Bio‐based and Degradable Block Polyester Pressure‐Sensitive Adhesives

A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm−1) and controllable storage and loss moduli, and t...

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Published inAngewandte Chemie International Edition Vol. 59; no. 52; pp. 23450 - 23455
Main Authors Chen, Thomas T. D., Carrodeguas, Leticia Peña, Sulley, Gregory S., Gregory, Georgina L., Williams, Charlotte K.
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 21.12.2020
John Wiley and Sons Inc
EditionInternational ed. in English
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Abstract A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm−1) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio‐based polyester formulations but without the need for tackifier or additives. Well‐defined bio‐based triblock polyesters were prepared using a mixture of renewable monomers and a one‐pot synthetic method with a single catalyst. These materials are pressure‐sensitive adhesives and are easily degraded under acidic conditions.
AbstractList A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm−1) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio‐based polyester formulations but without the need for tackifier or additives.
A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm −1 ) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio‐based polyester formulations but without the need for tackifier or additives. Well‐defined bio‐based triblock polyesters were prepared using a mixture of renewable monomers and a one‐pot synthetic method with a single catalyst. These materials are pressure‐sensitive adhesives and are easily degraded under acidic conditions.
A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm −1 ) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio‐based polyester formulations but without the need for tackifier or additives.
A new class of bio-based fully degradable block polyesters are pressure-sensitive adhesives. Bio-derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4-13 N cm-1 ) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio-based polyester formulations but without the need for tackifier or additives.A new class of bio-based fully degradable block polyesters are pressure-sensitive adhesives. Bio-derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4-13 N cm-1 ) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio-based polyester formulations but without the need for tackifier or additives.
A new class of bio-based fully degradable block polyesters are pressure-sensitive adhesives. Bio-derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4-13 N cm ) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio-based polyester formulations but without the need for tackifier or additives.
A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block polyesters with controlled compositions. They show moderate to high peel adhesions (4–13 N cm−1) and controllable storage and loss moduli, and they are removed by adhesive failure. Their properties compare favorably with commercial adhesives or bio‐based polyester formulations but without the need for tackifier or additives. Well‐defined bio‐based triblock polyesters were prepared using a mixture of renewable monomers and a one‐pot synthetic method with a single catalyst. These materials are pressure‐sensitive adhesives and are easily degraded under acidic conditions.
Author Sulley, Gregory S.
Gregory, Georgina L.
Carrodeguas, Leticia Peña
Williams, Charlotte K.
Chen, Thomas T. D.
AuthorAffiliation 1 Department of Chemistry University of Oxford Chemistry Research Laboratory 12 Mansfield Rd Oxford OX1 3TA UK
AuthorAffiliation_xml – name: 1 Department of Chemistry University of Oxford Chemistry Research Laboratory 12 Mansfield Rd Oxford OX1 3TA UK
Author_xml – sequence: 1
  givenname: Thomas T. D.
  surname: Chen
  fullname: Chen, Thomas T. D.
  organization: University of Oxford
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  givenname: Leticia Peña
  surname: Carrodeguas
  fullname: Carrodeguas, Leticia Peña
  organization: University of Oxford
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  givenname: Gregory S.
  surname: Sulley
  fullname: Sulley, Gregory S.
  organization: University of Oxford
– sequence: 4
  givenname: Georgina L.
  surname: Gregory
  fullname: Gregory, Georgina L.
  organization: University of Oxford
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  givenname: Charlotte K.
  orcidid: 0000-0002-0734-1575
  surname: Williams
  fullname: Williams, Charlotte K.
  email: charlotte.williams@chem.ox.ac.uk
  organization: University of Oxford
BackLink https://www.ncbi.nlm.nih.gov/pubmed/32886833$$D View this record in MEDLINE/PubMed
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Issue 52
Keywords block polyesters
polymers
degradable polymers
adhesives
ring-opening polymerization
Language English
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SSID ssj0028806
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Snippet A new class of bio‐based fully degradable block polyesters are pressure‐sensitive adhesives. Bio‐derived monomers are efficiently polymerized to make block...
A new class of bio-based fully degradable block polyesters are pressure-sensitive adhesives. Bio-derived monomers are efficiently polymerized to make block...
SourceID pubmedcentral
proquest
pubmed
crossref
wiley
SourceType Open Access Repository
Aggregation Database
Index Database
Enrichment Source
Publisher
StartPage 23450
SubjectTerms Additives
Adhesives
Adhesives - chemistry
block polyesters
Communication
Communications
degradable polymers
Formulations
Loss modulus
Monomers
Polyester resins
Polyesters
Polyesters - chemistry
Polymerization
polymers
ring-opening polymerization
Stability
Title Bio‐based and Degradable Block Polyester Pressure‐Sensitive Adhesives
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.202006807
https://www.ncbi.nlm.nih.gov/pubmed/32886833
https://www.proquest.com/docview/2469843995
https://www.proquest.com/docview/2440472777
https://pubmed.ncbi.nlm.nih.gov/PMC7756385
Volume 59
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