基于碳纤维材料基底的电解水制氢催化剂的研究进展
电解水制氢技术是未来获得清洁氢能源的有效途径之一。铂作为高效的电解水制氢催化剂,由于其价格昂贵,难以回收,不利于氢能源与氢经济的发展,因此发展高效的非贵金属电催化剂,使电解水制氢过程更加高效、经济化是十分关键的科学问题。本文综述了近年来电解水制氢催化剂的研究进展,重点集中在以碳纤维材料为基底的非贵金属催化剂领域。总结了几类重要的多相异质非贵金属催化剂,包括磷化物、硫化物、硒化物、碳化物、氧化物催化剂等,重点探讨了各种析氢催化剂的合成方法和性能提高策略。同时,本文也简要概述了碳纤维基底材料在电分析化学检测方面的应用研究。...
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Published in | 分析化学 Vol. 44; no. 9; pp. 1447 - 1457 |
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Main Author | |
Format | Journal Article |
Language | Chinese |
Published |
西北农林科技大学理学院,杨凌712100
2016
哈尔滨工业大学化工与化学学院,城市水资源与水环境国家重点实验室,哈尔滨150001%哈尔滨工业大学化工与化学学院,城市水资源与水环境国家重点实验室,哈尔滨150001 |
Subjects | |
Online Access | Get full text |
ISSN | 0253-3820 |
DOI | 10.11895/j.issn.0253-3820.160341 |
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Summary: | 电解水制氢技术是未来获得清洁氢能源的有效途径之一。铂作为高效的电解水制氢催化剂,由于其价格昂贵,难以回收,不利于氢能源与氢经济的发展,因此发展高效的非贵金属电催化剂,使电解水制氢过程更加高效、经济化是十分关键的科学问题。本文综述了近年来电解水制氢催化剂的研究进展,重点集中在以碳纤维材料为基底的非贵金属催化剂领域。总结了几类重要的多相异质非贵金属催化剂,包括磷化物、硫化物、硒化物、碳化物、氧化物催化剂等,重点探讨了各种析氢催化剂的合成方法和性能提高策略。同时,本文也简要概述了碳纤维基底材料在电分析化学检测方面的应用研究。 |
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Bibliography: | TONG Shan-Shan1,2, WANG Xue-Jing2, LI Qing-Chuan 2, HAN Xiao-Jun2( College of Science, Northwest A&F University, Yangling 712100, China ;State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China) Hydrogen evolution from water electrolysis is one of the effective ways to obtain clean hydrogen energy in the future. Pt-based materials are the efficient catalysts in hydrogen evolution reaction,but it is expensive,difficult to recycle,which impedes its application in the development of hydrogen energy and economy. Therefore,it is the key trend to develop efficient non-noble metal electrocatalysts with the aim of providing cost-competitive hydrogen energy. In this review,we highlighted the recent research efforts toward the synthesis of noble metal-free electrocatalysts for the hydrogen evolution reaction(HER),mainly focusing on nanomaterial catalysts supported on carbon fiber materials. We reviewed several importa |
ISSN: | 0253-3820 |
DOI: | 10.11895/j.issn.0253-3820.160341 |