苝分子低聚体的形成及其光谱性质

探讨了苝分子低聚体的形成条件和影响因素，这些低聚体与晶核形成紧密相关．用荧光光谱和吸收光谱法研究了不同的水含量和花浓度对聚集的影响，低聚体属于具有光活性的J型，能发红光．计算得到低聚体的聚集数为9，平衡常数数量级较大．...

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Bibliographic Details
Published in物理化学学报 Vol. 28; no. 2; pp. 283 - 289
Main Author 刘丽敏 张先付
Format Journal Article
LanguageChinese
Published 河北科技师范学院理化学院,河北秦皇岛,066004%河北科技师范学院理化学院,河北秦皇岛,066004 2012
MPC Technologies, Hamilton, ON, Canada L8S 3H4
Subjects
平衡常数
晶核
聚集
聚集数
苝
荧光
聚集数
荧光
聚集
平衡常数
苝
晶核
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ISSN1000-6818
DOI10.3866/PKU.WHXB201111292

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Summary:探讨了苝分子低聚体的形成条件和影响因素，这些低聚体与晶核形成紧密相关．用荧光光谱和吸收光谱法研究了不同的水含量和花浓度对聚集的影响，低聚体属于具有光活性的J型，能发红光．计算得到低聚体的聚集数为9，平衡常数数量级较大．
Bibliography:11-1892/06
Perylene; Aggregation; Crystal nuclei; Aggregation number; Equilibrium constant;Fluorescence
We report the conditions required for the formation of perylene oligomers, which are closely related to the crystal nuclei for the formation of perylene nanocrystal. The effects of water content and perylene concentration on aggregation were studied using fluorescence and absorption spectra. The spectra indicated that fluorescent J-type perylene oligomers were formed. An aggregation number of 9, and large equilibrium constant were obtained for the reaction.
LIU Li-Mi ZHANG Xian-Fu （1College of Physics and Chemistry, Hebei Normal University of Science and Technology, Qinhuangdao 066004, Hebei Province, P R. China; 2MPC Technologies, Hamilton, ON, Canada L8S 3H4）
ISSN:1000-6818
DOI:10.3866/PKU.WHXB201111292