Transition Metal Complexes Coordinated by Water Soluble Phosphane Ligands: How Cyclodextrins Can Alter the Coordination Sphere?

• Published in: Molecules (Basel, Switzerland) Vol. 22; no. 1; p. 140
• Main Authors: Ferreira, Michel, Bricout, Hervé, Tilloy, Sébastien, Monflier, Eric
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 01.01.2017; MDPI
• Subjects: beta-Cyclodextrins - chemistry; Cadmium; Catalysis; Chemical Sciences; Coordination Complexes - chemistry; cyclodextrin; Cyclodextrins; Expulsion; hydrosoluble organometallic complexes; Ligands; Magnetic Resonance Spectroscopy; Metal complexes; Molecular Structure; NMR; NMR spectroscopy; Nuclear magnetic resonance; Organometallic complexes; Organophosphorus Compounds - chemistry; Palladium; Palladium - chemistry; Phosphines - chemistry; Platinum; Platinum - chemistry; Steric hindrance; Sulfonic Acids - chemistry; supramolecular chemistry; TPPTS; Transition Elements - chemistry; Transition metal compounds; Water; β-Cyclodextrin; hydrosoluble organometallic complexes; palladium; platinum; supramolecular chemistry; TPPTS; cyclodextrin

The behaviour of platinum(II) and palladium(0) complexes coordinated by various hydrosoluble monodentate phosphane ligands has been investigated by P{¹H} NMR spectroscopy in the presence of randomly methylated β-cyclodextrin (RAME-β-CD). This molecular receptor can have no impact on the organometall...