Self-healing in Nanocomposite Hydrogels
Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self‐healing through autonomi...
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| Published in | Macromolecular rapid communications. Vol. 32; no. 16; pp. 1253 - 1258 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
17.08.2011
WILEY‐VCH Verlag |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self‐healing could be achieved not only immediately after being cut but also after a long waiting time.
Self‐healing: Nanocomposite (NC) gel with a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage can be repaired without the use of a healing agent, and even sections separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by contacting the cut surfaces at mildly elevated temperatures. |
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| AbstractList | Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self-healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re-)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self-healing could be achieved not only immediately after being cut but also after a long waiting time. Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self‐healing could be achieved not only immediately after being cut but also after a long waiting time. Self‐healing: Nanocomposite (NC) gel with a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage can be repaired without the use of a healing agent, and even sections separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by contacting the cut surfaces at mildly elevated temperatures. Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self‐healing could be achieved not only immediately after being cut but also after a long waiting time. magnified image Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self-healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re-)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self-healing could be achieved not only immediately after being cut but also after a long waiting time.Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self-healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re-)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self-healing could be achieved not only immediately after being cut but also after a long waiting time. |
| Author | Uyama, Kazuhisa Haraguchi, Kazutoshi Tanimoto, Hisashi |
| Author_xml | – sequence: 1 givenname: Kazutoshi surname: Haraguchi fullname: Haraguchi, Kazutoshi email: hara@kicr.or.jp organization: Material Chemistry Laboratory, Kawamura Institute of Chemical Research, 631 Sakado, Sakura, Chiba 285-0078, Japan – sequence: 2 givenname: Kazuhisa surname: Uyama fullname: Uyama, Kazuhisa organization: Material Chemistry Laboratory, Kawamura Institute of Chemical Research, 631 Sakado, Sakura, Chiba 285-0078, Japan – sequence: 3 givenname: Hisashi surname: Tanimoto fullname: Tanimoto, Hisashi organization: Material Chemistry Laboratory, Kawamura Institute of Chemical Research, 631 Sakado, Sakura, Chiba 285-0078, Japan |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/21732467$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Snippet | Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report... |
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| SubjectTerms | clay Cutting Damage Elasticity Healing Hydrogels Hydrogels - chemistry nanocomposite Nanocomposites Nanocomposites - chemistry Nanomaterials Nanostructure network Numerical control Polymers - chemistry self-healing Surface Properties |
| Title | Self-healing in Nanocomposite Hydrogels |
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