A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals
A literature survey on liquid-phase adsorption of selected heavy metals including Cu(II), Zn(II), Ni(II), Cd(II), Pb(II), Hg(II), and Cr(VI) on chitosan (CTS) and its derivatives was made from the viewpoint of adsorption capacity. This parameter was obtained from the Langmuir fit of isotherm data. T...
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Published in | Journal of environmental management Vol. 91; no. 4; pp. 798 - 806 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
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Elsevier Ltd
01.03.2010
Elsevier Academic Press Ltd |
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Abstract | A literature survey on liquid-phase adsorption of selected heavy metals including Cu(II), Zn(II), Ni(II), Cd(II), Pb(II), Hg(II), and Cr(VI) on chitosan (CTS) and its derivatives was made from the viewpoint of adsorption capacity. This parameter was obtained from the Langmuir fit of isotherm data. The magnitude of adsorption capacity of heavy metals on pristine CTS was also used to discuss the mechanism of adsorption; that is, how many amino groups in CTS chains would coordinate with one heavy metal ion. Furthermore, a newly defined parameter, the approaching equilibrium factor
R
L, was proposed to quantitatively indicate the favorability of the related adsorption process and to judge the correctness of adsorption capacity determined by the Langmuir equation. |
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AbstractList | A literature survey on liquid-phase adsorption of selected heavy metals including Cu(II), Zn(II), Ni(II), Cd(II), Pb(II), Hg(II), and Cr(VI) on chitosan (CTS) and its derivatives was made from the viewpoint of adsorption capacity. This parameter was obtained from the Langmuir fit of isotherm data. The magnitude of adsorption capacity of heavy metals on pristine CTS was also used to discuss the mechanism of adsorption; that is, how many amino groups in CTS chains would coordinate with one heavy metal ion. Furthermore, a newly defined parameter, the approaching equilibrium factor
R
L, was proposed to quantitatively indicate the favorability of the related adsorption process and to judge the correctness of adsorption capacity determined by the Langmuir equation. A literature survey on liquid-phase adsorption of selected heavy metals including Cu(II), Zn(II), Ni(II), Cd(II), Pb(II), Hg(II), and Cr(VI) on chitosan (CTS) and its derivatives was made from the viewpoint of adsorption capacity. This parameter was obtained from the Langmuir fit of isotherm data. The magnitude of adsorption capacity of heavy metals on pristine CTS was also used to discuss the mechanism of adsorption; that is, how many amino groups in CTS chains would coordinate with one heavy metal ion. Furthermore, a newly defined parameter, the approaching equilibrium factor R L, was proposed to quantitatively indicate the favorability of the related adsorption process and to judge the correctness of adsorption capacity determined by the Langmuir equation. A literature survey on liquid-phase adsorption of selected heavy metals including Cu(II), Zn(II), Ni(II), Cd(II), Pb(II), Hg(II), and Cr(VI) on chitosan (CTS) and its derivatives was made from the viewpoint of adsorption capacity. This parameter was obtained from the Langmuir fit of isotherm data. The magnitude of adsorption capacity of heavy metals on pristine CTS was also used to discuss the mechanism of adsorption; that is, how many amino groups in CTS chains would coordinate with one heavy metal ion. Furthermore, a newly defined parameter, the approaching equilibrium factor RL, was proposed to quantitatively indicate the favorability of the related adsorption process and to judge the correctness of adsorption capacity determined by the Langmuir equation. [PUBLICATION ABSTRACT] |
Author | Wu, Feng-Chin Juang, Ruey-Shin Tseng, Ru-Ling |
Author_xml | – sequence: 1 givenname: Feng-Chin surname: Wu fullname: Wu, Feng-Chin organization: Department of Chemical Engineering, National United University, Miao-Li 360, Taiwan – sequence: 2 givenname: Ru-Ling surname: Tseng fullname: Tseng, Ru-Ling organization: Department of Safety, Health and Environmental Engineering, National United University, Miao-Li 360, Taiwan – sequence: 3 givenname: Ruey-Shin surname: Juang fullname: Juang, Ruey-Shin email: rsjuang@saturn.yzu.edu.tw organization: Department of Chemical Engineering and Materials Science, Yuan Ze University, 135 Yuan-Tung Road, Chung-Li 32003, Taiwan |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22602377$$DView record in Pascal Francis https://www.ncbi.nlm.nih.gov/pubmed/19917518$$D View this record in MEDLINE/PubMed |
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Keywords | Adsorption capacity Chemical modification Chitosan Heavy metals Langmuir isotherm Modification Isotherm Review Adsorbent Experimental study Environmental management Heavy metal |
Language | English |
License | CC BY 4.0 Copyright 2009 Elsevier Ltd. All rights reserved. |
LinkModel | DirectLink |
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PMID | 19917518 |
PQID | 195622284 |
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PublicationCentury | 2000 |
PublicationDate | 2010-03-01 |
PublicationDateYYYYMMDD | 2010-03-01 |
PublicationDate_xml | – month: 03 year: 2010 text: 2010-03-01 day: 01 |
PublicationDecade | 2010 |
PublicationPlace | Kidlington |
PublicationPlace_xml | – name: Kidlington – name: England – name: London |
PublicationTitle | Journal of environmental management |
PublicationTitleAlternate | J Environ Manage |
PublicationYear | 2010 |
Publisher | Elsevier Ltd Elsevier Academic Press Ltd |
Publisher_xml | – name: Elsevier Ltd – name: Elsevier – name: Academic Press Ltd |
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SubjectTerms | Adsorbents Adsorption Adsorption capacity Animal, plant and microbial ecology Applied ecology Biological and medical sciences Carbohydrates Chemical modification Chemistry Techniques, Analytical - methods Chitosan Chitosan - chemistry Conservation, protection and management of environment and wildlife Derivatives Fundamental and applied biological sciences. Psychology General aspects Heavy metals Industrial Waste Isotherms Langmuir isotherm Management Mathematical analysis Metals, Heavy - chemistry Water Purification - methods |
Title | A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals |
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