Modulate Organic-Metal Oxide Heterojunction via [1,6] Azafulleroid for Highly Efficient Organic Solar Cells

By creating an effective π‐orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit enhanced electronic coupling to the underneath metal oxides. High power conversion efficiency of 10.3% can be achieved in organic solar cells u...

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Published in	Advanced materials (Weinheim) Vol. 28; no. 33; pp. 7269 - 7275
Main Authors	Li, Chang-Zhi, Huang, Jiang, Ju, Huanxin, Zang, Yue, Zhang, Jianyuan, Zhu, Junfa, Chen, Hongzheng, Jen, Alex K.-Y.
Format	Journal Article
Language	English
Published	Germany Blackwell Publishing Ltd 01.09.2016
Subjects	Butyric acid Coupling Energy conversion efficiency Esters fullerenes fulleroids interfaces Metal oxides organic solar cells Oxides Photovoltaic cells Solar cells organic solar cells fulleroids interfaces fullerenes metal oxides
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Abstract	By creating an effective π‐orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit enhanced electronic coupling to the underneath metal oxides. High power conversion efficiency of 10.3% can be achieved in organic solar cells using open‐cage phenyl C61 butyric acid methyl ester (PCBM)‐modified zinc oxide layer.
AbstractList	By creating an effective π‐orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit enhanced electronic coupling to the underneath metal oxides. High power conversion efficiency of 10.3% can be achieved in organic solar cells using open‐cage phenyl C61 butyric acid methyl ester (PCBM)‐modified zinc oxide layer. By creating an effective pi -orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit enhanced electronic coupling to the underneath metal oxides. High power conversion efficiency of 10.3% can be achieved in organic solar cells using open-cage phenyl C sub(61) butyric acid methyl ester (PCBM)-modified zinc oxide layer.
Author	Ju, Huanxin Jen, Alex K.-Y. Li, Chang-Zhi Huang, Jiang Zang, Yue Chen, Hongzheng Zhu, Junfa Zhang, Jianyuan
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Snippet	By creating an effective π‐orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit... By creating an effective π-orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit... By creating an effective pi -orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit...
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SubjectTerms	Butyric acid Coupling Energy conversion efficiency Esters fullerenes fulleroids interfaces Metal oxides organic solar cells Oxides Photovoltaic cells Solar cells
Title	Modulate Organic-Metal Oxide Heterojunction via [1,6] Azafulleroid for Highly Efficient Organic Solar Cells
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