少铅钙钛矿CH3NH3SrxPb（1-x）I3的合成及其在全固态薄膜太阳能电池中的应用
近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池（PSCs）得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看, Pb的毒性将制约其大规模应用.本文从减少吸光材料中Pb的含量出发,尝试用Sr部分取代Pb制备一系列少铅钙钛矿CH3NH3SrxPb（1-x）I3,并将其应用于钙钛矿太阳能电池进行光电性能的研究.研究结果表明,相比于全Pb钙钛矿（CH3NH3PbI3）材料, Sr取代量为30%（x=0.3）时,所形成的CH3NH3Sr0.3Pb0.7I3光谱吸收大范围增强,但基于此材料制备的电池器件性能明显下降....
Saved in:
| Published in | 物理化学学报 Vol. 31; no. 2; pp. 285 - 290 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024%大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024
2015
九州工业大学生命体工学研究科，北九州808-0196，福冈，日本 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-6818 |
| DOI | 10.3866/PKU.WHXB201412241 |
Cover
| Abstract | 近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池（PSCs）得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看, Pb的毒性将制约其大规模应用.本文从减少吸光材料中Pb的含量出发,尝试用Sr部分取代Pb制备一系列少铅钙钛矿CH3NH3SrxPb（1-x）I3,并将其应用于钙钛矿太阳能电池进行光电性能的研究.研究结果表明,相比于全Pb钙钛矿（CH3NH3PbI3）材料, Sr取代量为30%（x=0.3）时,所形成的CH3NH3Sr0.3Pb0.7I3光谱吸收大范围增强,但基于此材料制备的电池器件性能明显下降. |
|---|---|
| AbstractList | O644; 近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池(PSCs)得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看, Pb的毒性将制约其大规模应用.本文从减少吸光材料中Pb的含量出发,尝试用Sr部分取代Pb制备一系列少铅钙钛矿CH3NH3SrxPb(1-x)I3,并将其应用于钙钛矿太阳能电池进行光电性能的研究.研究结果表明,相比于全Pb钙钛矿(CH3NH3PbI3)材料, Sr取代量为30%(x=0.3)时,所形成的CH3NH3Sr0.3Pb0.7I3光谱吸收大范围增强,但基于此材料制备的电池器件性能明显下降. 近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池（PSCs）得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看, Pb的毒性将制约其大规模应用.本文从减少吸光材料中Pb的含量出发,尝试用Sr部分取代Pb制备一系列少铅钙钛矿CH3NH3SrxPb（1-x）I3,并将其应用于钙钛矿太阳能电池进行光电性能的研究.研究结果表明,相比于全Pb钙钛矿（CH3NH3PbI3）材料, Sr取代量为30%（x=0.3）时,所形成的CH3NH3Sr0.3Pb0.7I3光谱吸收大范围增强,但基于此材料制备的电池器件性能明显下降. |
| Abstract_FL | Hybrid organic-inorganic lead halide perovskite solar cel s (PSCs) have recently undergone rapid progress and exhibit high photoelectric conversion efficiencies of up to 19.3%. As light-absorber in PSCs, the hybrid organic-inorganic lead halide perovskite cannot be used in large-scale applications because of its high Pb content. In this work, we replaced some Pb with Sr to synthesize a novel perovskite CH3NH3SrxPb(1-x)I3 and used it as a light-absorber in PSCs. Compared with CH3NH3PbI3, CH3NH3Sr0.3Pb0.7I3 is a better light-absorber but the corresponding photovoltaic performance in PSCs decreased obviously. |
| Author | 白晓功 史彦涛 王开 董庆顺 邢玉瑾 张鸿 王亮 马廷丽 |
| AuthorAffiliation | 大连理工大学化学学院,精细化工国家重点实验室,辽宁大连116024 九州工业大学生命体工学研究科,北九州808-0196,福冈,日本 |
| AuthorAffiliation_xml | – name: 大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024%大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024; 九州工业大学生命体工学研究科，北九州808-0196，福冈，日本 |
| Author_FL | BAI Xiao-Gong MA Ting-Li SHI Yan-Tao ZHANG Hong WANG Liang DONG Qing-Shun WANG Kai XING Yu-Jin |
| Author_FL_xml | – sequence: 1 fullname: BAI Xiao-Gong – sequence: 2 fullname: SHI Yan-Tao – sequence: 3 fullname: WANG Kai – sequence: 4 fullname: DONG Qing-Shun – sequence: 5 fullname: XING Yu-Jin – sequence: 6 fullname: ZHANG Hong – sequence: 7 fullname: WANG Liang – sequence: 8 fullname: MA Ting-Li |
| Author_xml | – sequence: 1 fullname: 白晓功 史彦涛 王开 董庆顺 邢玉瑾 张鸿 王亮 马廷丽 |
| BookMark | eNotkE9LAkEAxedgkJkfoGuXTmvzZ3d2PZZUK0kJGXWTmdldNWwtJdxuRRrWJTOJSqEOHSQIiihCjL5M6-rJr9CGXd67_N578KZAwC7YJgAzCEaIRul8cnUzsqVvL2KIZISxjAIgiCCEEtWQNgnCpVKOQ4gQVDDVgoC5L5fDq-qwcTtstLz775hO1nSyUXSSfNSrIckZ9c7ixLuruPVav1Z3L87d6ofb7rjVjtvq9o-OB9eVwWnbfXwa3rwNTr685nv_9eHn8_kv0m16zc40mLBYvmSG_z0EUstLqZguJdZX4rGFhCSUKJaobFERJYqhqpbKkWoomsVVaJgCciyiAnGIDI4ZRwZjqsn8jKEILFQihFCRTEJgblxbZrbF7Ex6p3BQtP3BdDmfdRzu_6FAX7BPzo5JkS3Ymf2cz-4Vc7useJimlFCiIaqRX6gvgDw |
| ClassificationCodes | O644 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.3866/PKU.WHXB201412241 |
| DatabaseName | 维普_期刊 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| DocumentTitleAlternate | Synthesis of CH3NH3SrxPb（1-x）I3 with Less Pb Content and Its Application in All-Solid Thin Film Solar Cells |
| DocumentTitle_FL | Synthesis of CH3NH3SrxPb(1-x)I3 with Less Pb Content and Its Application in All-Solid Thin Film Solar Cells |
| EndPage | 290 |
| ExternalDocumentID | wlhxxb201502012 663638168 |
| GrantInformation_xml | – fundername: The project was supported by the National Natural Science Foundation of China; International Science&Technology Cooperation Program of China (2013DFA51000).国家自然科学基金; 中国国际科技合作计划 funderid: (51402036,51273032,91333104); (51402036,51273032,91333104); (2013DFA51000) |
| GroupedDBID | -02 2B. 2C. 2RA 5XA 5XC 92E 92I 92L ACGFS AENEX ALMA_UNASSIGNED_HOLDINGS CCEZO CDRFL CQIGP CW9 EBS EJD FIJ OK1 P2P RIG TCJ TGP U1G U5L ~WA 4A8 93N AAXUO AAYWO ADMLS FDB M41 PSX ROL UY8 |
| ID | FETCH-LOGICAL-c592-64f6c935d77f7b17d58fb70dec0b2c9c1b01db2ab1daa7ea592d5c2c73ccc7143 |
| ISSN | 1000-6818 |
| IngestDate | Thu May 29 03:54:35 EDT 2025 Wed Feb 14 10:38:14 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 2 |
| Keywords | 钙钛矿太阳能电池 Perovskite solar cel Less Pb 锶取代 Sr replacing CH3NH3SrxPb(1-x)I3 少铅 |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c592-64f6c935d77f7b17d58fb70dec0b2c9c1b01db2ab1daa7ea592d5c2c73ccc7143 |
| Notes | 11-1892/06 Hybrid organic-inorganic lead halide perovskite solar cel s （PSCs） have recently undergone rapid progress and exhibit high photoelectric conversion efficiencies of up to 19.3%. As light-absorber in PSCs, the hybrid organic-inorganic lead halide perovskite cannot be used in large-scale applications because of its high Pb content. In this work, we replaced some Pb with Sr to synthesize a novel perovskite CH3NH3SrxPb（1-x）I3 and used it as a light-absorber in PSCs. Compared with CH3NH3PbI3, CH3NH3Sr0.3Pb0.7I3 is a better light-absorber but the corresponding photovoltaic performance in PSCs decreased obviously. BAI Xiao-Gong SHI Yan-Tao WANG Kai DONG Qing-Shun XlNG Yu-Jin ZHANG Hong WANG Liang MA Ting（1State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning Province, R R. China; 2Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, Kitakyushu 808-0196, Fukuoka, Japan） Perovskite solar cell; Less Pb; Sr replac |
| PageCount | 6 |
| ParticipantIDs | wanfang_journals_wlhxxb201502012 chongqing_primary_663638168 |
| PublicationCentury | 2000 |
| PublicationDate | 2015 |
| PublicationDateYYYYMMDD | 2015-01-01 |
| PublicationDate_xml | – year: 2015 text: 2015 |
| PublicationDecade | 2010 |
| PublicationTitle | 物理化学学报 |
| PublicationTitleAlternate | Acta Physico-Chimica Sinica |
| PublicationTitle_FL | Acta Physico-Chimica Sinica |
| PublicationYear | 2015 |
| Publisher | 大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024%大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024 九州工业大学生命体工学研究科，北九州808-0196，福冈，日本 |
| Publisher_xml | – name: 九州工业大学生命体工学研究科，北九州808-0196，福冈，日本 – name: 大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024%大连理工大学化学学院，精细化工国家重点实验室，辽宁大连116024 |
| SSID | ssib001105268 ssj0030168 ssib024507715 ssib002258135 ssib051374152 ssib057925156 |
| Score | 2.0529227 |
| Snippet | 近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池（PSCs）得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看,... O644; 近年来,有机-无机杂化铅卤化物钙钛矿太阳能电池(PSCs)得到了迅猛发展,其最高光电转换效率已经达到19.3%.该类型太阳能电池使用的钙钛矿型吸光材料为含Pb的有机-无机杂化铅卤钙钛矿,从长远来看,... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 285 |
| SubjectTerms | CH3NH3SrxPb（1-x）I3 少铅 钙钛矿太阳能电池 锶取代 |
| Title | 少铅钙钛矿CH3NH3SrxPb（1-x）I3的合成及其在全固态薄膜太阳能电池中的应用 |
| URI | http://lib.cqvip.com/qk/92644X/201502/663638168.html https://d.wanfangdata.com.cn/periodical/wlhxxb201502012 |
| Volume | 31 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw5R3LThRBcELgoBfjMyJqONg3F-fZ032cnp3NgpGQCJHbZl4LB7MoQtxw0ggGvYhIjAqJHjwQExON0RiC8WccFk78glU9szvDqvFx9TKp7a539c5UdfqhKBd8U2M-17WSEdsRFCgwjFkY0RIMD25GVmjSEOchr4zS6oQ5MmlN9vRdLKxamp8LhsKFn-4r-ZeoQhvEFXfJ_kVkO0yhAWCILzwhwvD8oxgTzyJCJVwjHifcIMySgE44bwOCeDbhFSIqbtUYrRpXZ5tjAfGgwSWMaaVmG-bDhkR1CDORL1ehn3gUnwBDC6sQ5kgApFKJ4xKHZS0pAPKEI6mAHNQCWioZMsIo4gOOYxLHkfoxIgzZZRBRltJNIiwkFxpxQCj8ZMQpH1AM-ANaiuywYnKNjYwTh8teFSWibi7qgHLLxCkCFM1xrPaQk0RcKkIRAH8iNUir5CjSC0KXerS5gC-4KHJhHmFCooBf1byHYaQcIzMCtQNlNZJNlWRTL-m2U_k3aTvLRlJRIdw7YJiwQfsCTsHCX9rM0TJHbwfdRYZgjpCcheh2WUcExrUs-Xgy9pwwsFMGhgE5z7pQQ47RZW7WArrlshgK6vDB8dFtoKZRSOeIbv23theyBDyOgbI8cejM32RZQHoLVZZQ6ul9uN25isEoTpuNXZ4YuladFDquuMZ8Ok_MOstlb1-fbjYDHIFQ3OGV6n26bWu4gLkyPJIXP5o8u6mQnFtMy4sh3YTSz86Tf0szsJroFDeWzaHWwZO10jwWvvzZRuLM2HRNCKp96Qel8WSa6ZnG1E3It-X2x0bdb0wVMvXxo8qRrMQedNL35TGlZ2H6uHLIbd9seULxk3eP954s7a0-31tdb738Wngz7m8vwztxf_vBsNF6sZisLO8srySPHiZLn5KNzWRpM1nf2rlzd_fp4u79jeT1m71nH3bvfWmtfdx5_-rb57dIsrXWWts8qYxXvHG3WsqumimFFtdL1KzTkBtWZNt1O9DsyGL1wFajOFQDPeShFqhaFOh-oEW-b8c-0MB3TA9tIwxDG0rOU0pvY6YRn1YGTepHFpQGcayHJq-rLOKQN8WM-pD8qHW9XxnoeKp2Iz1RqAZlH8UVHKxfGcx8V8u-M7dqXdE_83uUAeUwwulM8Vmld252Pj4HtdNccF4Ome-ikwv7 |
| linkProvider | Ingenta |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E5%B0%91%E9%93%85%E9%92%99%E9%92%9B%E7%9F%BFCH3NH3SrxPb%EF%BC%881-x%EF%BC%89I3%E7%9A%84%E5%90%88%E6%88%90%E5%8F%8A%E5%85%B6%E5%9C%A8%E5%85%A8%E5%9B%BA%E6%80%81%E8%96%84%E8%86%9C%E5%A4%AA%E9%98%B3%E8%83%BD%E7%94%B5%E6%B1%A0%E4%B8%AD%E7%9A%84%E5%BA%94%E7%94%A8&rft.jtitle=%E7%89%A9%E7%90%86%E5%8C%96%E5%AD%A6%E5%AD%A6%E6%8A%A5&rft.au=%E7%99%BD%E6%99%93%E5%8A%9F&rft.au=%E5%8F%B2%E5%BD%A6%E6%B6%9B&rft.au=%E7%8E%8B%E5%BC%80&rft.au=%E8%91%A3%E5%BA%86%E9%A1%BA&rft.date=2015&rft.pub=%E5%A4%A7%E8%BF%9E%E7%90%86%E5%B7%A5%E5%A4%A7%E5%AD%A6%E5%8C%96%E5%AD%A6%E5%AD%A6%E9%99%A2%EF%BC%8C%E7%B2%BE%E7%BB%86%E5%8C%96%E5%B7%A5%E5%9B%BD%E5%AE%B6%E9%87%8D%E7%82%B9%E5%AE%9E%E9%AA%8C%E5%AE%A4%EF%BC%8C%E8%BE%BD%E5%AE%81%E5%A4%A7%E8%BF%9E116024%25%E5%A4%A7%E8%BF%9E%E7%90%86%E5%B7%A5%E5%A4%A7%E5%AD%A6%E5%8C%96%E5%AD%A6%E5%AD%A6%E9%99%A2%EF%BC%8C%E7%B2%BE%E7%BB%86%E5%8C%96%E5%B7%A5%E5%9B%BD%E5%AE%B6%E9%87%8D%E7%82%B9%E5%AE%9E%E9%AA%8C%E5%AE%A4%EF%BC%8C%E8%BE%BD%E5%AE%81%E5%A4%A7%E8%BF%9E116024&rft.issn=1000-6818&rft.issue=2&rft.spage=285&rft.epage=290&rft_id=info:doi/10.3866%2FPKU.WHXB201412241&rft.externalDocID=wlhxxb201502012 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F92644X%2F92644X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fwlhxxb%2Fwlhxxb.jpg |