Efficient industrial-current-density acetylene to polymer-grade ethylene via hydrogen-localization transfer over fluorine-modified copper
Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that...
Saved in:
| Published in | Nature communications Vol. 14; no. 1; pp. 8384 - 9 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
16.12.2023
Nature Publishing Group Nature Portfolio |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm
−2
with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cu
δ+
(near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu
0
(away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw.
Efficient electroreduction of acetylene to ethylene is crucial for industrial applications. Here, the authors reported fluorine modified copper for direct conversion of acetylene to polymer-grade ethylene in one single-pass with industrial-current-density. |
|---|---|
| AbstractList | Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm
−2
with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cu
δ+
(near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu
0
(away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw.
Efficient electroreduction of acetylene to ethylene is crucial for industrial applications. Here, the authors reported fluorine modified copper for direct conversion of acetylene to polymer-grade ethylene in one single-pass with industrial-current-density. Abstract Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm −2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cu δ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu 0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw. Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm −2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cu δ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu 0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw. Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm-2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cuδ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw.Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm-2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cuδ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw. Abstract Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm−2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cuδ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw. Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm−2 with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cuδ+ (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu0 (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw.Efficient electroreduction of acetylene to ethylene is crucial for industrial applications. Here, the authors reported fluorine modified copper for direct conversion of acetylene to polymer-grade ethylene in one single-pass with industrial-current-density. Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density and single-pass yield greatly impedes the production efficiency and industrial application. Herein, we develop a F-modified Cu catalyst that shows an industrial partial current density up to 0.76 A cm with an ethylene Faradic efficiency surpass 90%, and the maximum single-pass yield reaches a notable 78.5%. Furthermore, the Cu-F showcase the capability to directly convert acetylene into polymer-grade ethylene in a tandem flow cell, almost no acetylene residual in the production. Combined characterizations and calculations reveal that the Cu (near fluorine) enhances the water dissociation, and the generated active hydrogen are immediately transferred to Cu (away from fluorine) and react with the locally adsorbed acetylene. Therefore, the hydrogen evolution reaction is surpassed and the overall acetylene semi-hydrogenation performance is boosted. Our findings provide new opportunity towards rational design of catalysts for large-scale electrosynthesis of ethylene and other important industrial raw. |
| ArticleNumber | 8384 |
| Author | Bai, Lei Wang, Yi Leng, Kunyue Zheng, Lirong Bai, Jinbo Wu, Yuen Han, Zheng Qu, Yunteng |
| Author_xml | – sequence: 1 givenname: Lei surname: Bai fullname: Bai, Lei organization: International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics and Photon-Technology, Northwest University – sequence: 2 givenname: Yi orcidid: 0000-0003-4269-1455 surname: Wang fullname: Wang, Yi organization: International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics and Photon-Technology, Northwest University – sequence: 3 givenname: Zheng surname: Han fullname: Han, Zheng organization: International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics and Photon-Technology, Northwest University – sequence: 4 givenname: Jinbo surname: Bai fullname: Bai, Jinbo organization: Université Paris-Saclay, CentraleSupélec, ENS Paris-Saclay, CNRS, LMPS-Laboratoire de Mécanique Paris-Saclay, 8-10 rue Joliot-Curie – sequence: 5 givenname: Kunyue orcidid: 0000-0002-8182-0339 surname: Leng fullname: Leng, Kunyue email: lengky@nwu.edu.cn organization: International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics and Photon-Technology, Northwest University – sequence: 6 givenname: Lirong surname: Zheng fullname: Zheng, Lirong email: zhenglr@ihep.ac.cn organization: Institute of High Energy Physics – sequence: 7 givenname: Yunteng orcidid: 0000-0002-0964-3358 surname: Qu fullname: Qu, Yunteng email: yuntengqu@nwu.edu.cn organization: International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics and Photon-Technology, Northwest University – sequence: 8 givenname: Yuen orcidid: 0000-0001-9524-2843 surname: Wu fullname: Wu, Yuen organization: School of Chemistry and Materials Science, University of Science and Technology of China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38104169$$D View this record in MEDLINE/PubMed https://hal.science/hal-04378668$$DView record in HAL |
| BookMark | eNp9Ul1vFCEUnZgaW2v_gA9mEl_0AeVzhn0yTVNtk0180WfCwGWXZhZWYDZZ_4H_WrbTatuHEgLk3nPO5cJ53RyFGKBp3hL8iWAmP2dOeNcjTBninPQEiRfNCcWcINJTdvTgfNyc5XyD62ALIjl_1RwzSWq2W5w0fy6d88ZDKK0PdsoleT0iM6VUQ8hCyL7sW22g7EcI0JbYbuO430BCq6QttFDWc2bndbve2xRXENAYjR79b118DG1JOmQHqY27urhxiskHQJtovfNgWxO3W0hvmpdOjxnO7vbT5ufXyx8XV2j5_dv1xfkSGdGLggilAA5MbwQXRhtureGDrHPQnQVGBwPAawKAiA5jyrlxVjvDnBEdd-y0uZ51bdQ3apv8Rqe9itqr20BMK6VT8WYEJbpK7cHK3gxcCCwHd5Cgw4IwLoehan2ZtbbTsAFr6pslPT4SfZwJfq1WcacI7qngVFSFj7PC-gnv6nypDjHMWS-7Tu5IxX64q5birwlyURufDYyjDhCnrOgCM0a7-vEV-v4J9CZOKdR3PaCokFiSvqLePbz-v_r39qgAOQNMijkncMr4cvuptRs_1jbUwYxqNqOqZlS3ZlSHxugT6r36syQ2k3IFhxWk_9d-hvUXUy72Bw |
| CitedBy_id | crossref_primary_10_1002_anie_202502757 crossref_primary_10_1002_anie_202418459 crossref_primary_10_1021_jacs_4c17260 crossref_primary_10_1002_ange_202418459 crossref_primary_10_1007_s12209_024_00399_w crossref_primary_10_1021_jacs_4c03893 crossref_primary_10_1002_adma_202408681 crossref_primary_10_1002_ange_202502757 crossref_primary_10_1021_acsmaterialslett_4c02230 crossref_primary_10_1016_j_cclet_2025_110836 crossref_primary_10_1002_ange_202423381 crossref_primary_10_1038_s41467_024_50499_3 crossref_primary_10_1002_anie_202423381 crossref_primary_10_1016_j_apsusc_2024_161075 crossref_primary_10_1016_j_apsusc_2025_162288 crossref_primary_10_1002_ange_202423091 crossref_primary_10_1002_anie_202423091 crossref_primary_10_1002_aic_18663 crossref_primary_10_1021_acscatal_4c07524 crossref_primary_10_1002_anie_202413033 crossref_primary_10_1002_ange_202413033 crossref_primary_10_1039_D4QI03125C |
| Cites_doi | 10.1038/s41467-021-23699-4 10.1002/anie.202109538 10.1021/acs.chemrev.8b00705 10.1002/adma.201803111 10.1039/D1TA08002D 10.1038/s41929-021-00641-x 10.1038/s41467-021-26853-0 10.1021/acscatal.9b02922 10.1021/acscatal.2c00430 10.1021/acs.est.9b04352 10.1002/smll.202001384 10.1021/acscatal.1c02316 10.1038/s41467-021-27372-8 10.1038/s41557-019-0381-z 10.1021/cr400276u 10.1006/jcat.1994.1036 10.1038/s41467-023-37821-1 10.1126/science.abi4407 10.1016/j.cej.2021.134129 10.1002/anie.202206233 10.1038/s41467-021-23065-4 10.1149/1.2407974 10.1016/j.elecom.2013.05.036 10.1002/adma.202005192 10.1126/science.285.5428.712 10.1002/aenm.202101424 10.1039/D2CP01316A 10.1038/s41929-020-0450-0 10.1002/anie.202009757 10.1038/s41929-021-00640-y 10.1038/s41467-022-32933-6 10.1126/science.1156660 10.1016/j.carbon.2019.10.058 10.1021/jacs.3c02399 10.1002/ange.202307848 10.1038/s41893-023-01084-x 10.1002/anie.202301340 |
| ContentType | Journal Article |
| Copyright | The Author(s) 2023 2023. The Author(s). The Author(s) 2023. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: The Author(s) 2023 – notice: 2023. The Author(s). – notice: The Author(s) 2023. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | C6C AAYXX CITATION NPM 3V. 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7X7 7XB 88E 8AO 8FD 8FE 8FG 8FH 8FI 8FJ 8FK ABUWG AEUYN AFKRA ARAPS AZQEC BBNVY BENPR BGLVJ BHPHI C1K CCPQU DWQXO FR3 FYUFA GHDGH GNUQQ H94 HCIFZ K9. LK8 M0S M1P M7P P5Z P62 P64 PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQGLB PQQKQ PQUKI PRINS RC3 SOI 7X8 1XC 5PM DOA |
| DOI | 10.1038/s41467-023-44171-5 |
| DatabaseName | Springer Nature OA Free Journals CrossRef PubMed ProQuest Central (Corporate) Bacteriology Abstracts (Microbiology B) Calcium & Calcified Tissue Abstracts Chemoreception Abstracts Ecology Abstracts Entomology Abstracts (Full archive) Environment Abstracts Immunology Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) Nucleic Acids Abstracts Oncogenes and Growth Factors Abstracts Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) ProQuest Pharma Collection Technology Research Database ProQuest SciTech Collection ProQuest Technology Collection ProQuest Natural Science Collection ProQuest Hospital Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) ProQuest One Sustainability (subscription) ProQuest Central UK/Ireland Advanced Technologies & Aerospace Collection ProQuest Central Essentials Biological Science Collection ProQuest Central Technology Collection Natural Science Collection Environmental Sciences and Pollution Management ProQuest One Community College ProQuest Central Engineering Research Database Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Central Student AIDS and Cancer Research Abstracts SciTech Premium Collection ProQuest Health & Medical Complete (Alumni) Biological Sciences Health & Medical Collection (Alumni) Medical Database Biological Science Database ProQuest Advanced Technologies & Aerospace Database ProQuest Advanced Technologies & Aerospace Collection Biotechnology and BioEngineering Abstracts ProQuest Central Premium ProQuest One Academic Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) ProQuest One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Applied & Life Sciences ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central China Genetics Abstracts Environment Abstracts MEDLINE - Academic Hyper Article en Ligne (HAL) PubMed Central (Full Participant titles) Directory of Open Access Journals (DOAJ) |
| DatabaseTitle | CrossRef PubMed Publicly Available Content Database ProQuest Central Student Oncogenes and Growth Factors Abstracts ProQuest Advanced Technologies & Aerospace Collection ProQuest Central Essentials Nucleic Acids Abstracts SciTech Premium Collection ProQuest Central China Environmental Sciences and Pollution Management ProQuest One Applied & Life Sciences ProQuest One Sustainability Health Research Premium Collection Natural Science Collection Health & Medical Research Collection Biological Science Collection Chemoreception Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) ProQuest Central (New) ProQuest Medical Library (Alumni) Advanced Technologies & Aerospace Collection ProQuest Biological Science Collection ProQuest One Academic Eastern Edition ProQuest Hospital Collection ProQuest Technology Collection Health Research Premium Collection (Alumni) Biological Science Database Ecology Abstracts ProQuest Hospital Collection (Alumni) Biotechnology and BioEngineering Abstracts Entomology Abstracts ProQuest Health & Medical Complete ProQuest One Academic UKI Edition Engineering Research Database ProQuest One Academic Calcium & Calcified Tissue Abstracts ProQuest One Academic (New) Technology Collection Technology Research Database ProQuest One Academic Middle East (New) ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest One Health & Nursing ProQuest Natural Science Collection ProQuest Pharma Collection ProQuest Central ProQuest Health & Medical Research Collection Genetics Abstracts Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Bacteriology Abstracts (Microbiology B) AIDS and Cancer Research Abstracts ProQuest SciTech Collection Advanced Technologies & Aerospace Database ProQuest Medical Library Immunology Abstracts Environment Abstracts ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | CrossRef MEDLINE - Academic Publicly Available Content Database PubMed |
| Database_xml | – sequence: 1 dbid: C6C name: Springer Nature OA Free Journals url: http://www.springeropen.com/ sourceTypes: Publisher – sequence: 2 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 3 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 4 dbid: 8FG name: ProQuest Technology Collection url: https://search.proquest.com/technologycollection1 sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Biology |
| EISSN | 2041-1723 |
| EndPage | 9 |
| ExternalDocumentID | oai_doaj_org_article_56cfd7ed87cb45508bf564f2b91348bb PMC10725425 oai_HAL_hal_04378668v1 38104169 10_1038_s41467_023_44171_5 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: Natural Science Basic Research Program of Shaanxi 2022JM-018 – fundername: National Natural Science Foundation of China (National Science Foundation of China) grantid: 22275147; 21902150; 52301289 funderid: https://doi.org/10.13039/501100001809 – fundername: Natural Science Basic Research Program of Shaanxi 2022JQ-082 – fundername: National Natural Science Foundation of China (National Science Foundation of China) grantid: 21902150 – fundername: National Natural Science Foundation of China (National Science Foundation of China) grantid: 52301289 – fundername: National Natural Science Foundation of China (National Science Foundation of China) grantid: 22275147 |
| GroupedDBID | --- 0R~ 39C 3V. 53G 5VS 70F 7X7 88E 8AO 8FE 8FG 8FH 8FI 8FJ AAHBH AAJSJ ABUWG ACGFO ACGFS ACIWK ACMJI ACPRK ACSMW ADBBV ADFRT ADMLS ADRAZ AENEX AEUYN AFKRA AFRAH AHMBA AJTQC ALIPV ALMA_UNASSIGNED_HOLDINGS AMTXH AOIJS ARAPS ASPBG AVWKF AZFZN BBNVY BCNDV BENPR BGLVJ BHPHI BPHCQ BVXVI C6C CCPQU DIK EBLON EBS EE. EMOBN F5P FEDTE FYUFA GROUPED_DOAJ HCIFZ HMCUK HVGLF HYE HZ~ KQ8 LGEZI LK8 LOTEE M1P M48 M7P M~E NADUK NAO NXXTH O9- OK1 P2P P62 PIMPY PQQKQ PROAC PSQYO RNS RNT RNTTT RPM SNYQT SV3 TSG UKHRP AASML AAYXX CITATION PHGZM PHGZT NPM PJZUB PPXIY PQGLB 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7XB 8FD 8FK AARCD AZQEC C1K DWQXO FR3 GNUQQ H94 K9. P64 PKEHL PQEST PQUKI PRINS RC3 SOI 7X8 1XC 5PM PUEGO |
| ID | FETCH-LOGICAL-c575t-122eefec7c545cac4ddc4b84b8ba6de32bcee4cacee15600244cfdafc3fc564f3 |
| IEDL.DBID | M48 |
| ISSN | 2041-1723 |
| IngestDate | Wed Aug 27 01:29:20 EDT 2025 Thu Aug 21 18:37:54 EDT 2025 Fri Aug 15 06:21:22 EDT 2025 Fri Jul 11 10:48:06 EDT 2025 Wed Aug 13 08:10:30 EDT 2025 Mon Jul 21 06:06:37 EDT 2025 Tue Jul 01 02:10:50 EDT 2025 Thu Apr 24 23:08:10 EDT 2025 Fri Feb 21 02:39:53 EST 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Language | English |
| License | 2023. The Author(s). Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c575t-122eefec7c545cac4ddc4b84b8ba6de32bcee4cacee15600244cfdafc3fc564f3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0000-0003-4269-1455 0000-0002-8182-0339 0000-0001-9524-2843 0000-0002-0964-3358 |
| OpenAccessLink | http://journals.scholarsportal.info/openUrl.xqy?doi=10.1038/s41467-023-44171-5 |
| PMID | 38104169 |
| PQID | 2902580817 |
| PQPubID | 546298 |
| PageCount | 9 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_56cfd7ed87cb45508bf564f2b91348bb pubmedcentral_primary_oai_pubmedcentral_nih_gov_10725425 hal_primary_oai_HAL_hal_04378668v1 proquest_miscellaneous_2903326204 proquest_journals_2902580817 pubmed_primary_38104169 crossref_citationtrail_10_1038_s41467_023_44171_5 crossref_primary_10_1038_s41467_023_44171_5 springer_journals_10_1038_s41467_023_44171_5 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2023-12-16 |
| PublicationDateYYYYMMDD | 2023-12-16 |
| PublicationDate_xml | – month: 12 year: 2023 text: 2023-12-16 day: 16 |
| PublicationDecade | 2020 |
| PublicationPlace | London |
| PublicationPlace_xml | – name: London – name: England |
| PublicationTitle | Nature communications |
| PublicationTitleAbbrev | Nat Commun |
| PublicationTitleAlternate | Nat Commun |
| PublicationYear | 2023 |
| Publisher | Nature Publishing Group UK Nature Publishing Group Nature Portfolio |
| Publisher_xml | – name: Nature Publishing Group UK – name: Nature Publishing Group – name: Nature Portfolio |
| References | Fang (CR26) 2023; 145 Xue (CR22) 2023; 14 Zhou (CR28) 2019; 11 Fan (CR37) 2021; 11 Liu (CR13) 2022; 431 Wang (CR24) 2021; 12 Barhacs, Janssens, Hoeltzl (CR27) 2022; 24 CR14 CR35 Ma (CR30) 2020; 16 Huang, Durante, Isse, Gennaro (CR17) 2013; 34 Ma (CR29) 2020; 3 Bodke, Olschki, Schmidt, Ranzi (CR2) 1999; 285 Ling (CR12) 2021; 11 Studt (CR6) 2008; 320 Zhang (CR16) 2021; 12 Wang (CR20) 2021; 12 Jiao (CR7) 2021; 33 Wu, Liu, Wang, Lu, Zhang (CR32) 2020; 59 Xu (CR25) 2021; 12 Nitopi (CR23) 2019; 119 Guo (CR1) 2022; 375 Liu (CR5) 2021; 60 Chen (CR33) 2022; 61 Schobert (CR4) 2014; 114 CR8 Lv (CR36) 2018; 30 Zhu (CR21) 2022; 12 Bu (CR18) 2021; 4 Guo (CR34) 2022; 13 Gao (CR3) 2019; 9 Shi (CR19) 2021; 4 Abakumov (CR9) 2020; 157 Ma (CR11) 2022; 10 Davitt, Albright (CR15) 1971; 118 Otsuka, Yagi (CR10) 1994; 145 Liu (CR31) 2019; 53 W Xue (44171_CR22) 2023; 14 HJ Davitt (44171_CR15) 1971; 118 Q Fan (44171_CR37) 2021; 11 L Zhang (44171_CR16) 2021; 12 S Wang (44171_CR20) 2021; 12 AS Bodke (44171_CR2) 1999; 285 X Jiao (44171_CR7) 2021; 33 W Ma (44171_CR11) 2022; 10 S Nitopi (44171_CR23) 2019; 119 S Ma (44171_CR30) 2020; 16 R Shi (44171_CR19) 2021; 4 K Zhu (44171_CR21) 2022; 12 B Huang (44171_CR17) 2013; 34 W Guo (44171_CR1) 2022; 375 44171_CR8 B Barhacs (44171_CR27) 2022; 24 44171_CR35 Y Liu (44171_CR5) 2021; 60 44171_CR14 Z Liu (44171_CR13) 2022; 431 Y Xu (44171_CR25) 2021; 12 F Studt (44171_CR6) 2008; 320 W Ma (44171_CR29) 2020; 3 AA Abakumov (44171_CR9) 2020; 157 Y Ling (44171_CR12) 2021; 11 M Fang (44171_CR26) 2023; 145 Y Wu (44171_CR32) 2020; 59 J-J Lv (44171_CR36) 2018; 30 X Wang (44171_CR24) 2021; 12 H Liu (44171_CR31) 2019; 53 S Guo (44171_CR34) 2022; 13 K Otsuka (44171_CR10) 1994; 145 Y Zhou (44171_CR28) 2019; 11 S Chen (44171_CR33) 2022; 61 Y Gao (44171_CR3) 2019; 9 J Bu (44171_CR18) 2021; 4 H Schobert (44171_CR4) 2014; 114 |
| References_xml | – volume: 12 year: 2021 ident: CR24 article-title: Gold-in-copper at low CO coverage enables efficient electromethanation of CO publication-title: Nat. Commun. doi: 10.1038/s41467-021-23699-4 – volume: 60 start-page: 22522 year: 2021 end-page: 22528 ident: CR5 article-title: Polyoxometalate-based metal-organic framework as molecular sieve for highly selective semi-hydrogenation of acetylene on isolated single Pd atom sites publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202109538 – volume: 119 start-page: 7610 year: 2019 end-page: 7672 ident: CR23 article-title: Progress and perspectives of electrochemical CO reduction on copper in aqueous electrolyte publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.8b00705 – volume: 30 start-page: 1803111 year: 2018 ident: CR36 article-title: A highly porous copper electrocatalyst for carbon dioxide reduction publication-title: Adv. Mater. doi: 10.1002/adma.201803111 – volume: 10 start-page: 6122 year: 2022 end-page: 6128 ident: CR11 article-title: π-adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed n-doped carbon publication-title: J. Mater. Chem. A doi: 10.1039/D1TA08002D – ident: CR14 – volume: 4 start-page: 557 year: 2021 end-page: 564 ident: CR18 article-title: Selective electrocatalytic semihydrogenation of acetylene impurities for the production of polymer-grade ethylene publication-title: Nat. Catal. doi: 10.1038/s41929-021-00641-x – volume: 12 year: 2021 ident: CR16 article-title: Efficient electrocatalytic acetylene semihydrogenation by electron-rich metal sites in n-heterocyclic carbene metal complexes publication-title: Nat. Commun. doi: 10.1038/s41467-021-26853-0 – volume: 9 start-page: 8592 year: 2019 end-page: 8621 ident: CR3 article-title: Recent advances in intensified ethylene production-a review publication-title: ACS Catal. doi: 10.1021/acscatal.9b02922 – volume: 12 start-page: 4840 year: 2022 end-page: 4847 ident: CR21 article-title: Unraveling the role of interfacial water structure in electrochemical semihydrogenation of alkynes publication-title: ACS Catal. doi: 10.1021/acscatal.2c00430 – volume: 53 start-page: 11932 year: 2019 end-page: 11940 ident: CR31 article-title: Deep dehalogenation of florfenicol using crystalline CoP nanosheet arrays on a Ti plate via direct cathodic reduction and atomic H publication-title: Environ. Sci. Technol. doi: 10.1021/acs.est.9b04352 – volume: 16 start-page: 2001384 year: 2020 ident: CR30 article-title: Ionic exchange of metal-organic frameworks for constructing unsaturated copper single-atom catalysts for boosting oxygen reduction reaction publication-title: Small doi: 10.1002/smll.202001384 – volume: 11 start-page: 9471 year: 2021 end-page: 9478 ident: CR12 article-title: Selenium vacancy promotes transfer semihydrogenation of alkynes from water electrolysis publication-title: ACS Catal. doi: 10.1021/acscatal.1c02316 – volume: 12 year: 2021 ident: CR20 article-title: Highly efficient ethylene production via electrocatalytic hydrogenation of acetylene under mild conditions publication-title: Nat. Commun. doi: 10.1038/s41467-021-27372-8 – ident: CR35 – ident: CR8 – volume: 11 start-page: 1167 year: 2019 end-page: 1167 ident: CR28 article-title: Dopant-induced electron localization drives CO reduction to C hydrocarbons publication-title: Nat. Chem. doi: 10.1038/s41557-019-0381-z – volume: 114 start-page: 1743 year: 2014 end-page: 1760 ident: CR4 article-title: Production of acetylene and acetylene-based chemicals from coal publication-title: Chem. Rev. doi: 10.1021/cr400276u – volume: 145 start-page: 289 year: 1994 end-page: 294 ident: CR10 article-title: An electrochemical membrane reactor for selective hydrogenation of acetylene in abundant ethylene publication-title: J. Catal. doi: 10.1006/jcat.1994.1036 – volume: 14 year: 2023 ident: CR22 article-title: Electrosynthesis of polymer-grade ethylene via acetylene semihydrogenation over undercoordinated cu nanodots publication-title: Nat. Commun. doi: 10.1038/s41467-023-37821-1 – volume: 375 start-page: 1188 year: 2022 end-page: 1191 ident: CR1 article-title: Visualization of on-surface ethylene polymerization through ethylene insertion publication-title: Science doi: 10.1126/science.abi4407 – volume: 431 start-page: 134129 year: 2022 ident: CR13 article-title: Metal phthalocyanines as efficient electrocatalysts for acetylene semihydrogenation publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.134129 – volume: 61 start-page: e202206233 year: 2022 ident: CR33 article-title: Unveiling the proton-feeding effect in sulfur-doped Fe-N-C single-atom catalyst for enhanced CO electroreduction publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202206233 – volume: 12 year: 2021 ident: CR25 article-title: Low coordination number copper catalysts for electrochemical CO methanation in a membrane electrode assembly publication-title: Nat. Commun. doi: 10.1038/s41467-021-23065-4 – volume: 118 start-page: 236 year: 1971 ident: CR15 article-title: Electrochemical hydrogenation of ethylene, acetylene, and ethylene-acetylene mixtures publication-title: J. Electrochem. Soc. doi: 10.1149/1.2407974 – volume: 34 start-page: 90 year: 2013 end-page: 93 ident: CR17 article-title: Highly selective electrochemical hydrogenation of acetylene to ethylene at Ag and Cu cathodes publication-title: Electrochem. Commun. doi: 10.1016/j.elecom.2013.05.036 – volume: 33 start-page: 2005192 year: 2021 ident: CR7 article-title: Conversion of waste plastics into value-added carbonaceous fuels under mild conditions publication-title: Adv. Mater. doi: 10.1002/adma.202005192 – volume: 285 start-page: 712 year: 1999 end-page: 715 ident: CR2 article-title: High selectivities to ethylene by partial oxidation of ethane publication-title: Science doi: 10.1126/science.285.5428.712 – volume: 11 start-page: 2101424 year: 2021 ident: CR37 article-title: Manipulating cu nanoparticle surface oxidation states tunes catalytic selectivity toward CH or C products in CO electroreduction publication-title: Adv. Energy Mater. doi: 10.1002/aenm.202101424 – volume: 24 start-page: 21417 year: 2022 end-page: 21426 ident: CR27 article-title: C product formation in the CO electroreduction on boron-doped graphene anchored copper clusters publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/D2CP01316A – volume: 3 start-page: 478 year: 2020 end-page: 487 ident: CR29 article-title: Electrocatalytic reduction of CO to ethylene and ethanol through hydrogen-assisted C-C coupling over fluorine-modified copper publication-title: Nat. Catal. doi: 10.1038/s41929-020-0450-0 – volume: 59 start-page: 21170 year: 2020 end-page: 21175 ident: CR32 article-title: Selective transfer semihydrogenation of alkynes with H O (D O) as the H (D) source over a Pd-P cathode publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202009757 – volume: 4 start-page: 565 year: 2021 end-page: 574 ident: CR19 article-title: Room-temperature electrochemical acetylene reduction to ethylene with high conversion and selectivity publication-title: Nat. Catal. doi: 10.1038/s41929-021-00640-y – volume: 13 year: 2022 ident: CR34 article-title: Electrocatalytic hydrogenation of quinolines with water over a fluorine-modified cobalt catalyst publication-title: Nat. Commun. doi: 10.1038/s41467-022-32933-6 – volume: 320 start-page: 1320 year: 2008 end-page: 1322 ident: CR6 article-title: Identification of non-precious metal alloy catalysts for selective hydrogenation of acetylene publication-title: Science doi: 10.1126/science.1156660 – volume: 157 start-page: 277 year: 2020 end-page: 285 ident: CR9 article-title: Catalytic properties of reduced graphene oxide in acetylene hydrogenation publication-title: Carbon doi: 10.1016/j.carbon.2019.10.058 – volume: 145 start-page: 11323 year: 2023 end-page: 11332 ident: CR26 article-title: Hydrophobic, ultrastable Cu for robust CO electroreduction to C products at ampere-current levels publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.3c02399 – volume: 3 start-page: 478 year: 2020 ident: 44171_CR29 publication-title: Nat. Catal. doi: 10.1038/s41929-020-0450-0 – volume: 320 start-page: 1320 year: 2008 ident: 44171_CR6 publication-title: Science doi: 10.1126/science.1156660 – volume: 34 start-page: 90 year: 2013 ident: 44171_CR17 publication-title: Electrochem. Commun. doi: 10.1016/j.elecom.2013.05.036 – volume: 60 start-page: 22522 year: 2021 ident: 44171_CR5 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202109538 – volume: 12 year: 2021 ident: 44171_CR25 publication-title: Nat. Commun. doi: 10.1038/s41467-021-23065-4 – ident: 44171_CR35 doi: 10.1002/ange.202307848 – ident: 44171_CR14 doi: 10.1038/s41893-023-01084-x – volume: 11 start-page: 2101424 year: 2021 ident: 44171_CR37 publication-title: Adv. Energy Mater. doi: 10.1002/aenm.202101424 – volume: 114 start-page: 1743 year: 2014 ident: 44171_CR4 publication-title: Chem. Rev. doi: 10.1021/cr400276u – volume: 59 start-page: 21170 year: 2020 ident: 44171_CR32 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202009757 – volume: 4 start-page: 565 year: 2021 ident: 44171_CR19 publication-title: Nat. Catal. doi: 10.1038/s41929-021-00640-y – volume: 9 start-page: 8592 year: 2019 ident: 44171_CR3 publication-title: ACS Catal. doi: 10.1021/acscatal.9b02922 – volume: 24 start-page: 21417 year: 2022 ident: 44171_CR27 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/D2CP01316A – ident: 44171_CR8 doi: 10.1002/anie.202301340 – volume: 118 start-page: 236 year: 1971 ident: 44171_CR15 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2407974 – volume: 11 start-page: 9471 year: 2021 ident: 44171_CR12 publication-title: ACS Catal. doi: 10.1021/acscatal.1c02316 – volume: 53 start-page: 11932 year: 2019 ident: 44171_CR31 publication-title: Environ. Sci. Technol. doi: 10.1021/acs.est.9b04352 – volume: 145 start-page: 11323 year: 2023 ident: 44171_CR26 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.3c02399 – volume: 145 start-page: 289 year: 1994 ident: 44171_CR10 publication-title: J. Catal. doi: 10.1006/jcat.1994.1036 – volume: 119 start-page: 7610 year: 2019 ident: 44171_CR23 publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.8b00705 – volume: 12 start-page: 4840 year: 2022 ident: 44171_CR21 publication-title: ACS Catal. doi: 10.1021/acscatal.2c00430 – volume: 11 start-page: 1167 year: 2019 ident: 44171_CR28 publication-title: Nat. Chem. doi: 10.1038/s41557-019-0381-z – volume: 33 start-page: 2005192 year: 2021 ident: 44171_CR7 publication-title: Adv. Mater. doi: 10.1002/adma.202005192 – volume: 30 start-page: 1803111 year: 2018 ident: 44171_CR36 publication-title: Adv. Mater. doi: 10.1002/adma.201803111 – volume: 10 start-page: 6122 year: 2022 ident: 44171_CR11 publication-title: J. Mater. Chem. A doi: 10.1039/D1TA08002D – volume: 12 year: 2021 ident: 44171_CR24 publication-title: Nat. Commun. doi: 10.1038/s41467-021-23699-4 – volume: 61 start-page: e202206233 year: 2022 ident: 44171_CR33 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202206233 – volume: 13 year: 2022 ident: 44171_CR34 publication-title: Nat. Commun. doi: 10.1038/s41467-022-32933-6 – volume: 16 start-page: 2001384 year: 2020 ident: 44171_CR30 publication-title: Small doi: 10.1002/smll.202001384 – volume: 4 start-page: 557 year: 2021 ident: 44171_CR18 publication-title: Nat. Catal. doi: 10.1038/s41929-021-00641-x – volume: 12 year: 2021 ident: 44171_CR20 publication-title: Nat. Commun. doi: 10.1038/s41467-021-27372-8 – volume: 285 start-page: 712 year: 1999 ident: 44171_CR2 publication-title: Science doi: 10.1126/science.285.5428.712 – volume: 157 start-page: 277 year: 2020 ident: 44171_CR9 publication-title: Carbon doi: 10.1016/j.carbon.2019.10.058 – volume: 12 year: 2021 ident: 44171_CR16 publication-title: Nat. Commun. doi: 10.1038/s41467-021-26853-0 – volume: 375 start-page: 1188 year: 2022 ident: 44171_CR1 publication-title: Science doi: 10.1126/science.abi4407 – volume: 431 start-page: 134129 year: 2022 ident: 44171_CR13 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.134129 – volume: 14 year: 2023 ident: 44171_CR22 publication-title: Nat. Commun. doi: 10.1038/s41467-023-37821-1 |
| SSID | ssj0000391844 |
| Score | 2.5457914 |
| Snippet | Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate current density... Abstract Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity represents a sustainable pathway, but the inadequate... |
| SourceID | doaj pubmedcentral hal proquest pubmed crossref springer |
| SourceType | Open Website Open Access Repository Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 8384 |
| SubjectTerms | 140/133 140/146 147/135 147/137 147/143 639/301/299/886 639/638/77/886 Acetylene Catalysts Copper Copper converters Current density Direct conversion Engineering Sciences Ethylene Fluorine Humanities and Social Sciences Hydrogen Hydrogen evolution reactions Hydrogenation Industrial applications Localization multidisciplinary Polymers Science Science (multidisciplinary) |
| SummonAdditionalLinks | – databaseName: Directory of Open Access Journals (DOAJ) dbid: DOA link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1Lb9QwELZQJSQuiDcpBRnEDaxunJf3WFCrFQJOVOrN8mPMrrRNVmm20v4E_jUzTjY0VMAFKSc_Essz9jfOjL9h7G05h8Kr4IWXYSZyaY2whUpF5hBtSmNTb-g_5Jev5eI8_3RRXNxI9UUxYT09cD9xx0Xpgq_Aq8pZuoGrbCjKPEhLLmNlLe2-iHk3DlNxD87meHTJh1sys0wdX-VxT0CIEpR1KxXFBIkiYT_iy5LCIW_bmrdDJn_zm0Y4OnvA7g92JD_px_-Q3YH6EbvbZ5bcPWY_TiM1BL6Gr8bkHML1ZEzCU9R6t-PGQbdD2AHeNXzTrHeX0IrvrfHAAQUYa65Xhi93vm1Q00REvuHmJu-izQstpyhQHtZbiuUDcdn4VUDDlrtms4H2CTs_O_32cSGGrAvCoenWiVRKgACucmhcOeNy711uFT7WlB4yaRFXc6wAoFvYiPE5SsgElwVHksmesoO6qeE545mr0qCMUlBJ7FEYr6CQcwflHKU48wlL9xLQbqAkp8wYax1d45nSvdQ0Sk1HqekiYe_GPpuekOOvrT-QYMeWRKYdC1DF9KBi-l8qlrA3qBaTdyxOPmsqI2YoVZbqOk3Y0V5r9LANXGlJTlzKbVIl7PVYjQuYvDKmhmYb22RZTAuQsGe9ko2fIvo1tJjnCVMT9ZuMZVpTr5aRJByP9Xj2lzgD7_ea-mtcf56ww_8xYS_YPUkLLZUiLY_YQddu4SXabp19FZfpT4DvRLM priority: 102 providerName: Directory of Open Access Journals – databaseName: ProQuest Technology Collection dbid: 8FG link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3db9MwELdgCIkXxPcCAxnEG1hrnC_3CQ20UiHgiUl7s_xxXit1TUnTSf0T-K-5c9JMZWJSnmInsXvn-119598x9r4cQ-FV8MLLMBK5tEbYQqUic4g2pbGpN7QP-eNnOT3Lv50X5_2G27pPq9zZxGiofe1oj_xYUjyMykRUn1a_BVWNouhqX0LjLruXItJQSpeafB32WIj9XOV5f1ZmlKnjdR4tAwKVoNpbqSj28CjS9iPKzCgp8qbHeTNx8p_oaQSlySP2sPcm-Ukn_sfsDiyfsPtdfcntU_bnNBJE4Gv4fCjRIVxHySQ85a63W24ctFsEH-BtzVf1YnsJjbhojAcOKMbYcjU3fLb1TY36JiL-9ec3eRs9X2g45YLysNhQRh-Iy9rPA7q33NWrFTTP2Nnk9NeXqehrLwiHDlwrUikBArjKoYvljMu9d7lVeFlTesikRXTNsQGAzmIj0ucueBNcFlxR5iF7zg6W9RIOGc9clQZllIJK4hOF8QoKOXZQjm0oRj5h6U4C2vXE5FQfY6FjgDxTupOaRqnpKDVdJOzD8Myqo-W4tfdnEuzQkyi14426udD9CtVFiROowKvKWTrqrXBwOBFpKTdBWZuwd6gWe--YnnzXdI_4oRSq31WasKOd1ujeGKz1teom7O3QjMuYYjNmCfUm9smyWBwgYS86JRs-RSRs6DePE6b21G9vLPsty_ksUoXjn3tZoFlO2Medpl6P6_8_2Mvbp_GKPZC0hFIp0vKIHbTNBl6jb9baN3EB_gV1-Tuf priority: 102 providerName: ProQuest – databaseName: Springer Nature HAS Fully OA dbid: AAJSJ link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1Lj9MwELaWXSFxQbw3sCCDuIFF47zcY0G7qirgAivtzfJjvK3UbapsulJ_Av-aGScNKgtISDn5kTiecb5xPPMNY2_LMRReBS-8DCORS2uELVQqModoUxqbekP_Ib98Lafn-eyiuDhgchcLE532I6Vl_EzvvMM-XOdxSSPCCEqalYriDjsiqnbU7aPJZPZtNvxZIc5zled9hMwoU3_ovIdCkawfsWVOrpC37czb7pK_nZlGKDp7wO73NiSfdKN-yA5g9Yjd7bJKbh-zH6eRFgJvwxdDYg7hOiIm4cljvd1y46DdIuQAb2u-rpfbK2jEZWM8cEDhxZqbheHzrW9q1DIRUa-P2uRttHeh4eQBysNyQ358IK5qvwho1HJXr9fQPGHnZ6ffP01Fn3FBODTbWpFKCRDAVQ4NK2dc7r3LrcLLmtJDJi1iao4VABSBjfieu-BNcFlwRZmH7Ck7XNUrOGY8c1UalFEKKok9CuMVFHLsoBzbUIx8wtKdBLTr6cgpK8ZSx2PxTOlOahqlpqPUdJGwd0OfdUfG8c_WH0mwQ0si0o4FdXOpe8XSRYkvUIFXlbMU4K1wcPgi0pJHgrI2YW9QLfbuMZ181lRGrFCqLNVNmrCTndbo_hNwrSUd4FJekyphr4dqXLx0ImNWUG9imyyLKQES9qxTsuFRRL2G1vI4YWpP_fbGsl-zWswjQThu6XHfL3EG3u809de4_j5hz_-v-Qt2T9KSSqVIyxN22DYbeIkWWmtf9UvyJ8KuOsA priority: 102 providerName: Springer Nature |
| Title | Efficient industrial-current-density acetylene to polymer-grade ethylene via hydrogen-localization transfer over fluorine-modified copper |
| URI | https://link.springer.com/article/10.1038/s41467-023-44171-5 https://www.ncbi.nlm.nih.gov/pubmed/38104169 https://www.proquest.com/docview/2902580817 https://www.proquest.com/docview/2903326204 https://hal.science/hal-04378668 https://pubmed.ncbi.nlm.nih.gov/PMC10725425 https://doaj.org/article/56cfd7ed87cb45508bf564f2b91348bb |
| Volume | 14 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1Zb9NAEB71EKgvFTcuJVoQb7BQr6_NA0JplBBFtEJApLxZe7mJlMbBdSr8E_jXzK7toNAWyYqlPZy1Z8bzrXd2PoA3cddEmmeaapad0JBJQWXEfRoo9DaxkL4W9jvk2Xk8moTjaTTdgZbuqHmAV7dO7Syf1KRYvP_1s_qEBv-x3jLOP1yFztzR-1BLqOXTaBf20TMlltHgrIH77s0cdHFCEzZ7Z27vegD3bdIrxCndLVflMvqjA5rZeMmbYPRmTOU_C6vOXw0fwGEDNEmv1oyHsGOWj-BeTT1ZPYbfA5c7Ai9D5hv2DqrqbE1U27D2siJCmbJCv2RImZNVvqguTUEvCqENMShhV3M9F2RW6SJHVaTONTZbO0npQLEpiA0TJdlibYP9DL3M9TxD5EtUvlqZ4glMhoMf_RFtaBmoQmxXUp8xYzKjEoXoSwkVaq1CyfGQItYmYBIdb4gVxtht2ggCQpVpkakgU1EcZsFT2FvmS_McSKASP-OCc5Mw7BEJzU3EusrEXZlFJ9oDv5VAqpqc5ZY6Y5G6tfOAp7UAUxRg6gSYRh683fRZ1Rk7_tv61Ap209Jm23YFeXGRNsabRjHeQGI0T5S0u8A5Dg5vhEkbtsCl9OA1qsXWNUa9L6kts6mjeBzza9-D41Zr0lbNU2ZXeS35SeLBq001WrhdthFLk69dmyBwvAEePKuVbPNXrap6wLfUb2ss2zXL-cxlEcd5P4vwje3Bu1ZT_47r7gd2dOcYXsABs4bkM-rHx7BXFmvzEhFbKTuwm0wT_OXDzx3Y7_XG38d4Ph2cf_2Gpf2433HfQjrOXP8AHWFFYg |
| linkProvider | Scholars Portal |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1LbxMxELZKEYIL4s1CAYPgBFaz3pdzQKhAQ0rTnlqpN7N-bBMp3Q2bTdH-BP4Mv5EZ76MKFb1VymntdezMeL6JPTMfIW_joY2MyAwzPBuwkKuUqUj4LNCANnGqfJPiOeTBYTw-Dr-fRCcb5E-XC4NhlZ1NdIbaFBrPyLc53ochTUTyafGTIWsU3q52FBqNWuzb-hf8ZVt-3PsK8n3H-Wj36MuYtawCTINrUjGfc2szqxMNzoNOdWiMDpWAj0pjYwOuADdCaLAWs4wBw0KdmTTTQaajOMwCGPcGuRkGgOSYmT761p_pYLV1EYZtbs4gENvL0FkiAEaGXF8-i9bwz9EEAKpNMQjzsod7OVDzn9taB4Kje-Ru673SnUbd7pMNmz8gtxo-y_oh-b3rClLAMHTWU4Iw3ZSAYgZj5auawpqrGsDO0qqgi2Jen9mSnZapsdSC2riW81lKp7UpC9Bv5vC2zRellfO0bUkx9pRm8xVGEFp2VphZBu401cViYctH5PhapPKYbOZFbp8SGujEz0QqhE04vBGlRtiID7WNhyqLBsYjficBqdtC6MjHMZfuQj4QspGaBKlJJzUZeeR9_86iKQNyZe_PKNi-J5bwdg-K8lS2FkFGMSwgsUYkWmFquYDJwUK4wlgIoZRH3oBarI0x3plIfIb1qEQci3PfI1ud1sjW-CzlxVbxyOu-GcwG3gWluS1Wrk8QODICjzxplKz_Kiz6Bn760CNiTf3W5rLeks-mrjS5P0h4BDDgkQ-dpl7M6_8_2LOrl_GK3B4fHUzkZO9w_zm5w3E7-Zz58RbZrMqVfQF-YaVeus1IyY_r3v1_AX0qfKs |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1bb9MwFLZGJxAviDuBAQbBE1htnJv7gNDGVnVsVBNi0t6y-LZW6pqSpkP5Cfwlfh3nOEmnMrG3SXmKHcfOOT7fic-NkHdx30RaWM00tz0WcpkxGQmfBQrQJs6krzM8h_w2iofH4deT6GSD_GljYdCtspWJTlDrXOEZeZejPQzLRCRd27hFHO0OPs9_MqwghZbWtpxGzSIHpvoFv2-LT_u7QOv3nA_2fnwZsqbCAFOgppTM59wYa1SiQJFQmQq1VqEUcMks1ibgEjAkhAZjMOIY8CxUVmdWBVZFcWgDGPcW2Uzwr6hDNnf2RkffVyc8mHtdhGETqdMLRHcROrkEMMmw8pfPojU0dEUDAOPG6JJ5Vd-96rb5j-3WQeLgPrnX6LJ0u2a-B2TDzB6S23V1y-oR-b3n0lPAMHSyKhDCVJ0Qimn0nC8rCqsuK4A-Q8uczvNpdW4KdlZk2lADTORaLiYZHVe6yIHbmUPfJnqUlk7vNgVFT1Rqp0v0JzTsPNcTC8o1Vfl8borH5PhG6PKEdGb5zDwjNFCJb0UmhEk4PBFlWpiI95WJ-9JGPe0Rv6VAqpq06FidY5o683wg0ppqKVAtdVRLI498WD0zr5OCXNt7Bwm76okJvd2NvDhLG_mQRjEsIDFaJEpioLmAycFCuETPCCGlR94CW6yNMdw-TPEeZqcScSwufI9stVyTNqJokV5uHI-8WTWDEEHLUDYz-dL1CQJXmsAjT2smW70KU8CB1t73iFhjv7W5rLfMJmOXqNzvJTwCUPDIx5ZTL-f1_w_2_PplvCZ3YOenh_ujgxfkLsfd5HPmx1ukUxZL8xKUxFK-anYjJac3LQD-AjQcgj0 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Efficient+industrial-current-density+acetylene+to+polymer-grade+ethylene+via+hydrogen-localization+transfer+over+fluorine-modified+copper&rft.jtitle=Nature+communications&rft.au=Bai%2C+Lei&rft.au=Wang%2C+Yi&rft.au=Han%2C+Zheng&rft.au=Bai%2C+Jinbo&rft.date=2023-12-16&rft.eissn=2041-1723&rft.volume=14&rft.issue=1&rft.spage=8384&rft_id=info:doi/10.1038%2Fs41467-023-44171-5&rft_id=info%3Apmid%2F38104169&rft.externalDocID=38104169 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2041-1723&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2041-1723&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2041-1723&client=summon |