Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography

• Published in: Journal of separation science Vol. 39; no. 23; pp. 4544 - 4548
• Main Authors: Wang, Xin, Lamprou, Alexandros, Svec, Frantisek, Bai, Yu, Liu, Huwei
• Format: Journal Article
• Language: English
• Published: Germany Blackwell Publishing Ltd 01.12.2016; Wiley Subscription Services, Inc; Wiley Blackwell (John Wiley & Sons)
• Subjects: Chiral stationary phases; Chromatography; Enantioselectivity; Liquid chromatography; Metal-organic frameworks; Nano-liquid chromatography; Nanostructure; Phenyls; Polymer monoliths; Polymerization; Polymers; Separation; Synthesis (chemistry); Polymer monoliths; Nano-liquid chromatography; Enantioselectivity; Chiral stationary phases; Metal-organic frameworks

A new approach to the preparation of enantioselective porous polymer monolithic columns with incorporated chiral metal–organic framework for nano‐liquid chromatography has been developed. While no enantioseparation was achieved with monolithic poly(4‐vinylpyridine‐co‐ethylene dimethacrylate) column,...