Formation of a High Conductivity Fuel Cell Electrolyte by Pressing Diphenylsiloxane-Based Inorganic-Organic Hybrid Particles
An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulf...
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Published in | Journal of the American Ceramic Society Vol. 92; no. s1; pp. S185 - S188 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Malden, USA
Blackwell Publishing Inc
01.01.2009
Wiley Subscription Services, Inc |
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Abstract | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO–SiO2 particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO–SiO2 particles was lower than 10−9 S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10−2 S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. |
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AbstractList | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph
2
SiO–SiO
2
), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph
2
SiO–SiO
2
particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph
2
SiO–SiO
2
particles was lower than 10
−9
S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10
−2
S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO–SiO2 particles via layer‐by‐layer assembly. A flexible sheet‐like electrolyte was successfully obtained from the resulting PAMPS‐deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO–SiO2 particles was lower than 10−9 S/cm at 80°C. On the other hand, the PAMPS‐deposited samples showed proton conductivities ∼7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 × 10−2 S/cm at 80°C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (Ph2SiO-SiO2), was prepared by sol-gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2-acrylamido-2-methyl-1-propane sulfonic acid) (PAMPS) was deposited on the Ph2SiO-SiO2 particles via layer-by-layer assembly. A flexible sheet-like electrolyte was successfully obtained from the resulting PAMPS-deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO-SiO2 particles was lower than 10-9 S/cm at 80{degrees}C. On the other hand, the PAMPS-deposited samples showed proton conductivities ~7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 x 10-2 S/cm at 80{degrees}C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (...-...), was prepared by sol-gel process using diphenyldiethoxysilane (DPDES) and tetraethoxysilane (TEOS), and a high proton conducting polymer of poly(2-acrylamido-2-methyl-1-propane sulfonic acid) (PAMPS) was deposited on the ...-... particles via layer-by-layer assembly. A flexible sheet-like electrolyte was successfully obtained from the resulting PAMPS-deposited particles by pressing. The proton conductivity of the sheet prepared using unmodified Ph2SiO-SiO2 particles was lower than 10... S/cm at 80...C. On the other hand, the PAMPS-deposited samples showed proton conductivities 7 orders of magnitude higher than those of the sample prepared using unmodified particles, and their conductivity reached about 1 x 10... S/cm at 80...C and 80% relative humidity. This is ascribed to the PAMPS layer being concentrated at the particle interfaces, which percolated throughout the monolithic sample. (ProQuest: ... denotes formulae/symbols omitted.) |
Author | Sakakibara, Saki Muto, Hiroyuki Sakamoto, Hisatoshi Sakai, Mototsugu Daiko, Yusuke Matsuda, Atsunori Katagiri, Kiyofumi |
Author_xml | – sequence: 1 givenname: Yusuke surname: Daiko fullname: Daiko, Yusuke organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan – sequence: 2 givenname: Saki surname: Sakakibara fullname: Sakakibara, Saki organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan – sequence: 3 givenname: Hisatoshi surname: Sakamoto fullname: Sakamoto, Hisatoshi organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan – sequence: 4 givenname: Kiyofumi surname: Katagiri fullname: Katagiri, Kiyofumi organization: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, Aichi 464-8603,Japan – sequence: 5 givenname: Hiroyuki surname: Muto fullname: Muto, Hiroyuki organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan – sequence: 6 givenname: Mototsugu surname: Sakai fullname: Sakai, Mototsugu organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan – sequence: 7 givenname: Atsunori surname: Matsuda fullname: Matsuda, Atsunori email: matsuda@tutms.tut.ac.jp organization: Department of Materials Science, Toyohashi University of Technology, Tempaku, Toyohashi, Aichi 441-8580, Japan |
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Cites_doi | 10.1002/fuce.200400050 10.1016/S0167-2738(02)00746-4 10.1016/j.ssi.2006.03.053 10.1016/0167-2738(94)00228-K 10.1021/jp022347p 10.1149/1.2885101 10.1021/ja01168a090 10.1002/1521-4095(200009)12:18<1370::AID-ADMA1370>3.0.CO;2-1 10.1038/35073536 10.1016/j.ssi.2007.02.001 10.1016/S0376-7388(00)00633-5 10.1016/j.ssi.2007.01.021 10.1557/JMR.2005.0151 10.1039/b700410a |
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Notes | ArticleID:JACE02640 istex:EBA4D1CEBAB914A1080B546885CA6CF68B744CFA ark:/67375/WNG-3GVN5LWF-M Presented at the 10th International Conference on Ceramic Processing Science, May 25–28, 2008, Inuyama, Japan. This work has been supported by New Energy and Industrial Technology Development Organization (NEDO) project “Development of Technology for Next‐Generation Fuel Cells.” M. Hickner—contributing editor ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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Snippet | An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph2SiO–SiO2), was prepared by sol–gel process using... An inorganic–organic nanohybrid particle with a two‐dimensional chain structure, diphenylsiloxane‐silica (Ph 2 SiO–SiO 2 ), was prepared by sol–gel process... An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (...-...), was prepared by sol-gel process using... An inorganic-organic nanohybrid particle with a two-dimensional chain structure, diphenylsiloxane-silica (Ph2SiO-SiO2), was prepared by sol-gel process using... |
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SubjectTerms | Ceramics Conductivity Electrolytes Fuel cells Protons Silica |
Title | Formation of a High Conductivity Fuel Cell Electrolyte by Pressing Diphenylsiloxane-Based Inorganic-Organic Hybrid Particles |
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