Nano- to macro-scale control of 3D printed materials via polymerization induced microphase separation
Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural fea...
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| Published in | Nature communications Vol. 13; no. 1; pp. 3577 - 10 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
22.06.2022
Nature Publishing Group Nature Portfolio |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications.
3D printing allows the macroscopic structure of objects to be easily controlled but controlling the nanostructure of 3D printed materials has rarely been reported. Here, the authors report an efficient and versatile process for fabricating 3D printed materials with controlled nano-scale structural features. |
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| AbstractList | Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications. Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications. 3D printing allows the macroscopic structure of objects to be easily controlled but controlling the nanostructure of 3D printed materials has rarely been reported. Here, the authors report an efficient and versatile process for fabricating 3D printed materials with controlled nano-scale structural features. Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications.Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications. Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we report an efficient and versatile process for fabricating 3D printed materials with controlled nanoscale structural features. This approach uses resins containing macromolecular chain transfer agents (macroCTAs) which microphase separate during the photoinduced 3D printing process to form nanostructured materials. By varying the chain length of the macroCTA, we demonstrate a high level of control over the microphase separation behavior, resulting in materials with controllable nanoscale sizes and morphologies. Importantly, the bulk mechanical properties of 3D printed objects are correlated with their morphologies; transitioning from discrete globular to interpenetrating domains results in a marked improvement in mechanical performance, which is ascribed to the increased interfacial interaction between soft and hard domains. Overall, the findings of this work enable the simplified production of materials with tightly controllable nanostructures for broad potential applications.3D printing allows the macroscopic structure of objects to be easily controlled but controlling the nanostructure of 3D printed materials has rarely been reported. Here, the authors report an efficient and versatile process for fabricating 3D printed materials with controlled nano-scale structural features. 3D printing allows the macroscopic structure of objects to be easily controlled but controlling the nanostructure of 3D printed materials has rarely been reported. Here, the authors report an efficient and versatile process for fabricating 3D printed materials with controlled nano-scale structural features. |
| ArticleNumber | 3577 |
| Author | Shi, Xiaobing Zhang, Jin Corrigan, Nathaniel Yao, Yin Boyer, Cyrille Xiu, Yuan Bobrin, Valentin A. |
| Author_xml | – sequence: 1 givenname: Valentin A. surname: Bobrin fullname: Bobrin, Valentin A. organization: Cluster for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales – sequence: 2 givenname: Yin surname: Yao fullname: Yao, Yin organization: Electron Microscope Unit, Mark Wainwright Analytical Centre, University of New South Wales – sequence: 3 givenname: Xiaobing surname: Shi fullname: Shi, Xiaobing organization: Cluster for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales – sequence: 4 givenname: Yuan surname: Xiu fullname: Xiu, Yuan organization: Cluster for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales – sequence: 5 givenname: Jin orcidid: 0000-0002-4257-8148 surname: Zhang fullname: Zhang, Jin email: jin.zhang6@unsw.edu.au organization: School of Mechanical and Manufacturing Engineering, University of New South Wales – sequence: 6 givenname: Nathaniel surname: Corrigan fullname: Corrigan, Nathaniel email: n.corrigan@unsw.edu.au organization: Cluster for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales, Australian Centre for Nanomedicine, School of Chemical Engineering, University of New South Wales – sequence: 7 givenname: Cyrille orcidid: 0000-0002-4564-4702 surname: Boyer fullname: Boyer, Cyrille email: cboyer@unsw.edu.au organization: Cluster for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales, Australian Centre for Nanomedicine, School of Chemical Engineering, University of New South Wales |
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| Snippet | Although 3D printing allows the macroscopic structure of objects to be easily controlled, controlling the nanostructure of 3D printed materials has rarely been... 3D printing allows the macroscopic structure of objects to be easily controlled but controlling the nanostructure of 3D printed materials has rarely been... |
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| SubjectTerms | 140/131 147/3 3-D printers 639/301/923/1028 639/638/298/923/1028 639/638/455/957 Chain transfer Controllability Domains Humanities and Social Sciences Macromolecules Mechanical properties Molecular chains Morphology multidisciplinary Nanostructure Nanostructured materials Printed materials Printing Resins Science Science (multidisciplinary) Separation Three dimensional printing |
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| Title | Nano- to macro-scale control of 3D printed materials via polymerization induced microphase separation |
| URI | https://link.springer.com/article/10.1038/s41467-022-31095-9 https://www.proquest.com/docview/2679466327 https://www.proquest.com/docview/2680235012 https://pubmed.ncbi.nlm.nih.gov/PMC9217958 https://doaj.org/article/18acc584471040ca8570dd9d25fcd021 |
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