Head-To-Tail and Heteroleptic Pentanuclear Circular Helicates
Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, w...
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Published in | Angewandte Chemie (International ed.) Vol. 49; no. 37; pp. 6655 - 6658 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley-VCH Verlag
03.09.2010
WILEY-VCH Verlag WILEY‐VCH Verlag Wiley |
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Abstract | Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands). |
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AbstractList | Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands). |
Author | Faulkner, Robert A Whitehead, Martina Voss, Melanie L Allen, Kirsty E Harding, Lindsay P Riis-Johannessen, T Rice, Craig R |
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BackLink | https://www.ncbi.nlm.nih.gov/pubmed/20672275$$D View this record in MEDLINE/PubMed |
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Keywords | N,S ligands SELF-RECOGNITION helical structures heteroleptic complexes LIGAND STRANDS COMPLEXES DINUCLEAR copper supramolecular chemistry UNITS |
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Snippet | Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of... |
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SubjectTerms | Chemistry Chemistry, Multidisciplinary copper helical structures heteroleptic complexes N, S ligands Physical Sciences S ligands Science & Technology supramolecular chemistry |
Title | Head-To-Tail and Heteroleptic Pentanuclear Circular Helicates |
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