新型吸附剂铜基铂对放射性碘的吸附研究

通过测定铜基铂对放射性碘的吸附和洗脱性能，探索铂对铜基铂（PCC）性能的影响。在含有亚硫酸钠的稀硫酸介质中，采用柱层析技术测定了PCC对I-的吸附容量、洗脱效率。结果表明：氯铂酸用量在2mL时合成的PCC对I的工作吸附容量可达0．224mg／g（I与Cu的质量比），吸附效率大于99％。以15mL0．1mol／L氢氧化钠溶液洗脱铜基铂，洗脱效率在95％以上。...

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Bibliographic Details
Published in同位素 Vol. 27; no. 3; pp. 157 - 161
Main Author 许晓飞 王刚 马红利 董鹏 傅红宇 罗文博
Format Journal Article
LanguageChinese
Published 原子高科股份有限公司,北京,102413 2014
Subjects
放射性碘
选择性吸附
铜基铂
radioactive iodine
selective adsorption
选择性吸附
放射性碘
铜基铂
platinum-coated copper
Online AccessGet full text
ISSN1000-7512
DOI10.7538/tws.2014.27.03.0157

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Summary:通过测定铜基铂对放射性碘的吸附和洗脱性能，探索铂对铜基铂（PCC）性能的影响。在含有亚硫酸钠的稀硫酸介质中，采用柱层析技术测定了PCC对I-的吸附容量、洗脱效率。结果表明：氯铂酸用量在2mL时合成的PCC对I的工作吸附容量可达0．224mg／g（I与Cu的质量比），吸附效率大于99％。以15mL0．1mol／L氢氧化钠溶液洗脱铜基铂，洗脱效率在95％以上。
Bibliography:platinum-coated copper selective adsorption radioactive iodine
11-2566/TL
XU Xiao-fei, WANG Gang, MA Hong-li, DONG Peng, FU Hong-yu, LUO Wen-bo （HTA CO. ,LTD., Beijing 102413,China）
The adsorption and elution properties of platinum-coated copper （PCC） for radioactive iodine have been revealed and the effects of platinum on the performance of PCC were explored. In sulfuric acid medium containing sodium sulfite, the adsorption capacity, elution efficiency of PCC and the effect of platinum on PCC were determined by column chromatography. The results showed that the adsorption capacity of PCC prepared with 2 mL ehloroplatinie acid or more for I was up to 0. 224 mg/g with the adsorption efficiency of more than 990% while the elution efficiency was more than 95G by 15 mL 0.1 mol/L sodium hydroxide solution.
ISSN:1000-7512
DOI:10.7538/tws.2014.27.03.0157