Formation of a High Conductivity Fuel Cell Electrolyte by Pressing Diphenylsiloxane-Based Inorganic-Organic Hybrid Particles
An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulf...
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| Published in | Journal of the American Ceramic Society Vol. 92; no. s1; pp. S185 - S188 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Malden, USA
Blackwell Publishing Inc
01.01.2009
Wiley Subscription Services, Inc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO–SiO2 particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO–SiO2 particles was lower than 10−9 S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10−2 S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. |
|---|---|
| AbstractList | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph
2
SiO–SiO
2
), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph
2
SiO–SiO
2
particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph
2
SiO–SiO
2
particles was lower than 10
−9
S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10
−2
S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO–SiO2 particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO–SiO2 particles was lower than 10−9 S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10−2 S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (Ph2SiO-SiO2), was prepared by sol-gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2-acrylamido-2-methyl-1-propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO-SiO2 particles via layer-by-layer assembly. A flexible sheet-like electrolyte was successfully obtained from the resulting PAMPS-deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO-SiO2 particles was lower than 10-9 S/cm at 80{degrees}C. On the other hand, the PAMPS-deposited samples showed proton conductivities ~7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 x 10-2 S/cm at 80{degrees}C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (...-...), was prepared by sol-gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2-acrylamido-2-methyl-1-propane sulfonic acid) (PAMPS) was deposited on the ...-... particles via layer-by-layer assembly. A flexible sheet-like electrolyte was successfully obtained from the resulting PAMPS-deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO-SiO2 particles was lower than 10... S/cm at 80...C. On the other hand, the PAMPS-deposited samples showed proton conductivities 7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 x 10... S/cm at 80...C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. (ProQuest: ... denotes formulae/symbols omitted.) |
| Author | Sakakibara, Saki Muto, Hiroyuki Sakamoto, Hisatoshi Sakai, Mototsugu Daiko, Yusuke Matsuda, Atsunori Katagiri, Kiyofumi |
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| Cites_doi | 10.1002/fuce.200400050 10.1016/S0167-2738(02)00746-4 10.1016/j.ssi.2006.03.053 10.1016/0167-2738(94)00228-K 10.1021/jp022347p 10.1149/1.2885101 10.1021/ja01168a090 10.1002/1521-4095(200009)12:18<1370::AID-ADMA1370>3.0.CO;2-1 10.1038/35073536 10.1016/j.ssi.2007.02.001 10.1016/S0376-7388(00)00633-5 10.1016/j.ssi.2007.01.021 10.1557/JMR.2005.0151 10.1039/b700410a |
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| Notes | ArticleID:JACE02640 istex:EBA4D1CEBAB914A1080B546885CA6CF68B744CFA ark:/67375/WNG-3GVN5LWF-M Presented at the 10th International Conference on Ceramic Processing Science, May 25–28, 2008, Inuyama, Japan. This work has been supported by New Energy and Industrial Technology Development Organization (NEDO) project “Development of Technology for Next‐Generation Fuel Cells.” M. Hickner—contributing editor ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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| References_xml | – volume: 177 start-page: 2421 year: 2006 end-page: 4 article-title: Structure and Proton Conductivity of Mechanochemically Treated 50CsHSO ·50CsH PO publication-title: Solid State Ionics – volume: 178 start-page: 601 year: 2007 end-page: 5 article-title: Preparation and Characterization of Surface‐Sulfonated Phenylsilsesquioxane‐Methylsilsesquioxane Particles publication-title: Solid State Ionics – volume: 38 start-page: 5854 year: 2005 end-page: 6 article-title: Self‐Assembly of Surface‐Charged Latex Nanoparticles publication-title: A New Route to the Creation of Continuous Channels for Ion Conduction – volume: 77 start-page: 105 year: 1995 end-page: 10 article-title: Proton and Deuteron Conductivity in CsHSO and CsDSO by Isotopic Exchange publication-title: Solid State Ionics – start-page: 87 year: 2003 end-page: 97 – volume: 5 start-page: 302 year: 2005 end-page: 8 article-title: Aspects of the Chemical Degradation of PFSA Ionomers Used in PEM Fuel Cells publication-title: Fuel Cells – volume: 178 start-page: 621 year: 2007 end-page: 5 article-title: Structures and Electrical Properties of Core‐Shell Composite Electrolytes with Multi‐Heterointerfaces publication-title: Solid State Ionics – volume: 20 start-page: 1234 year: 2005 end-page: 41 article-title: Gel‐Melting Method for Preparation of Organically Modified Siloxane Low‐Melting Glasses publication-title: J. Mater. Res. – volume: 156 start-page: 357 year: 2003 end-page: 69 article-title: Proton Conduction of CsH PO and its Composite with Silica in Dry and Humid Atmospheres publication-title: Solid State Ionics – volume: 9 start-page: 2319 year: 2007 end-page: 40 article-title: Layer‐by‐Layer Assembly as a Versatile Bottom‐up Nanofabrication Technique for Exploratory Research and Realistic Application publication-title: Phys. Chem. Chem. Phys. – volume: 410 start-page: 910 year: 2001 end-page: 3 article-title: Solid Acids as Fuel Cell Electrolytes publication-title: Nature – volume: 107 start-page: 4024 year: 2003 end-page: 33 article-title: Brønsted Acid‐Base Ionic Liquid as Proton‐Conducting Nonaqueous Electrolytes publication-title: J. Phys. Chem. B – volume: 12 start-page: 1370 year: 2000 end-page: 2 article-title: A Sol‐Gel‐Derived Glass as a Fuel Cell Electrolyte publication-title: Adv. Mater. – volume: 72 start-page: 5705 year: 1950 end-page: 12 article-title: Hydrolysis of Ethyl Silicate publication-title: J. Am. Chem. Soc. – volume: 185 start-page: 41 year: 2001 end-page: 58 article-title: Recent Advances in the Functionalisation of Polybenzimidazole and Polyetherketone for Fuel Cell Applications publication-title: J. Memb. Sci. – volume: 155 start-page: B479 year: 2008 end-page: 82 article-title: Deposition of Ultrathin Nafion Layers on Sol–Gel‐Derived Phenylsilsesquioxane Particles Via Layer‐By‐Layer Assembly publication-title: J. Electrochem. Soc. – ident: e_1_2_5_15_2 doi: 10.1002/fuce.200400050 – ident: e_1_2_5_4_2 doi: 10.1016/S0167-2738(02)00746-4 – volume: 177 start-page: 2421 year: 2006 ident: e_1_2_5_5_2 article-title: Structure and Proton Conductivity of Mechanochemically Treated 50CsHSO4·50CsH2PO4 publication-title: Solid State Ionics doi: 10.1016/j.ssi.2006.03.053 contributor: fullname: Matsuda A. – volume: 38 start-page: 5854 year: 2005 ident: e_1_2_5_9_2 article-title: Self‐Assembly of Surface‐Charged Latex Nanoparticles publication-title: A New Route to the Creation of Continuous Channels for Ion Conduction contributor: fullname: Gao J. – ident: e_1_2_5_3_2 doi: 10.1016/0167-2738(94)00228-K – ident: e_1_2_5_8_2 doi: 10.1021/jp022347p – ident: e_1_2_5_12_2 doi: 10.1149/1.2885101 – ident: e_1_2_5_16_2 doi: 10.1021/ja01168a090 – ident: e_1_2_5_7_2 doi: 10.1002/1521-4095(200009)12:18<1370::AID-ADMA1370>3.0.CO;2-1 – ident: e_1_2_5_2_2 doi: 10.1038/35073536 – volume: 178 start-page: 621 year: 2007 ident: e_1_2_5_11_2 article-title: Structures and Electrical Properties of Core‐Shell Composite Electrolytes with Multi‐Heterointerfaces publication-title: Solid State Ionics doi: 10.1016/j.ssi.2007.02.001 contributor: fullname: Daiko Y. – ident: e_1_2_5_6_2 doi: 10.1016/S0376-7388(00)00633-5 – volume: 178 start-page: 601 year: 2007 ident: e_1_2_5_10_2 article-title: Preparation and Characterization of Surface‐Sulfonated Phenylsilsesquioxane‐Methylsilsesquioxane Particles publication-title: Solid State Ionics doi: 10.1016/j.ssi.2007.01.021 contributor: fullname: Daiko Y. – ident: e_1_2_5_17_2 doi: 10.1557/JMR.2005.0151 – start-page: 87 volume-title: Multilayer Thin Films. Sequential Assembly of Nanocomposite Materials year: 2003 ident: e_1_2_5_14_2 contributor: fullname: Joanny J. F. – ident: e_1_2_5_13_2 doi: 10.1039/b700410a |
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| Snippet | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using... An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph 2 SiO–SiO 2 ), was prepared by sol–gel process... An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (...-...), was prepared by sol-gel process using... An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (Ph2SiO-SiO2), was prepared by sol-gel process using... |
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| SubjectTerms | Ceramics Conductivity Electrolytes Fuel cells Protons Silica |
| Title | Formation of a High Conductivity Fuel Cell Electrolyte by Pressing Diphenylsiloxane-Based Inorganic-Organic Hybrid Particles |
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