A new thin film photochromic material: Oxygen-containing yttrium hydride

In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light at moderate intensity triggers a decrease in the optical transmission of visible and infrared (IR) light. The photo-darkening is colour-neutra...

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Published inSolar energy materials and solar cells Vol. 95; no. 12; pp. 3596 - 3599
Main Authors Mongstad, Trygve, Platzer-Björkman, Charlotte, Maehlen, Jan Petter, Mooij, Lennard P.A., Pivak, Yevheniy, Dam, Bernard, Marstein, Erik S., Hauback, Bjørn C., Karazhanov, Smagul Zh
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.12.2011
Elsevier
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Abstract In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light at moderate intensity triggers a decrease in the optical transmission of visible and infrared (IR) light. The photo-darkening is colour-neutral. We show that the optical transmission of samples of 500 nm thickness can be reduced by up to 50% after one hour of illumination with light of moderate intensity. The reaction is reversible and samples that are left in the dark return to the initial transparent state. The relaxation time in the dark depends on the temperature of the sample and the duration of the light exposure. The photochromic reaction takes place under ambient conditions in the as-deposited state of the thin-film samples. [Display omitted] ► Photochromic response in the as-deposited state at ambient conditions. ► Sensitive to visible and ultraviolet light. ► Colour-neutral photo-darkening. ► Persistent photoconductivity accompanies the photochromic darkening. ► Reversible reaction, material relaxes back to transparent state when left in dark.
AbstractList In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light at moderate intensity triggers a decrease in the optical transmission of visible and infrared (IR) light. The photo-darkening is colour-neutral. We show that the optical transmission of samples of 500 nm thickness can be reduced by up to 50% after one hour of illumination with light of moderate intensity. The reaction is reversible and samples that are left in the dark return to the initial transparent state. The relaxation time in the dark depends on the temperature of the sample and the duration of the light exposure. The photochromic reaction takes place under ambient conditions in the as-deposited state of the thin-film samples.
In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light at moderate intensity triggers a decrease in the optical transmission of visible and infrared (IR) light. The photo-darkening is colour-neutral. We show that the optical transmission of samples of 500 nm thickness can be reduced by up to 50% after one hour of illumination with light of moderate intensity. The reaction is reversible and samples that are left in the dark return to the initial transparent state. The relaxation time in the dark depends on the temperature of the sample and the duration of the light exposure. The photochromic reaction takes place under ambient conditions in the as-deposited state of the thin-film samples. [Display omitted] ► Photochromic response in the as-deposited state at ambient conditions. ► Sensitive to visible and ultraviolet light. ► Colour-neutral photo-darkening. ► Persistent photoconductivity accompanies the photochromic darkening. ► Reversible reaction, material relaxes back to transparent state when left in dark.
Author Marstein, Erik S.
Karazhanov, Smagul Zh
Dam, Bernard
Hauback, Bjørn C.
Pivak, Yevheniy
Maehlen, Jan Petter
Platzer-Björkman, Charlotte
Mongstad, Trygve
Mooij, Lennard P.A.
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  givenname: Trygve
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  givenname: Charlotte
  surname: Platzer-Björkman
  fullname: Platzer-Björkman, Charlotte
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  givenname: Jan Petter
  surname: Maehlen
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  givenname: Lennard P.A.
  surname: Mooij
  fullname: Mooij, Lennard P.A.
  organization: Delft University of Technology, Materials for Energy Conversion and Storage, Julianalaan 136, 2628BL Delft, The Netherlands
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  givenname: Yevheniy
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  givenname: Bernard
  surname: Dam
  fullname: Dam, Bernard
  organization: Delft University of Technology, Materials for Energy Conversion and Storage, Julianalaan 136, 2628BL Delft, The Netherlands
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  givenname: Erik S.
  surname: Marstein
  fullname: Marstein, Erik S.
  organization: Institute for Energy Technology, Box 40, NO-2027 Kjeller, Norway
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  givenname: Bjørn C.
  surname: Hauback
  fullname: Hauback, Bjørn C.
  organization: Institute for Energy Technology, Box 40, NO-2027 Kjeller, Norway
– sequence: 9
  givenname: Smagul Zh
  surname: Karazhanov
  fullname: Karazhanov, Smagul Zh
  organization: Institute for Energy Technology, Box 40, NO-2027 Kjeller, Norway
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Issue 12
Keywords Thin films
Photochromism
Photoconductivity
Sputter deposition
Yttrium compounds
Hydrogen
Doped materials
Relaxation time
Thickness
Oxygen additions
Luminous intensity
Transparent thin film
Yttrium hydride
Ultraviolet radiation
Initial conditions
Optical transmission
Illumination
Trigger circuits
Photochromic materials
Language English
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Snippet In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light...
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SubjectTerms Condensed matter: electronic structure, electrical, magnetic, and optical properties
Engineering Science with specialization in Electronics
Exact sciences and technology
Hydrides
Hydrogen
Illumination
Infrared
Infrared radiation
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Photochromism
Photoconductivity
Physics
Solar cells
Solar energy
Sputter deposition
TECHNOLOGY
TEKNIKVETENSKAP
Teknisk fysik med inriktning mot elektronik
Thin films
Yttrium
Yttrium compounds
Title A new thin film photochromic material: Oxygen-containing yttrium hydride
URI https://dx.doi.org/10.1016/j.solmat.2011.08.018
https://search.proquest.com/docview/1777117423
https://search.proquest.com/docview/911158541
https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-166327
Volume 95
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