Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution

The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. Th...

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Published inPolymers Vol. 11; no. 5; p. 850
Main Authors Lei, Yanhua, Qiu, Zhichao, Liu, Jiurong, Li, Dongdong, Tan, Ning, Liu, Tao, Zhang, Yuliang, Chang, Xueting, Gu, Yanhong, Yin, Yansheng
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 10.05.2019
MDPI
Subjects
Barriers
Cathodic coating (process)
Cathodic protection
conducting polymer
corrosion
Corrosion effects
Corrosion potential
Corrosion prevention
Corrosion tests
Dielectric properties
Electrochemical analysis
Electrochemical impedance spectroscopy
Electrodes
Electrolytes
Epoxy resins
Graphene
LEIS
Measuring instruments
Nanosheets
PANI
Polyanilines
Primers (coatings)
Protective coatings
Scanning electron microscopy
Spectrum analysis
Zinc
Zinc coatings
United States > US
China
Japan
LEIS
conducting polymer
PANI
corrosion
graphene
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Abstract The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. The protective properties and electrochemical behavior of coatings with artificial defects were investigated by monitoring the free corrosion potential versus time and by using localized electrochemical impedance spectroscopy (LEIS). A synergetic enhancement of the physical barrier role of the coating and the zinc sacrificial cathodic protection was achieved in the case of ZRP including PANI/Gr nanosheets. In addition, the ZRP mixed with the PANI/Gr at a content of 0.6% exhibited the best anticorrosion performance across the range of investigated PANI/Gr contents.
AbstractList The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. The protective properties and electrochemical behavior of coatings with artificial defects were investigated by monitoring the free corrosion potential versus time and by using localized electrochemical impedance spectroscopy (LEIS). A synergetic enhancement of the physical barrier role of the coating and the zinc sacrificial cathodic protection was achieved in the case of ZRP including PANI/Gr nanosheets. In addition, the ZRP mixed with the PANI/Gr at a content of 0.6% exhibited the best anticorrosion performance across the range of investigated PANI/Gr contents.
Author Zhang, Yuliang
Li, Dongdong
Gu, Yanhong
Liu, Jiurong
Qiu, Zhichao
Lei, Yanhua
Tan, Ning
Liu, Tao
Chang, Xueting
Yin, Yansheng
AuthorAffiliation 1 Institute of Marine Materials Science and Engineering, College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China; qzc4321@163.com (Z.Q.); liujingrong@126.com (J.L.); 201730410071@stu.shmtu.edu.cn (D.L.); tanning986@163.com (N.T.); liutao@shmtu.edu.cn (T.L.); ylzhang@shmtu.edu.cn (Y.Z.); xtchang@shmtu.edu.cn (X.C.); ysyin@shmtu.edu.cn (Y.Y.)
2 Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing Institute of Petrochemical Technology, Beijing 102617, China
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/31083352$$D View this record in MEDLINE/PubMed
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2019 by the authors. 2019
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Snippet The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated....
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StartPage 850
SubjectTerms Barriers
Cathodic coating (process)
Cathodic protection
conducting polymer
corrosion
Corrosion effects
Corrosion potential
Corrosion prevention
Corrosion tests
Dielectric properties
Electrochemical analysis
Electrochemical impedance spectroscopy
Electrodes
Electrolytes
Epoxy resins
Graphene
LEIS
Measuring instruments
Nanosheets
PANI
Polyanilines
Primers (coatings)
Protective coatings
Scanning electron microscopy
Spectrum analysis
Zinc
Zinc coatings
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Title Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution
URI https://www.ncbi.nlm.nih.gov/pubmed/31083352
https://www.proquest.com/docview/2557237958
https://search.proquest.com/docview/2231989922
https://pubmed.ncbi.nlm.nih.gov/PMC6572091
https://doaj.org/article/4488efe8ca884af29a5fcbbb6cb55166
Volume 11
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