the digestion of simulated rubble samples was evaluated. Next, weight distribution coefficients (Kd's) of Zr, Nb, and Mo between an extraction chromatographic resin (tetra valent actinide resin, TEVA resin) and acid solutions (HF-HCl and HF-HNO3 solutions) were determined to obtain suitable solution conditions for the separation of Mo from Zr and Nb. Based on the obtained Kd's, a chromatographic separation scheme was designed and applied to the digested solution of the simulated rubble sample. Consequently, Mo was successfully separated from Zr, Nb and other major metal ions of the simulated rubble sample. A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to enable super(93)Mo assay of the rubble samples. Although super(93)Mo analysis has been reported in a few studies, the known separation method is tedious and time consuming, or the target is a simple material. Therefore, a simple and rapid protocol for the separation of a complex material, i.e., the rubble sample, was developed in this study. Firstly, loss of Mo during the digestion of simulated rubble samples was evaluated. Next, weight distribution coefficients (K sub(d)'s) of Zr, Nb, and Mo between an extraction chromatographic resin (tetra valent actinide resin, TEVA resin) and acid solutions (HF-HCl and HF-HNO sub(3) solutions) were determined to obtain suitable solution conditions for the separation of Mo from Zr and Nb. Based on the obtained K sub(d)'s, a chromatographic separation scheme was designed and applied to the digested solution of the simulated rubble sample. Consequently, Mo was successfully separated from Zr, Nb and other major metal ions of the simulated rubble sample. |
| Author | Ozawa, Mayumi Yabuki, Koshi Shimada, Asako Kimiyama, Kazuhiro Sato, Kenji Kameo, Yutaka |
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| Cites_doi | 10.1016/j.nds.2011.04.001 10.1016/j.apradiso.2009.08.011 10.1016/0003-2670(95)00144-O 10.1021/ac60160a019 10.1021/ac400918r 10.1016/S0003-2670(00)86889-0 10.1080/00223131.2014.915769 10.1021/ac60147a002 10.1007/BF02060599 10.1039/b105708c 10.1007/BF02040307 10.1021/ac60177a045 10.1080/00223131.2014.921583 10.1039/a908278f |
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| Keywords | Waste management Weight distribution coefficient 93Mo Mutual separation TEVA resin Fukushima Daiichi Nuclear Power Station Radioactive waste Demolition waste Mo Waste treatment Transition metal Partition coefficient Radioisotope Niobium Acidic solution Separation method Zirconium Nuclear power plant Extraction chromatography Molybdenum 93 |
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| Snippet | •Simple separation of Mo from Zr, Nb, and major elements in rubble was achieved.•No loss of Mo during digestion of rubble was confirmed.•Extraction of Fe and... A method for separation of Mo from Zr, Nb, and other major elements of rubble samples from the Fukushima Daiichi Nuclear Power Station (FDNPS) was developed to... |
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| SubjectTerms | 93Mo actinides Applied sciences Chromatography Chromatography, Liquid Exact sciences and technology Fukushima Daiichi Nuclear Power Station Hafnium Ions metal ions molybdenum Molybdenum - isolation & purification Mutual separation Niobium Niobium - chemistry nuclear power Pollution Polymers power plants Radioactive wastes Resins Separation Simulation TEVA resin Waste management Wastes Weight distribution coefficient Zirconium Zirconium - chemistry |
| Title | Development of a separation method for molybdenum from zirconium, niobium, and major elements of rubble samples |
| URI | https://dx.doi.org/10.1016/j.chroma.2014.10.053 https://www.ncbi.nlm.nih.gov/pubmed/25456594 https://www.proquest.com/docview/1800443010 https://www.proquest.com/docview/2101373488 |
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