Electrostatically cooperative host-in-host of metal cluster ⊂ ionic organic cages in nanopores for enhanced catalysis

• Published in: Nature communications Vol. 13; no. 1; pp. 1471 - 8
• Main Authors: Tan, Liangxiao, Zhou, Jun-Hao, Sun, Jian-Ke, Yuan, Jiayin
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 18.03.2022; Nature Publishing Group; Nature Portfolio
• Subjects: 119/118; 140/131; 147/137; 639/638/263; 639/638/541; 639/638/77; Cages; Cascade chemical reactions; Catalysis; Catalysts; Catalytic activity; Cations; Composite materials; Encapsulation; Humanities and Social Sciences; Ion pairs; Ionic liquids; Ions; Metal clusters; multidisciplinary; Porous materials; Science; Science (multidisciplinary); Substrates

The construction of hierarchically nanoporous composite for high-performance catalytic application is still challenging. In this work, a series of host-in-host ionic porous materials are crafted by encapsulating ionic organic cages into a hyper-crosslinked, oppositely charged porous poly(ionic liqui...