Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution
The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. Th...
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Published in | Polymers Vol. 11; no. 5; p. 850 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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10.05.2019
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Abstract | The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. The protective properties and electrochemical behavior of coatings with artificial defects were investigated by monitoring the free corrosion potential versus time and by using localized electrochemical impedance spectroscopy (LEIS). A synergetic enhancement of the physical barrier role of the coating and the zinc sacrificial cathodic protection was achieved in the case of ZRP including PANI/Gr nanosheets. In addition, the ZRP mixed with the PANI/Gr at a content of 0.6% exhibited the best anticorrosion performance across the range of investigated PANI/Gr contents. |
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AbstractList | The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. The protective properties and electrochemical behavior of coatings with artificial defects were investigated by monitoring the free corrosion potential versus time and by using localized electrochemical impedance spectroscopy (LEIS). A synergetic enhancement of the physical barrier role of the coating and the zinc sacrificial cathodic protection was achieved in the case of ZRP including PANI/Gr nanosheets. In addition, the ZRP mixed with the PANI/Gr at a content of 0.6% exhibited the best anticorrosion performance across the range of investigated PANI/Gr contents. |
Author | Zhang, Yuliang Li, Dongdong Gu, Yanhong Liu, Jiurong Qiu, Zhichao Lei, Yanhua Tan, Ning Liu, Tao Chang, Xueting Yin, Yansheng |
AuthorAffiliation | 1 Institute of Marine Materials Science and Engineering, College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China; qzc4321@163.com (Z.Q.); liujingrong@126.com (J.L.); 201730410071@stu.shmtu.edu.cn (D.L.); tanning986@163.com (N.T.); liutao@shmtu.edu.cn (T.L.); ylzhang@shmtu.edu.cn (Y.Z.); xtchang@shmtu.edu.cn (X.C.); ysyin@shmtu.edu.cn (Y.Y.) 2 Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing Institute of Petrochemical Technology, Beijing 102617, China |
AuthorAffiliation_xml | – name: 2 Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing Institute of Petrochemical Technology, Beijing 102617, China – name: 1 Institute of Marine Materials Science and Engineering, College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China; qzc4321@163.com (Z.Q.); liujingrong@126.com (J.L.); 201730410071@stu.shmtu.edu.cn (D.L.); tanning986@163.com (N.T.); liutao@shmtu.edu.cn (T.L.); ylzhang@shmtu.edu.cn (Y.Z.); xtchang@shmtu.edu.cn (X.C.); ysyin@shmtu.edu.cn (Y.Y.) |
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Snippet | The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated.... |
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SubjectTerms | Barriers Cathodic coating (process) Cathodic protection conducting polymer corrosion Corrosion effects Corrosion potential Corrosion prevention Corrosion tests Dielectric properties Electrochemical analysis Electrochemical impedance spectroscopy Electrodes Electrolytes Epoxy resins Graphene LEIS Measuring instruments Nanosheets PANI Polyanilines Primers (coatings) Protective coatings Scanning electron microscopy Spectrum analysis Zinc Zinc coatings |
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Title | Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution |
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