Metal-organic framework and inorganic glass composites
Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new...
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| Published in | Nature communications Vol. 11; no. 1; pp. 5800 - 12 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
16.11.2020
Nature Publishing Group Nature Portfolio |
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| Abstract | Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.
Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show that they can be combined with different inorganic aluminophosphate glasses to produce a composite with mechanical properties intermediate between the two end-members. |
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| AbstractList | Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.
Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show that they can be combined with different inorganic aluminophosphate glasses to produce a composite with mechanical properties intermediate between the two end-members. Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show that they can be combined with different inorganic aluminophosphate glasses to produce a composite with mechanical properties intermediate between the two end-members. Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself. Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show that they can be combined with different inorganic aluminophosphate glasses to produce a composite with mechanical properties intermediate between the two end-members. Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself. |
| ArticleNumber | 5800 |
| Author | Keen, David A. Calahoo, Courtney Tuffnell, Joshua M. Xia, Yang Sapnik, Adam F. Keeble, Dean S. Longley, Louis Thorne, Michael F. Limbach, René Wondraczek, Lothar Bennett, Thomas D. |
| Author_xml | – sequence: 1 givenname: Louis orcidid: 0000-0002-9178-9603 surname: Longley fullname: Longley, Louis organization: Department of Materials Science and Metallurgy, University of Cambridge – sequence: 2 givenname: Courtney surname: Calahoo fullname: Calahoo, Courtney organization: Otto Schott Institute of Materials Research, University of Jena – sequence: 3 givenname: René surname: Limbach fullname: Limbach, René organization: Otto Schott Institute of Materials Research, University of Jena – sequence: 4 givenname: Yang surname: Xia fullname: Xia, Yang organization: Otto Schott Institute of Materials Research, University of Jena – sequence: 5 givenname: Joshua M. surname: Tuffnell fullname: Tuffnell, Joshua M. organization: Department of Materials Science and Metallurgy, University of Cambridge – sequence: 6 givenname: Adam F. surname: Sapnik fullname: Sapnik, Adam F. organization: Department of Materials Science and Metallurgy, University of Cambridge – sequence: 7 givenname: Michael F. orcidid: 0000-0002-3188-2478 surname: Thorne fullname: Thorne, Michael F. organization: Department of Materials Science and Metallurgy, University of Cambridge – sequence: 8 givenname: Dean S. surname: Keeble fullname: Keeble, Dean S. organization: Diamond Light Source Ltd., Diamond House, Harwell Campus – sequence: 9 givenname: David A. orcidid: 0000-0003-0376-2767 surname: Keen fullname: Keen, David A. organization: ISIS Facility, Rutherford Appleton Laboratory, Harwell Campus – sequence: 10 givenname: Lothar orcidid: 0000-0002-0747-3076 surname: Wondraczek fullname: Wondraczek, Lothar organization: Otto Schott Institute of Materials Research, University of Jena – sequence: 11 givenname: Thomas D. orcidid: 0000-0003-3717-3119 surname: Bennett fullname: Bennett, Thomas D. email: tdb35@cam.ac.uk organization: Department of Materials Science and Metallurgy, University of Cambridge |
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| Snippet | Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas... Metal-organic frameworks constitute a family of glass formers that is distinct from those that are polymeric, metallic, or inorganic. Here the authors show... |
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| SubjectTerms | 639/301 639/301/119/1002 639/301/357/404 Aluminum phosphate Composite materials Domains Glass Humanities and Social Sciences Interfacial bonding Ion transport Materials selection Mechanical properties Metal-organic frameworks multidisciplinary Science Science (multidisciplinary) Temperature |
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| Title | Metal-organic framework and inorganic glass composites |
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