Cellulose nanocrystals and related nanocomposites: Review of some properties and challenges
ABSTRACT Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly compo...
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| Published in | Journal of polymer science. Part B, Polymer physics Vol. 52; no. 12; pp. 791 - 806 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken, NJ
Blackwell Publishing Ltd
15.06.2014
Wiley Wiley Subscription Services, Inc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | ABSTRACT
Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top‐down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 791–806
Impressive mechanical properties and reinforcing capability, abundance, low weight, renewability, and biodegradability make cellulose nanocrystals ideal candidates for use in polymer nanocomposites. This Review also looks at the broad range of potential applications of these nanoparticles, as well as the remaining questions in the field. |
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| AbstractList | ABSTRACT
Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top‐down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 791–806
Impressive mechanical properties and reinforcing capability, abundance, low weight, renewability, and biodegradability make cellulose nanocrystals ideal candidates for use in polymer nanocomposites. This Review also looks at the broad range of potential applications of these nanoparticles, as well as the remaining questions in the field. Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top-down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top-down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. copyright 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 791-806 Impressive mechanical properties and reinforcing capability, abundance, low weight, renewability, and biodegradability make cellulose nanocrystals ideal candidates for use in polymer nanocomposites. This Review also looks at the broad range of potential applications of these nanoparticles, as well as the remaining questions in the field. Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top-down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 791-806 [PUBLICATION ABSTRACT] Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant fibers. Indeed, lignocellulosic fibers consist of semicrystalline cellulose nanofibrils embedded in an amorphous matrix mainly composed of lignin and hemicelluloses. These nanostructures give the mechanical strength to higher plant cells, and are biodegradable, renewable, resistant, and widely available to produce nanocomposites with low density, and improved and controlled mechanical, optical, and barrier properties. Nanoparticles can be extracted from cellulose using a top‐down mechanically or chemically assisted deconstructing strategy, and owing to their highly reactive surface ensuing nanomaterials can be chemically modified to tailor their properties for a wide range of applications. This review is limited to cellulose chemically extracted nanocrystals and aims to provide an overview about several aspects that involve this material, including sources, properties, challenges, and perspectives. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52 , 791–806 |
| Author | El Kissi, Nadia Dufresne, Alain Mariano, Marcos |
| Author_xml | – sequence: 1 givenname: Marcos surname: Mariano fullname: Mariano, Marcos organization: Grenoble Institute of Technology (Grenoble INP)-The International School of Paper, Print Media and Biomaterials (Pagora), CS10065, 38402, Saint Martin d'Hères Cedex, France – sequence: 2 givenname: Nadia surname: El Kissi fullname: El Kissi, Nadia organization: Laboratoire Rhéologie et Procédés, Grenoble INP-CNRS-UJF, UMR 5520, BP 53, 38041, Grenoble Cedex 9, France – sequence: 3 givenname: Alain surname: Dufresne fullname: Dufresne, Alain email: alain.dufresne@pagora.grenoble-inp.fr organization: Grenoble Institute of Technology (Grenoble INP)-The International School of Paper, Print Media and Biomaterials (Pagora), CS10065, 38402, Saint Martin d'Hères Cedex, France |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28569297$$DView record in Pascal Francis https://hal.science/hal-02302485$$DView record in HAL |
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(e_1_2_10_10_1) 2004 Grunert M. (e_1_2_10_72_1) 2002; 86 e_1_2_10_110_1 e_1_2_10_91_1 Yu X. (e_1_2_10_69_1); 013 e_1_2_10_95_1 e_1_2_10_118_1 e_1_2_10_4_1 e_1_2_10_53_1 e_1_2_10_137_1 e_1_2_10_16_1 e_1_2_10_39_1 e_1_2_10_76_1 e_1_2_10_99_1 e_1_2_10_114_1 e_1_2_10_8_1 e_1_2_10_57_1 e_1_2_10_133_1 e_1_2_10_58_1 e_1_2_10_34_1 e_1_2_10_11_1 e_1_2_10_30_1 e_1_2_10_119_1 e_1_2_10_145_1 e_1_2_10_80_1 e_1_2_10_149_1 e_1_2_10_61_1 e_1_2_10_84_1 e_1_2_10_107_1 e_1_2_10_126_1 e_1_2_10_27_1 e_1_2_10_65_1 e_1_2_10_88_1 e_1_2_10_103_1 e_1_2_10_141_1 e_1_2_10_122_1 e_1_2_10_24_1 e_1_2_10_43_1 e_1_2_10_20_1 e_1_2_10_108_1 e_1_2_10_130_1 Azeredo H. M. C. 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Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of... Cellulosic nanoparticles with high Young's modulus, crystallinity, specific surface area, and aspect ratio can be found in the natural structure of plant... |
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| SubjectTerms | Applied sciences barrier Biodegradability biofibers Cellulose Chemical Sciences Composites Compounding ingredients Density Engineering Sciences Exact sciences and technology Fillers and reinforcing agents Forms of application and semi-finished materials mechanical properties Nanocomposites Nanocrystals Nanoparticles Nanostructure Polymer industry, paints, wood polysaccharides Specific surface Technology of polymers |
| Title | Cellulose nanocrystals and related nanocomposites: Review of some properties and challenges |
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