“珠串”堆叠超结构的介孔铁酸锌的制备与表征
以硫酸亚铁和硝酸锌为铁源和锌源，十二烷基硫酸钠为颗粒尺寸控制剂，草酸钠为沉淀剂，通过草酸盐的热分解制备了介孔铁酸锌。利用x射线粉末衍射、热分析、红外光谱、场发射扫描电镜和氮气吸附一脱附等手段对不同表面活性剂加入量制备的样品的晶相组成和表面结构进行了表征，结果显示，Fe2＋和十二烷基硫酸钠的摩尔比为10：1，煅烧温度为500℃时制备的铁酸锌有较大的表面积（82．0m2·g-1），BJH平均孔径为12．5nm，孔体积为0．257cm3·g-1，得到的介孔铁酸锌具有由尺寸均一的纳米粒子规则排列而形成的“珠串”堆叠超结构。...
Saved in:
| Published in | 材料工程 no. 10; pp. 24 - 28 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
福州大学化学化工学院,福州,350108
2013
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-4381 1001-4381 |
| DOI | 10.3969/j.issn.1001-4381.2013.10.004 |
Cover
| Abstract | 以硫酸亚铁和硝酸锌为铁源和锌源，十二烷基硫酸钠为颗粒尺寸控制剂，草酸钠为沉淀剂，通过草酸盐的热分解制备了介孔铁酸锌。利用x射线粉末衍射、热分析、红外光谱、场发射扫描电镜和氮气吸附一脱附等手段对不同表面活性剂加入量制备的样品的晶相组成和表面结构进行了表征，结果显示，Fe2＋和十二烷基硫酸钠的摩尔比为10：1，煅烧温度为500℃时制备的铁酸锌有较大的表面积（82．0m2·g-1），BJH平均孔径为12．5nm，孔体积为0．257cm3·g-1，得到的介孔铁酸锌具有由尺寸均一的纳米粒子规则排列而形成的“珠串”堆叠超结构。 |
|---|---|
| AbstractList | TB34; 以硫酸亚铁和硝酸锌为铁源和锌源,十二烷基硫酸钠为颗粒尺寸控制剂,草酸钠为沉淀剂,通过草酸盐的热分解制备了介孔铁酸锌.利用X射线粉末衍射、热分析、红外光谱、场发射扫描电镜和氮气吸附脱附等手段对不同表面活性剂加入量制备的样品的晶相组成和表面结构进行了表征,结果显示,Fe2+和十二烷基硫酸钠的摩尔比为10∶1,煅烧温度为500℃时制备的铁酸锌有较大的表面积(82.0m2·g-1),BJH平均孔径为12.5nm,孔体积为0.257cm3·g-1,得到的介孔铁酸锌具有由尺寸均一的纳米粒子规则排列而形成的“珠串”堆叠超结构. 以硫酸亚铁和硝酸锌为铁源和锌源，十二烷基硫酸钠为颗粒尺寸控制剂，草酸钠为沉淀剂，通过草酸盐的热分解制备了介孔铁酸锌。利用x射线粉末衍射、热分析、红外光谱、场发射扫描电镜和氮气吸附一脱附等手段对不同表面活性剂加入量制备的样品的晶相组成和表面结构进行了表征，结果显示，Fe2＋和十二烷基硫酸钠的摩尔比为10：1，煅烧温度为500℃时制备的铁酸锌有较大的表面积（82．0m2·g-1），BJH平均孔径为12．5nm，孔体积为0．257cm3·g-1，得到的介孔铁酸锌具有由尺寸均一的纳米粒子规则排列而形成的“珠串”堆叠超结构。 |
| Author | 沈水发 刘玉红 李玲 潘海波 |
| AuthorAffiliation | 福州大学化学化工学院,福州350108 |
| AuthorAffiliation_xml | – name: 福州大学化学化工学院,福州,350108 |
| Author_FL | LIU Yu-hong SHEN Shui-fa LI Ling PAN Hai-bo |
| Author_FL_xml | – sequence: 1 fullname: SHEN Shui-fa – sequence: 2 fullname: LIU Yu-hong – sequence: 3 fullname: LI Ling – sequence: 4 fullname: PAN Hai-bo |
| Author_xml | – sequence: 1 fullname: 沈水发 刘玉红 李玲 潘海波 |
| BookMark | eNrjYmDJy89LZWBQMTTQM7Y0s9TP0sssLs7TMzQwMNQ1MbYw1DMyMDQGcvUMDEyYGDjh4ixIbA4G3uLizCQg19DA1NDQhJPB_lHDnOf9C57s2PSoYe7TBW1P-xe82Nb6fPfkZ_Nans9qebK7--naKS8nN75s3fFySg9Q5GnHtqdL2p_s6HuxcMXTfY08DKxpiTnFqbxQmpshxM01xNlD18ff3dPZ0Uc32dTMRNc4NTkxxcjAJBVImlgkGxhYGhmbJadYpBomGVumpZhbmpiamlsmmpuZmCUmmRubmaUkGxtZpgKFU1LSUtMSjbkZVCHGlifmpSXmpcdn5ZcW5QEtjE_OSU8G-RzoRwMToDpFiLrkjPy89MJMoMqCoszcxKLKeBNzU3NjExMDYwAwe3Cg |
| ClassificationCodes | TB34 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.3969/j.issn.1001-4381.2013.10.004 |
| DatabaseName | 维普_期刊 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Preparation and Characterization of Mesoporous ZnFe204 with Superstructure o{ Stacking Strings o{ Bead |
| DocumentTitle_FL | Preparation and Characterization of Mesoporous ZnFe2O4 with Superstructure of Stacking Strings of Bead |
| EISSN | 1001-4381 |
| EndPage | 28 |
| ExternalDocumentID | clgc201310004 47573440 |
| GrantInformation_xml | – fundername: 国家自然科学基金资助项目; 福建省自然科学基金资助项目; 福建省教育厅资助项目 funderid: (21101028); (2012J01204); (JK2012002) |
| GroupedDBID | -02 2.D 2B. 2C0 2RA 2VQ 5VS 5XA 5XC 92H 92I 92L ACBEA ACGFS ACIWK ALMA_UNASSIGNED_HOLDINGS AMTXH CCEZO CDRFL CQIGP CW9 FEDTE FIJ GROUPED_DOAJ HVGLF IPNFZ RIG TCJ TGT U1G U5L W92 ~WA 4A8 93N ABJNI PSX |
| ID | FETCH-LOGICAL-c564-3ecad204ead248c009236cd8e1b39fd7945579a7646ab7366dc329e945ddfefa3 |
| ISSN | 1001-4381 |
| IngestDate | Thu May 29 04:06:47 EDT 2025 Wed Feb 14 10:39:09 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 10 |
| Keywords | 介孔 coprecipitation 铁酸锌 superstructure of stacking strings of bead 珠串超结构 共沉淀 ZnFe2O4 mesoporous |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c564-3ecad204ead248c009236cd8e1b39fd7945579a7646ab7366dc329e945ddfefa3 |
| Notes | 11-1800/TB ZnFe2 04 ; mesoporous ; coprecipitation ; superstructure of stacking strings of bead Mesoporous ZnFe2O4 was successfully synthesized through the reaction of Zn2＋ , Fe2＋ and C202/4- using sodium dodecyl sulfate （SDS） as size-controlling reagent. The characterizations were done by X-ray powder diffraction （XRD）, differential thermal analysis-thermo gravimetric analysis （DTA-TG）, fourier transform-infrared spectroscopy （FT-IR）, field emission scanning electronic mi- croscopy （FE-SEM）, nitrogen adsorption-desorption measurement, showing that mesoporous Zn- Fe204 can be obtained after calcined at 500℃ with Fe2＋ ： SDS （mol）=10 ： 1, its surface area is 82.0m2·g-1, BJH average diameter is 12.5nm, pore volume is 0. 257cm3 .g-1 and the mesoporous ZnFe204 has superstructure of stacking strings of bead. SHEN Shui-fa,LIU Yu-hong,LI Ling,PAN Hai-bo （College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China） |
| PageCount | 5 |
| ParticipantIDs | wanfang_journals_clgc201310004 chongqing_primary_47573440 |
| PublicationCentury | 2000 |
| PublicationDate | 2013 |
| PublicationDateYYYYMMDD | 2013-01-01 |
| PublicationDate_xml | – year: 2013 text: 2013 |
| PublicationDecade | 2010 |
| PublicationTitle | 材料工程 |
| PublicationTitleAlternate | Journal of Materials Engineering |
| PublicationTitle_FL | Journal of Materials Engineering |
| PublicationYear | 2013 |
| Publisher | 福州大学化学化工学院,福州,350108 |
| Publisher_xml | – name: 福州大学化学化工学院,福州,350108 |
| SSID | ssib001105114 ssib038074674 ssib051373031 ssib044725097 ssj0002507531 ssib023166898 |
| Score | 1.927404 |
| Snippet | ... TB34;... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 24 |
| SubjectTerms | 介孔 共沉淀 珠串超结构 铁酸锌 |
| Title | “珠串”堆叠超结构的介孔铁酸锌的制备与表征 |
| URI | http://lib.cqvip.com/qk/92115X/201310/47573440.html https://d.wanfangdata.com.cn/periodical/clgc201310004 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1Na1QxMNQKogfxE1u19NCcytb3Xr5P8l77Su3BU4XelvfZHmRbtb301EKrgmIP7UlUKnjw4sVDKRT8HZ7Lrtv9F85ks7sPKUWFx2OYzGQmmZBMkklCyEQhmDQlEzWYe5QwQTF-LS2lqCmweCEZRrXZANnHcu4Jn18Ui0NDPytRS-tr6VS2cea5kv-xKuDArnhK9h8s288UEACDfeEPFob_X9m4F6kwTWNF9SwNPRpzGmkaBb2kGRoLxGuJgKMBAkm1QK4ooobRWFITU80RY0ILcEzSkWWfoQYwBim1jwDwghTEgCs6XeECETZz5IIk5fTRMQoNfRpqTIpAll91i60CIMWzAHzGkikaWiWBS_e3hpAEygdyEPBoxF3JjD_pFDDaVghIMbaMIQ2DSScDVbFpURcVzVhyAKxABBiQV1dDusdYXdeNwWF4YVl3ZDsD51qyV-2veWXk755S_3NMYUYaO6ZgjlP9HDEqkE3ZwEA-GEv7EY5cCcU49y6Qi4FSPgabzj6aHziq4Nb6g_1rcLKl1IOJL74CwCu3LHGuwFUd7PcKn0HP7PZv0eeAVJh32tWFnoKXyITT_sF5uuOdIssrjaVn4CnZg2uNMmksVXyshWvkqpscjYfdln6dDG0s3yBXKldm3iQPTzY_tHcPmkffTzY_tg5etnYPTg932sd7vz5tt99vN4_ftL7td_a2OjtHnf23gGm9Pmx9edU8enf6-Wvrx9YtsjAbL0zP1dwjILVMSF5jRZbkgcehwwu4zvCKMCazXBd-ykyZw2gihDKJklwmqWJS5hkLTAHoPC-LMmG3yXBjpVHcIeMeEHh-IVIDLjT3ylSqJBFaejlTUHvFCBnt10R9tXvXS71nxxEy5qqm7jqAF_Xs6VKGNYlbZHz0PO675HJgn1HBpbt7ZHjt-XpxH5zZtXTMLgKN2dbxG6KAeQg |
| linkProvider | Ingenta |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E2%80%9C%E7%8F%A0%E4%B8%B2%E2%80%9D%E5%A0%86%E5%8F%A0%E8%B6%85%E7%BB%93%E6%9E%84%E7%9A%84%E4%BB%8B%E5%AD%94%E9%93%81%E9%85%B8%E9%94%8C%E7%9A%84%E5%88%B6%E5%A4%87%E4%B8%8E%E8%A1%A8%E5%BE%81&rft.jtitle=%E6%9D%90%E6%96%99%E5%B7%A5%E7%A8%8B&rft.au=%E6%B2%88%E6%B0%B4%E5%8F%91+%E5%88%98%E7%8E%89%E7%BA%A2+%E6%9D%8E%E7%8E%B2+%E6%BD%98%E6%B5%B7%E6%B3%A2&rft.date=2013&rft.issn=1001-4381&rft.eissn=1001-4381&rft.issue=10&rft.spage=24&rft.epage=28&rft_id=info:doi/10.3969%2Fj.issn.1001-4381.2013.10.004&rft.externalDocID=47573440 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F92115X%2F92115X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fclgc%2Fclgc.jpg |