Self-templated synthesis of uniform hollow spheres based on highly conjugated three-dimensional covalent organic frameworks

Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and u...

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Published inNature communications Vol. 11; no. 1; pp. 5561 - 8
Main Authors Liu, Yuan-Yuan, Li, Xiang-Chun, Wang, Shi, Cheng, Tao, Yang, Huiyan, Liu, Chen, Gong, Yanting, Lai, Wen-Yong, Huang, Wei
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 03.11.2020
Nature Publishing Group
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ISSN2041-1723
2041-1723
DOI10.1038/s41467-020-18844-4

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Abstract Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500–700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number ( t + ) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g −1 at 0.5 A g −1 , which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials. Covalent organic frameworks (COFs) are promising porous crystalline materials but controllable synthesis of COFs with uniform morphology remains challenging. Here, the authors report a self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional COFs.
AbstractList Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500–700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number (t+) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g−1 at 0.5 A g−1, which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials.Covalent organic frameworks (COFs) are promising porous crystalline materials but controllable synthesis of COFs with uniform morphology remains challenging. Here, the authors report a self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional COFs.
Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500–700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number ( t + ) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g −1 at 0.5 A g −1 , which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials. Covalent organic frameworks (COFs) are promising porous crystalline materials but controllable synthesis of COFs with uniform morphology remains challenging. Here, the authors report a self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional COFs.
Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500-700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number (t+) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g-1 at 0.5 A g-1, which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials.Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500-700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number (t+) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g-1 at 0.5 A g-1, which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials.
Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500–700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number ( t + ) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g −1 at 0.5 A g −1 , which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials.
Covalent organic frameworks (COFs) are promising porous crystalline materials but controllable synthesis of COFs with uniform morphology remains challenging. Here, the authors report a self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional COFs.
ArticleNumber 5561
Author Lai, Wen-Yong
Li, Xiang-Chun
Gong, Yanting
Yang, Huiyan
Liu, Chen
Huang, Wei
Liu, Yuan-Yuan
Wang, Shi
Cheng, Tao
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Snippet Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis...
Covalent organic frameworks (COFs) are promising porous crystalline materials but controllable synthesis of COFs with uniform morphology remains challenging....
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StartPage 5561
SubjectTerms 147/135
147/143
639/301/299/1013
639/638/298/921
Capacitance
Covalence
Crystal structure
Crystallinity
Diameters
Electrode materials
Electrolytes
Humanities and Social Sciences
Lithium
Lithium ions
Morphology
multidisciplinary
Ostwald ripening
Polymers
Porous materials
Science
Science (multidisciplinary)
Spheres
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Title Self-templated synthesis of uniform hollow spheres based on highly conjugated three-dimensional covalent organic frameworks
URI https://link.springer.com/article/10.1038/s41467-020-18844-4
https://www.proquest.com/docview/2471530894
https://www.proquest.com/docview/2457690791
https://pubmed.ncbi.nlm.nih.gov/PMC7642269
https://doaj.org/article/fdbfb87003384a50ba4d43b732aab831
Volume 11
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