离子液体改性氧化石墨烯／丁苯橡胶复合材料的热降解动力学
为了提高氧化石墨烯（GO）在丁苯橡胶（SBR）中的分散性，采用离子液体氯化1-烯丙基-3-甲基咪唑（AMIMCI）对GO进行改性。得到了离子液体改性GO（GO-IL）。通过乳液混合法制备了GO-IL／SBR复合材料，研究了GO-IL／SBR硫化胶的热稳定性，并分别采用Kissinger法和Flynne-walle-Ozawa法计算了该硫化胶的热降解活化能。结果表明，与未改性的GO相比，GO-IL能明显提高SBR硫化胶的热稳定性；当填料用量为5份（质量）时，GO-IL／SBR硫化胶的最大热失重温度和热降解活化能比GO／SBR硫化胶分别提高了4．0℃和17．35kJ／mol。...
Saved in:
| Published in | 合成橡胶工业 Vol. 41; no. 1; pp. 6 - 11 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
南京理工大学 教育部软化学和功能材料重点实验室,南京,210094%南京东瑞减震控制科技有限公司,南京,210096
2018
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-1255 |
| DOI | 10.3969/j.issn.1000-1255.2018.01.003 |
Cover
| Abstract | 为了提高氧化石墨烯（GO）在丁苯橡胶（SBR）中的分散性，采用离子液体氯化1-烯丙基-3-甲基咪唑（AMIMCI）对GO进行改性。得到了离子液体改性GO（GO-IL）。通过乳液混合法制备了GO-IL／SBR复合材料，研究了GO-IL／SBR硫化胶的热稳定性，并分别采用Kissinger法和Flynne-walle-Ozawa法计算了该硫化胶的热降解活化能。结果表明，与未改性的GO相比，GO-IL能明显提高SBR硫化胶的热稳定性；当填料用量为5份（质量）时，GO-IL／SBR硫化胶的最大热失重温度和热降解活化能比GO／SBR硫化胶分别提高了4．0℃和17．35kJ／mol。 |
|---|---|
| AbstractList | 为了提高氧化石墨烯（GO）在丁苯橡胶（SBR）中的分散性，采用离子液体氯化1-烯丙基-3-甲基咪唑（AMIMCI）对GO进行改性。得到了离子液体改性GO（GO-IL）。通过乳液混合法制备了GO-IL／SBR复合材料，研究了GO-IL／SBR硫化胶的热稳定性，并分别采用Kissinger法和Flynne-walle-Ozawa法计算了该硫化胶的热降解活化能。结果表明，与未改性的GO相比，GO-IL能明显提高SBR硫化胶的热稳定性；当填料用量为5份（质量）时，GO-IL／SBR硫化胶的最大热失重温度和热降解活化能比GO／SBR硫化胶分别提高了4．0℃和17．35kJ／mol。 TQ333.1; 为了提高氧化石墨烯(GO)在丁苯橡胶(SBR)中的分散性,采用离子液体氯化1-烯丙基-3-甲基咪唑(AMIMCl)对GO进行改性,得到了离子液体改性GO(GO-IL).通过乳液混合法制备了GO-IL/SBR复合材料,研究了GO-IL/SBR硫化胶的热稳定性,并分别采用Kissinger法和Flynne-Walle-Ozawa法计算了该硫化胶的热降解活化能.结果表明,与未改性的GO相比,GO-IL能明显提高SBR硫化胶的热稳定性;当填料用量为5份(质量)时,GO-IL/SBR硫化胶的最大热失重温度和热降解活化能比GO/SBR硫化胶分别提高了4.0 ℃和17.35 kJ/mol. |
| Abstract_FL | In order to improve the dispersion of graphene oxide (GO) in styrene-butadiene rubber (SBR) matrix, ionic liquid 1-allyl-3-methylimidazolium chloride (AMIMCl) was used to modify GO,and the obtained filler, ionic liquid modified GO (GO-IL), was emulsion blended with SBR to prepare GO-IL/ SBR composite. The thermal stability of GO-IL/ SBR vulcanizate was investigated, and their thermal decomposition activation energy was calculated by Kissinger and Flynne-Walle-Ozawa methods,respectively. The results showed that GO-IL significantly improved the thermal stability of SBR vulcanizate compared with unmodified GO. When the filler was 5 phr, the maximum thermal mass loss temperature and the thermal decomposition activation energy of GO-IL/ SBR vulcanizate increased by 4. 0 ℃ and 17. 35 kJ/ mol compared with those of GO/ SBR vulcanizate separately. |
| Author | 陈杨;张旭敏;薛晓东;贾红兵;徐赵东 |
| AuthorAffiliation | 南京理工大学教育部软化学和功能材料重点实验室,南京210094;南京东瑞减震控制科技有限公司,南京210096 |
| AuthorAffiliation_xml | – name: 南京理工大学 教育部软化学和功能材料重点实验室,南京,210094%南京东瑞减震控制科技有限公司,南京,210096 |
| Author_FL | CHEN Yang XUE Xiao-dong ZHANG Xu-min XU Zhao-dong JIA Hong-bing |
| Author_FL_xml | – sequence: 1 fullname: CHEN Yang – sequence: 2 fullname: ZHANG Xu-min – sequence: 3 fullname: XUE Xiao-dong – sequence: 4 fullname: JIA Hong-bing – sequence: 5 fullname: XU Zhao-dong |
| Author_xml | – sequence: 1 fullname: 陈杨;张旭敏;薛晓东;贾红兵;徐赵东 |
| BookMark | eNo9j09LAkEAxedgkFpfIoJOu83s7M7uHEP6B0JE3WWdnVWXWsslyluhh7AkoRAsIvqD2kGMAimqb-PM2qmv0IbR6cHj997jJUDML_ocgFkEVUwJnffUQhD4KoIQKkgzDFWDyFIhUiHEMRD_9ydBIgi8yIxCVhysh-130WvIwfPw81xevMnDjnzqiNNmePMi7rphpf_9cTZ8PRqd9OXj7agyEA910TiW1w3ZbIWX1bDS-2rVR517UeuK2pXotafAhGtvBXz6T5NgY2lxM7WipNeWV1MLaYUZFCuUOK6j6cTlXOcMm1aWmcjMwqwNqQYZ4q6rY4fbFjEcgik1EOHMgppBmEYYxUkwN27dt33X9nMZr7hX8qO9TJ4deLny73sYncYROTMmWb7o53YLEbtTKmzbpXKGmDpGiGIT_wCAFHyZ |
| ClassificationCodes | TQ333.1 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.3969/j.issn.1000-1255.2018.01.003 |
| DatabaseName | 维普期刊资源整合服务平台 中文科技期刊数据库-CALIS站点 中文科技期刊数据库-7.0平台 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Thermal degradation kinetics of ionic liquid modified graphene oxide/ styrene-butadiene rubber composite |
| DocumentTitle_FL | Thermal degradation kinetics of ionic liquid modified graphene oxide/styrene-butadiene rubber composite |
| EndPage | 11 |
| ExternalDocumentID | hcxjgy201801003 674311937 |
| GroupedDBID | -02 2B. 2C0 2RA 5XA 5XC 92H 92I 92L ACGFS ALMA_UNASSIGNED_HOLDINGS CCEZO CDRFL CQIGP CW9 GROUPED_DOAJ TCJ TGT U1G U5L W92 ~WA 4A8 93N ABJNI PSX |
| ID | FETCH-LOGICAL-c593-96dfd246fee4ec378bc717b0ba0920c1eff43dea865d6399516ec80256c26c93 |
| ISSN | 1000-1255 |
| IngestDate | Thu May 29 03:53:54 EDT 2025 Wed Feb 14 10:08:08 EST 2024 |
| IsPeerReviewed | false |
| IsScholarly | true |
| Issue | 1 |
| Keywords | styrene-butadiene rubber ionic liquid graphene oxide composite 复合材料 热稳定性 氧化石墨烯 thermal stability 离子液体 丁苯橡胶 |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c593-96dfd246fee4ec378bc717b0ba0920c1eff43dea865d6399516ec80256c26c93 |
| Notes | In order to improve the dispersion of graphene oxide （GO） in styrene-butadiene rubber （SBR） matrix, ionic liquid 1-allyl-3-methylimidazo- lium chloride （AMIMC1） was used to modify GO, and the obtained filler, ionic liquid modified GO （GO-IL） , was emulsion blended with SBR to pre- pare GO-IL/SBR composite. The thermal stability of GO-IL/SBR vulcanizate was investigated, and their thermal decomposition activation energy was ealcu- lated by Kissinger and Flynne-Walle-Ozawa me-thods, respectively. The results showed that GO-IL significantly improved the thermal stability of SBR vulcanizate compared with unmodified GO. When the filler was 5 phr, the maximum thermal mass loss temperature and the thermal decomposition activation energy of GO-IL/SBR vulcanizate increased by 4.0℃ and 17, 35 kJ/mol compared with those of GO/SBR vulcanizate separately. graphene oxide; styrene-butadienerubber; composite; ionic liquid; thermal stability CHEN Yang1 , ZHANG Xu-min1 , XUE Xiao-dong1 , JIA Hong-bing1 , XU Zhao-dong2 （ 1. Key L |
| PageCount | 6 |
| ParticipantIDs | wanfang_journals_hcxjgy201801003 chongqing_primary_674311937 |
| PublicationCentury | 2000 |
| PublicationDate | 2018 |
| PublicationDateYYYYMMDD | 2018-01-01 |
| PublicationDate_xml | – year: 2018 text: 2018 |
| PublicationDecade | 2010 |
| PublicationTitle | 合成橡胶工业 |
| PublicationTitleAlternate | China Synthetic Rubber Industry |
| PublicationTitle_FL | China Synthetic Rubber Industry |
| PublicationYear | 2018 |
| Publisher | 南京理工大学 教育部软化学和功能材料重点实验室,南京,210094%南京东瑞减震控制科技有限公司,南京,210096 |
| Publisher_xml | – name: 南京理工大学 教育部软化学和功能材料重点实验室,南京,210094%南京东瑞减震控制科技有限公司,南京,210096 |
| SSID | ssj0039698 ssib002263290 ssib046728776 ssib051370708 ssib001104941 |
| Score | 2.1018524 |
| Snippet | ... TQ333.1;... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 6 |
| SubjectTerms | 丁苯橡胶 复合材料 氧化石墨烯 热稳定性 离子液体 |
| Title | 离子液体改性氧化石墨烯／丁苯橡胶复合材料的热降解动力学 |
| URI | http://lib.cqvip.com/qk/92553X/201801/674311937.html https://d.wanfangdata.com.cn/periodical/hcxjgy201801003 |
| Volume | 41 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3Na9VAEF_aCqIH8RNrVXroHl9Nsslm9-Bh85pHERTECr098tni4dWPFrQnpR6kWiwohSoiftDWQ6koFEX9b5r36sl_wZlNXpqqFBUey2SSzPx2JsnMZrPzCBmSThjBsIHXeBizmh3CgFWEFquZEM1tO-GGG-KM7sVLfPSqfWHcGe_pPV_5amlmOhyOZv-4ruR_vAo88Cuukv0Hz5ZCgQE0-Bda8DC0f-Vj6rtUcep51HeoGqHSoD5sws-ivk094DDkSKAlEsKgytXH5IRDRZ1KjnJkg3pMy7GoEsgRjKoG9YFfp6KhBQpIPKkPrad3caokVTmHoV48HZLTESQAjBBaexcYKJJS61JU2F0VcLBEPp4lEJXSMITSMDQhux1UvJpM79ICba7ld0geyHQK_LK8YrtquxhBG9N6oLsqx-tqdEA4aADcK3QnPM2U2rq51Hqx14NNH3vmKTQkwgeBTleyrzEK5Hglonr1zcuuMIHr8SE1dKpxJC_gtet-yYMCr2QXeWT5NW4xyaWOWyh9uJSOXx4KXVXWYDvxuvyKEtePmJCAu71kn-W6plN5o6CzYROL_1SyM6zNvzMpCiEShss72ahjMhcCQDkJh6DylaQFnP1kqMB6bi-kWKVkcqo1cQNyL70UrpUGrYlK1jZ2mBwqhluDKr93jpCe2cmj5GClCOcxcrmz8iVbX2xvftj69qT99HP77mr7_Wr2aKnz8mP2eq0zt_Hj6-OtT_e2H260373antvM3i5kiw_aLxbbS8udZ_c7c-vflxe2V99k82vZ_PNsfeU4udLwx-qjteKPRmqRI1lN8jiNLZunSWInEXNFGLmmGxphYEjLiMwkTW0WJ4HgTowJvWPyJBI4WIgsHkl2gvS1plrJSTKIxbysIAiT2I1tGBsEYZCGLAxwupoHadpPBkrTNK_n5WSapRv7yWBhrGbxkLnVnIxuX5u4g9Y1wNjs1J4CBsgBPDJ_Q3ia9E3fnEnOQM48HZ7VV8ZPyIuY0w |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E7%A6%BB%E5%AD%90%E6%B6%B2%E4%BD%93%E6%94%B9%E6%80%A7%E6%B0%A7%E5%8C%96%E7%9F%B3%E5%A2%A8%E7%83%AF%EF%BC%8F%E4%B8%81%E8%8B%AF%E6%A9%A1%E8%83%B6%E5%A4%8D%E5%90%88%E6%9D%90%E6%96%99%E7%9A%84%E7%83%AD%E9%99%8D%E8%A7%A3%E5%8A%A8%E5%8A%9B%E5%AD%A6&rft.jtitle=%E5%90%88%E6%88%90%E6%A9%A1%E8%83%B6%E5%B7%A5%E4%B8%9A&rft.au=%E9%99%88%E6%9D%A8%3B%E5%BC%A0%E6%97%AD%E6%95%8F%3B%E8%96%9B%E6%99%93%E4%B8%9C%3B%E8%B4%BE%E7%BA%A2%E5%85%B5%3B%E5%BE%90%E8%B5%B5%E4%B8%9C&rft.date=2018&rft.issn=1000-1255&rft.volume=41&rft.issue=1&rft.spage=6&rft.epage=11&rft_id=info:doi/10.3969%2Fj.issn.1000-1255.2018.01.003&rft.externalDocID=674311937 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F92553X%2F92553X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fhcxjgy%2Fhcxjgy.jpg |