Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents
The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedur...
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| Published in | Molecules Vol. 27; no. 12; p. 3900 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
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MDPI AG
17.06.2022
MDPI |
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| Online Access | Get full text |
| ISSN | 1420-3049 1420-3049 |
| DOI | 10.3390/molecules27123900 |
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| Abstract | The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C—H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C—H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail. |
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| AbstractList | The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C—H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C—H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail. The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C-H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C-H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail.The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C-H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C-H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail. |
| Author | Kotaro Kikushima Toshifumi Dohi Samata E. Shetgaonkar Fateh V. Singh Ritu Mamgain |
| AuthorAffiliation | 2 College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu 525-0058, Shiga, Japan; kixy@okayama-u.ac.jp 1 Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technoloy-Chennai, Chennai 600127, Tamil Nadu, India; samatashetgaonkar@gmail.com (S.E.S.); ritu.mamgain@vit.ac.in (R.M.) |
| AuthorAffiliation_xml | – name: 2 College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu 525-0058, Shiga, Japan; kixy@okayama-u.ac.jp – name: 1 Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technoloy-Chennai, Chennai 600127, Tamil Nadu, India; samatashetgaonkar@gmail.com (S.E.S.); ritu.mamgain@vit.ac.in (R.M.) |
| Author_xml | – sequence: 1 givenname: Samata E. surname: Shetgaonkar fullname: Shetgaonkar, Samata E. – sequence: 2 givenname: Ritu surname: Mamgain fullname: Mamgain, Ritu – sequence: 3 givenname: Kotaro surname: Kikushima fullname: Kikushima, Kotaro – sequence: 4 givenname: Toshifumi orcidid: 0000-0002-2812-9581 surname: Dohi fullname: Dohi, Toshifumi – sequence: 5 givenname: Fateh V. orcidid: 0000-0002-6358-4408 surname: Singh fullname: Singh, Fateh V. |
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| Title | Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents |
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