Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation

• Published in: Molecules (Basel, Switzerland) Vol. 28; no. 5; p. 2226
• Main Authors: Govindaraj, Manivannan, Zhong, Shih-Ying, Lin, Chia-Her, Chen, Jhy-Der
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 27.02.2023; MDPI
• Subjects: Acids; Chemical properties; Chemical research; Coordination compounds; coordination mode; coordination polymer; Crystal structure; crystal structure analysis; Degassing of metals; dicarboxylate; Geometry; Ligands; Metals; Nitrogen; Photodegradation; Polymers; Taiwan; crystal structure analysis; dicarboxylate; coordination polymer; coordination mode

Eight coordination polymers constructed from divalent metal salts, N,N′-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids are reported, affording [Co(L)(5-ter-IPA)(H2O)2]n (5-tert-H2IPA = 5-tert-butylisophthalic acid), 1, {[Co(L)(5-NO2-IPA)]⋅2H2O}n (5-NO2-H2IPA = 5-nitroisop...