Structural Evolution and Properties of Praseodymium Antimony Oxochlorides Based on a Chain-like Tertiary Building Unit
Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents us...
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| Published in | Molecules (Basel, Switzerland) Vol. 28; no. 6; p. 2725 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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| Abstract | Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH2CH3)3][FeII(2,2′-bpy)3][Pr4Sb12O18Cl15]·EtOH (1) (2,2′-bpy = 2,2′-bipyridine), [HN(CH2CH3)3][FeII(2,2′-bpy)3]2[Pr4Sb12O18Cl14)2Cl]·N(CH2CH3)3·2H2O (2), and (H3O)[Pr4Sb12O18Cl12.5(TEOA)0.5]·2.5EtOH (3) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr4Sb12O18Cl15−x]n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr4Sb12}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1, 2, and 3, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. |
|---|---|
| AbstractList | Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH
CH
)
][Fe
(2,2'-bpy)
][Pr
Sb
O
Cl
]·EtOH (
) (2,2'-bpy = 2,2'-bipyridine), [HN(CH
CH
)
][Fe
(2,2'-bpy)
]
[Pr
Sb
O
Cl
)
Cl]·N(CH
CH
)
·2H
O (
), and (H
O)[Pr
Sb
O
Cl
(TEOA)
]·2.5EtOH (
) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic
chain of [Pr
Sb
O
Cl
]
as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr
Sb
}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of
,
, and
, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound
has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH[sub.2]CH[sub.3])[sub.3]][Fe[sup.II](2,2′-bpy)[sub.3]][Pr[sub.4]Sb[sub.12]O[sub.18]Cl[sub.15]]·EtOH (1) (2,2′-bpy = 2,2′-bipyridine), [HN(CH[sub.2]CH[sub.3])[sub.3]][Fe[sup.II](2,2′-bpy)[sub.3]][sub.2][Pr[sub.4]Sb[sub.12]O[sub.18]Cl[sub.14])[sub.2]Cl]·N(CH[sub.2]CH[sub.3])[sub.3]·2H[sub.2]O (2), and (H[sub.3]O)[Pr[sub.4]Sb[sub.12]O[sub.18]Cl[sub.12.5](TEOA)[sub.0.5]]·2.5EtOH (3) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr[sub.4]Sb[sub.12]O[sub.18]Cl[sub.15−x]]n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr[sub.4]Sb[sub.12]}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1, 2, and 3, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH2CH3)3][FeII(2,2′-bpy)3][Pr4Sb12O18Cl15]·EtOH (1) (2,2′-bpy = 2,2′-bipyridine), [HN(CH2CH3)3][FeII(2,2′-bpy)3]2[Pr4Sb12O18Cl14)2Cl]·N(CH2CH3)3·2H2O (2), and (H3O)[Pr4Sb12O18Cl12.5(TEOA)0.5]·2.5EtOH (3) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr4Sb12O18Cl15−x]n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr4Sb12}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1, 2, and 3, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH 2 CH 3 ) 3 ][Fe II (2,2′-bpy) 3 ][Pr 4 Sb 12 O 18 Cl 15 ]·EtOH ( 1 ) (2,2′-bpy = 2,2′-bipyridine), [HN(CH 2 CH 3 ) 3 ][Fe II (2,2′-bpy) 3 ] 2 [Pr 4 Sb 12 O 18 Cl 14 ) 2 Cl]·N(CH 2 CH 3 ) 3 ·2H 2 O ( 2 ), and (H 3 O)[Pr 4 Sb 12 O 18 Cl 12.5 (TEOA) 0.5 ]·2.5EtOH ( 3 ) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr 4 Sb 12 O 18 Cl 15− x ] n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr 4 Sb 12 }) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1 , 2 , and 3 , respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH2CH3)3][FeII(2,2'-bpy)3][Pr4Sb12O18Cl15]·EtOH (1) (2,2'-bpy = 2,2'-bipyridine), [HN(CH2CH3)3][FeII(2,2'-bpy)3]2[Pr4Sb12O18Cl14)2Cl]·N(CH2CH3)3·2H2O (2), and (H3O)[Pr4Sb12O18Cl12.5(TEOA)0.5]·2.5EtOH (3) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr4Sb12O18Cl15-x]n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr4Sb12}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1, 2, and 3, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level.Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH2CH3)3][FeII(2,2'-bpy)3][Pr4Sb12O18Cl15]·EtOH (1) (2,2'-bpy = 2,2'-bipyridine), [HN(CH2CH3)3][FeII(2,2'-bpy)3]2[Pr4Sb12O18Cl14)2Cl]·N(CH2CH3)3·2H2O (2), and (H3O)[Pr4Sb12O18Cl12.5(TEOA)0.5]·2.5EtOH (3) (TEOA = mono-deprotonated triethanolamine anion). Single-crystal X-ray diffraction analysis revealed that all the three structures feature an anionic zig-zag chain of [Pr4Sb12O18Cl15-x]n as the tertiary building unit (TBU), which is formed by interconnections of praseodymium antimony oxochloride clusters (denoted as {Pr4Sb12}) as secondary building units. Interestingly, different arrangements or linkages of chain-like TBUs result in one-dimensional, two-dimensional layered, and three-dimensional structures of 1, 2, and 3, respectively, thus demonstrating clearly the structural evolution of metal oxohalide crystals. The title compounds have been characterized by elemental analysis, powder X-ray diffraction, thermogravimetric analysis, and UV-Vis spectroscopy, and the photodegradation for methyl blue in an aqueous solution of compound 1 has been preliminarily studied. This work offers a way to deeply understand the assembly process of intricate lanthanide-antimony(III) oxohalide structures at the atomic level. |
| Audience | Academic |
| Author | Huang, Xiao-Ying Pan, Tian-Yu Wen, Wei-Yang Hu, Bing Li, Zi-Wei Hu, Qian-Qian |
| AuthorAffiliation | 2 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China 3 University of Chinese Academy of Sciences, Beijing 100049, China 1 College of Chemistry, Fuzhou University, Fuzhou 350108, China |
| AuthorAffiliation_xml | – name: 2 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China – name: 1 College of Chemistry, Fuzhou University, Fuzhou 350108, China – name: 3 University of Chinese Academy of Sciences, Beijing 100049, China |
| Author_xml | – sequence: 1 givenname: Wei-Yang surname: Wen fullname: Wen, Wei-Yang – sequence: 2 givenname: Bing surname: Hu fullname: Hu, Bing – sequence: 3 givenname: Tian-Yu surname: Pan fullname: Pan, Tian-Yu – sequence: 4 givenname: Zi-Wei surname: Li fullname: Li, Zi-Wei – sequence: 5 givenname: Qian-Qian surname: Hu fullname: Hu, Qian-Qian – sequence: 6 givenname: Xiao-Ying orcidid: 0000-0002-3514-216X surname: Huang fullname: Huang, Xiao-Ying |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/36985695$$D View this record in MEDLINE/PubMed |
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| DOI | 10.3390/molecules28062725 |
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| Keywords | metal oxochloride tertiary building unit photodegradation single-crystal structure lanthanide antimony cluster structural evolution |
| Language | English |
| License | https://creativecommons.org/licenses/by/4.0 Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
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| Title | Structural Evolution and Properties of Praseodymium Antimony Oxochlorides Based on a Chain-like Tertiary Building Unit |
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