New method for resolving the enantiomeric composition of 2-methyltetrols in atmospheric organic aerosols
► Chiral GC–MS method determines the enantiomeric composition of 2-methyltetrols. ► Enantiomer composition was used as a tool to study the origin of 2-methyltetrols. ► The validated method proved not to influence the enantiomer composition. ► Non-racemic mixtures of 2-methyltetrols were found in amb...
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Published in | Journal of Chromatography A Vol. 1218; no. 51; pp. 9288 - 9294 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
23.12.2011
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Abstract | ► Chiral GC–MS method determines the enantiomeric composition of 2-methyltetrols. ► Enantiomer composition was used as a tool to study the origin of 2-methyltetrols. ► The validated method proved not to influence the enantiomer composition. ► Non-racemic mixtures of 2-methyltetrols were found in ambient aerosol samples. ► The method elucidated a primary origin contribution to atmospheric 2-methyltetrols.
In order to facilitate the determination of the primary and secondary origin of atmospheric organic aerosols, a novel method involving chiral capillary gas chromatography coupled with mass spectrometry has been developed and validated. The method was focused on the analysis of 2-methylerythritol and 2-methylthreitol, considered to be tracers of secondary organic aerosols from the oxidation of atmospheric isoprene. The method was validated by performing various tests using authentic standards, including pure enantiomeric standards. The result showed that the analytical method itself does not affect the enantiomeric composition of the samples analyzed. The method was applied on atmospheric aerosols from a boreal forest collected in Aspvreten, Sweden and on laboratory samples obtained from liquid phase oxidation of isoprene and smog chamber experiments. Aerosol samples contained one enantiomer of 2-methylerythritol in significantly larger quantities than the others. In contrast, the liquid-phase oxidation of isoprene and its gas-phase oxidation in the smog chamber produced all enantiomers in equal quantities. The results obtained where the enantiomer fraction, EF, is larger than 0.50 suggest that 2-methyltetrols in atmospheric aerosols may also have biological origin. Information about the differences between enantiomer fractions obtained using this method brings new insights in the area of atmospheric aerosols. |
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AbstractList | In order to facilitate the determination of the primary and secondary origin of atmospheric organic aerosols, a novel method involving chiral capillary gas chromatography coupled with mass spectrometry has been developed and validated. The method was focused on the analysis of 2-methylerythritol and 2-methylthreitol, considered to be tracers of secondary organic aerosols from the oxidation of atmospheric isoprene. The method was validated by performing various tests using authentic standards, including pure enantiomeric standards. The result showed that the analytical method itself does not affect the enantiomeric composition of the samples analyzed. The method was applied on atmospheric aerosols from a boreal forest collected in Aspvreten, Sweden and on laboratory samples obtained from liquid phase oxidation of isoprene and smog chamber experiments. Aerosol samples contained one enantiomer of 2-methylerythritol in significantly larger quantities than the others. In contrast, the liquid-phase oxidation of isoprene and its gas-phase oxidation in the smog chamber produced all enantiomers in equal quantities. The results obtained where the enantiomer fraction, EF, is larger than 0.50 suggest that 2-methyltetrols in atmospheric aerosols may also have biological origin. Information about the differences between enantiomer fractions obtained using this method brings new insights in the area of atmospheric aerosols. ► Chiral GC–MS method determines the enantiomeric composition of 2-methyltetrols. ► Enantiomer composition was used as a tool to study the origin of 2-methyltetrols. ► The validated method proved not to influence the enantiomer composition. ► Non-racemic mixtures of 2-methyltetrols were found in ambient aerosol samples. ► The method elucidated a primary origin contribution to atmospheric 2-methyltetrols. In order to facilitate the determination of the primary and secondary origin of atmospheric organic aerosols, a novel method involving chiral capillary gas chromatography coupled with mass spectrometry has been developed and validated. The method was focused on the analysis of 2-methylerythritol and 2-methylthreitol, considered to be tracers of secondary organic aerosols from the oxidation of atmospheric isoprene. The method was validated by performing various tests using authentic standards, including pure enantiomeric standards. The result showed that the analytical method itself does not affect the enantiomeric composition of the samples analyzed. The method was applied on atmospheric aerosols from a boreal forest collected in Aspvreten, Sweden and on laboratory samples obtained from liquid phase oxidation of isoprene and smog chamber experiments. Aerosol samples contained one enantiomer of 2-methylerythritol in significantly larger quantities than the others. In contrast, the liquid-phase oxidation of isoprene and its gas-phase oxidation in the smog chamber produced all enantiomers in equal quantities. The results obtained where the enantiomer fraction, EF, is larger than 0.50 suggest that 2-methyltetrols in atmospheric aerosols may also have biological origin. Information about the differences between enantiomer fractions obtained using this method brings new insights in the area of atmospheric aerosols. |
Author | González, Nélida J.D. Nozière, Barbara Pei, Yuxin Borg-Karlson, Anna-Karin Dommen, Josef Prévôt, André S.H. Krejci, Radovan Redeby, Johan Pettersson |
Author_xml | – sequence: 1 givenname: Nélida J.D. surname: González fullname: González, Nélida J.D. email: nelida.gonzalez@itm.su.se organization: Department of Applied Environmental Science, Stockholm University, 10691 Stockholm, Sweden – sequence: 2 givenname: Anna-Karin surname: Borg-Karlson fullname: Borg-Karlson, Anna-Karin organization: Department of Chemistry, Organic Chemistry, Royal Institute of Technology, 10044 Stockholm, Sweden – sequence: 3 givenname: Johan Pettersson surname: Redeby fullname: Redeby, Johan Pettersson organization: Department of Chemistry, Analytical Chemistry, Royal Institute of Technology, 10044 Stockholm, Sweden – sequence: 4 givenname: Barbara surname: Nozière fullname: Nozière, Barbara organization: Department of Applied Environmental Science, Stockholm University, 10691 Stockholm, Sweden – sequence: 5 givenname: Radovan surname: Krejci fullname: Krejci, Radovan organization: Department of Applied Environmental Science, Stockholm University, 10691 Stockholm, Sweden – sequence: 6 givenname: Yuxin surname: Pei fullname: Pei, Yuxin organization: Department of Chemistry, Organic Chemistry, Royal Institute of Technology, 10044 Stockholm, Sweden – sequence: 7 givenname: Josef surname: Dommen fullname: Dommen, Josef organization: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland – sequence: 8 givenname: André S.H. surname: Prévôt fullname: Prévôt, André S.H. organization: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland |
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Keywords | Secondary Organic Aerosols Chiral GC–MS 2-Methylthreitol Isoprene 2-Methylerythritol Separation Derivatization Solvent extraction Ultrasound assisted extraction Sample preparation Enantiomer Acetylation Ultrasound Coupled method Chiral GC-MS Chiral stationary phase Air Acetic anhydride Operating conditions Gas chromatography Suspended particle Alditol Cyclodextrin Optical resolution Aerosols Mass spectrometry |
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Snippet | ► Chiral GC–MS method determines the enantiomeric composition of 2-methyltetrols. ► Enantiomer composition was used as a tool to study the origin of... In order to facilitate the determination of the primary and secondary origin of atmospheric organic aerosols, a novel method involving chiral capillary gas... |
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SubjectTerms | 2-Methylerythritol 2-Methylthreitol aerosols Aerosols - analysis Air Pollutants - analysis Analytical chemistry Atmosphere - chemistry boreal forests Butadienes - analysis Butadienes - chemistry capillary gas chromatography Chemistry Chiral GC-MS Chromatographic methods and physical methods associated with chromatography enantiomers Erythritol - analogs & derivatives Erythritol - analysis Erythritol - chemistry Exact sciences and technology Gas chromatographic methods Gas Chromatography-Mass Spectrometry - methods Hemiterpenes - analysis Hemiterpenes - chemistry Isoprene Limit of Detection mass spectrometry oxidation Oxidation-Reduction Pentanes - analysis Pentanes - chemistry Reproducibility of Results Secondary Organic Aerosols Stereoisomerism Sweden tracer techniques Trees |
Title | New method for resolving the enantiomeric composition of 2-methyltetrols in atmospheric organic aerosols |
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