Highly sensitive analytical method for herbicide clopyralid residue in cattle manure compost with ultraperformance liquid chromatography tandem mass spectrometry

A micro liquid–liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix effects practically negligible during determination with ultraperformance liquid chromatography-electrospray ionization tandem mass spectrome...

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Published inJournal of Pesticide Science Vol. 44; no. 3; pp. 186 - 191
Main Authors Seike, Nobuyasu, Namiki, Sayuri, Watanabe, Eiki
Format Journal Article
LanguageEnglish
Published Tokyo Pesticide Science Society of Japan 20.08.2019
Japan Science and Technology Agency
Subjects
analytical validation
Cattle manure
Chromatography
clopyralid
compost
Composting
Composts
Herbicides
Ionization
Ions
LC-MS/MS
Liquid chromatography
Mass spectrometry
Mass spectroscopy
micro liquid–liquid extraction
Sample preparation
Scientific imaging
Spectroscopy
Online AccessGet full text
ISSN1348-589X
1349-0923
DOI10.1584/jpestics.D19-023

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Abstract A micro liquid–liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix effects practically negligible during determination with ultraperformance liquid chromatography-electrospray ionization tandem mass spectrometry with an improved limit of quantification of 0.7 µg/kg dry weight. Moreover, it had good accuracy and reproducibility. Therefore, the method is proposed as a highly effective routine analytical technique for investigating the actual status of clopyralid residue in compost.
AbstractList A micro liquid-liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix effects practically negligible during determination with ultraperformance liquid chromatography-electrospray ionization tandem mass spectrometry with an improved limit of quantification of 0.7 µg/kg dry weight. Moreover, it had good accuracy and reproducibility. Therefore, the method is proposed as a highly effective routine analytical technique for investigating the actual status of clopyralid residue in compost.A micro liquid-liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix effects practically negligible during determination with ultraperformance liquid chromatography-electrospray ionization tandem mass spectrometry with an improved limit of quantification of 0.7 µg/kg dry weight. Moreover, it had good accuracy and reproducibility. Therefore, the method is proposed as a highly effective routine analytical technique for investigating the actual status of clopyralid residue in compost.
A micro liquid–liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix effects practically negligible during determination with ultraperformance liquid chromatography-electrospray ionization tandem mass spectrometry with an improved limit of quantification of 0.7 µg/kg dry weight. Moreover, it had good accuracy and reproducibility. Therefore, the method is proposed as a highly effective routine analytical technique for investigating the actual status of clopyralid residue in compost.
Author Namiki, Sayuri
Watanabe, Eiki
Seike, Nobuyasu
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Snippet A micro liquid–liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix...
A micro liquid-liquid extraction has been applied to sample preparation in the current authorized method for clopyralid in compost. The method rendered matrix...
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SubjectTerms analytical validation
Cattle manure
Chromatography
clopyralid
compost
Composting
Composts
Herbicides
Ionization
Ions
LC-MS/MS
Liquid chromatography
Mass spectrometry
Mass spectroscopy
micro liquid–liquid extraction
Sample preparation
Scientific imaging
Spectroscopy
Title Highly sensitive analytical method for herbicide clopyralid residue in cattle manure compost with ultraperformance liquid chromatography tandem mass spectrometry
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