Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2

• Published in: Nature communications Vol. 9; no. 1; pp. 1 - 8
• Main Authors: Wang, Yi-Rong, Huang, Qing, He, Chun-Ting, Chen, Yifa, Liu, Jiang, Shen, Feng-Cui, Lan, Ya-Qian
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 26.10.2018; Nature Publishing Group; Nature Portfolio
• Subjects: 639/301/299/921; 639/638/161/886; 639/638/77/887; 639/925/357/404; Carbon dioxide; Catalysis; Catalysts; Chemical reduction; Density functional theory; Electrocatalysts; Electrons; Humanities and Social Sciences; Metal-organic frameworks; Migration; multidisciplinary; Science; Science (multidisciplinary)

The design of highly stable, selective and efficient electrocatalysts for CO 2 reduction reaction is desirable while largely unmet. In this work, a series of precisely designed polyoxometalate-metalloporphyrin organic frameworks are developed. Noted that the integration of {ε-PMo 8 V Mo 4 VI O 40 Zn...