Green and facile synthesis of few-layer graphene via liquid exfoliation process for Lithium-ion batteries

A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochem...

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Published inScientific reports Vol. 8; no. 1; pp. 9766 - 8
Main Authors Lin, Pin-Chun, Wu, Jhao-Yi, Liu, Wei-Ren
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 27.06.2018
Nature Publishing Group
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Abstract A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochemical performance as anode materials for Li-ion batteries. Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) as well as BET isotherms and XPS are carried out in this study. The results of atomic force microscopy (AFM) further revealed that up to 85% of the prepared FLG were less than 10 layers. This exfoliation process happened mainly due to the cavitation-induced intensive tensile stress acting on the layered materials. Electrochemical measurements demonstrate that graphite anode delivered only 240 mAh/g while FLG anode achieved more than 322 mAh/g at 5C rate test. These results indicate that JC method not only paves the way for cheaper and safer production of graphene but also holds great potential applications in energy-related technology.
AbstractList A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochemical performance as anode materials for Li-ion batteries. Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) as well as BET isotherms and XPS are carried out in this study. The results of atomic force microscopy (AFM) further revealed that up to 85% of the prepared FLG were less than 10 layers. This exfoliation process happened mainly due to the cavitation-induced intensive tensile stress acting on the layered materials. Electrochemical measurements demonstrate that graphite anode delivered only 240 mAh/g while FLG anode achieved more than 322 mAh/g at 5C rate test. These results indicate that JC method not only paves the way for cheaper and safer production of graphene but also holds great potential applications in energy-related technology.A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochemical performance as anode materials for Li-ion batteries. Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) as well as BET isotherms and XPS are carried out in this study. The results of atomic force microscopy (AFM) further revealed that up to 85% of the prepared FLG were less than 10 layers. This exfoliation process happened mainly due to the cavitation-induced intensive tensile stress acting on the layered materials. Electrochemical measurements demonstrate that graphite anode delivered only 240 mAh/g while FLG anode achieved more than 322 mAh/g at 5C rate test. These results indicate that JC method not only paves the way for cheaper and safer production of graphene but also holds great potential applications in energy-related technology.
A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochemical performance as anode materials for Li-ion batteries. Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) as well as BET isotherms and XPS are carried out in this study. The results of atomic force microscopy (AFM) further revealed that up to 85% of the prepared FLG were less than 10 layers. This exfoliation process happened mainly due to the cavitation-induced intensive tensile stress acting on the layered materials. Electrochemical measurements demonstrate that graphite anode delivered only 240 mAh/g while FLG anode achieved more than 322 mAh/g at 5C rate test. These results indicate that JC method not only paves the way for cheaper and safer production of graphene but also holds great potential applications in energy-related technology.
ArticleNumber 9766
Author Liu, Wei-Ren
Wu, Jhao-Yi
Lin, Pin-Chun
Author_xml – sequence: 1
  givenname: Pin-Chun
  surname: Lin
  fullname: Lin, Pin-Chun
  organization: Department of Chemical Engineering, Chung Yuan Christian University
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  givenname: Jhao-Yi
  surname: Wu
  fullname: Wu, Jhao-Yi
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  givenname: Wei-Ren
  surname: Liu
  fullname: Liu, Wei-Ren
  email: wrliu1203@gmail.com
  organization: Department of Chemical Engineering, Chung Yuan Christian University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/29950565$$D View this record in MEDLINE/PubMed
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Snippet A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without...
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proquest
pubmed
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StartPage 9766
SubjectTerms 140/133
140/146
639/4077/4079/891
639/638/898
Atomic force microscopy
Cavitation
Electrochemistry
Exfoliation
Graphite
Humanities and Social Sciences
Lithium
multidisciplinary
Oxidants
Oxidizing agents
Raman spectroscopy
Scanning electron microscopy
Science
Science (multidisciplinary)
Tensile stress
Transmission electron microscopy
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Title Green and facile synthesis of few-layer graphene via liquid exfoliation process for Lithium-ion batteries
URI https://link.springer.com/article/10.1038/s41598-018-27922-z
https://www.ncbi.nlm.nih.gov/pubmed/29950565
https://www.proquest.com/docview/2060855857
https://www.proquest.com/docview/2061405642
https://pubmed.ncbi.nlm.nih.gov/PMC6021450
Volume 8
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